Photocurable elastomer composition, seal material, gasket for hard disc drive, hard disc drive and apparatus

Patent metadata

Field	Value
Publication number	US-9388267-B2
Application number	US-201414762891-A
Country	US
Kind code	B2
Filing date	Feb 4, 2014
Priority date	Feb 4, 2013
Publication date	Jul 12, 2016
Grant date	Jul 12, 2016

Abstract

A photocurable elastomer composition comprising: (A) a liquid polymer having a number average molecular weight of 5,000 or more, and mainly containing —[CH 2 C(CH 3 ) 2 ]— units; (B) a (meth)acrylate monomer; and (C) a photo polymerization initiator, the mass ratio ((A):(B)) between the component (A) and the component (B) being 10:90 to 39:61.

First claim

The invention claimed is:

1. A photocurable elastomer composition, comprising:
(A) a liquid polymer having a number average molecular weight of 5,000 or more, and containing 80 mass % or more of —[CH 2 C(CH 3 ) 2 ]— units;
(B) a (meth)acrylate monomer;
(C) a photo polymerization initiator, wherein:
the mass ratio ((A):(B)) between the component (A) and the component (B) is 12:88 to 39:61.

2. The photocurable elastomer composition according to claim 1 , the composition further comprising as a component (D) a polymer having a number average molecular weight of 1,000 or more and having two or more reactive functional groups per molecule, which are at least one selected from the group consisting of (meth)acryloyl group, vinyl group, vinylidene group and maleimide group, by 100 parts by mass or less with respect to 100 parts by mass in total of the component (A) and the component (B).

3. The photocurable elastomer composition according to claim 2 , wherein: the component (D) is a polymer having a number average molecular weight of 2,000 or more and mainly containing any one selected from the group consisting of units derived from polyisoprene, units derived from polybutadiene, units derived from styrene-butadiene copolymer, units derived from ethylene-propylene copolymer, and units derived from hydrogenated products thereof.

4. The photocurable elastomer composition according to claim 1 , wherein: the component (B) is a monofunctional acrylate.

5. The photocurable elastomer composition according to claim 1 , wherein: the component (B) is at least one selected from the group consisting of hydrocarbon (meth)acrylates having 6 or more carbon atoms, isobornyl (meth)acrylate, and (meth)acrylates derived from dicyclopentadiene.

6. The photocurable elastomer composition according to claim 1 , wherein: the molecular weight of the component (A) is 5,000 to 15,000;
the composition further comprising as a component (D) a polymer having a number average molecular weight of 1,000 or more and having two or more reactive functional groups per molecule, which are at least one selected from the group consisting of (meth)acryloyl group, vinyl group, vinylidene group and maleimide group;
the mass ratio ((D):(A)) between the component (D) and the component (A) is 20:80 to 80:20; and
the content of the component (B) is 40 mass % to 70 mass % with respect to the total amount of the component (D), the component (A) and the component (B).

7. The photocurable elastomer composition according to claim 6 , wherein: the component (D) has a hydrogenated butadiene skeleton as the main skeleton.

8. The photocurable elastomer composition according to claim 6 , wherein: the component (D) has (meth)acryloyl groups on both terminals.

9. The photocurable elastomer composition according to claim 6 , wherein: the component (B) has a cyclic hydrocarbon skeleton.

10. The photocurable elastomer composition according to claim 9 , wherein: the component (B) is isobornyl acrylate.

11. The photocurable elastomer composition according to claim 1 , the composition further comprising as the component (D) a polymer having a number average molecular weight of 3,000 or more and having two or more reactive functional groups per molecule, which are at least one selected from the group consisting of (meth)acryloyl group, vinyl group, vinylidene group and maleimide group, wherein:
the mass ratio ((A):(D)) between the component (A) and the component (D) is 7:93 to 75:25, and
the content of the component (B) is 25 to 55 mass % with respect to the total amount of the component (A), the component (D) and the component (B).

12. The photocurable elastomer composition according to claim 11 , wherein: the component (D) is a polymer mainly containing any one selected from the group consisting of units derived from polyisoprene, units derived from polybutadiene, units derived from styrene-butadiene copolymer, units derived from ethylene-propylene copolymer, and units derived from hydrogenated products thereof.

13. The photocurable elastomer composition according to claim 11 , wherein: the component (B) is at least one monofunctional (meth)acrylate selected from the group consisting of hydrocarbon (meth)acrylates having 6 or more carbon atoms, isobornyl (meth)acrylate, and (meth)acrylates derived from dicyclopentadiene.

14. The photocurable elastomer composition according to claim 11 , the composition further containing as the component (E) at least one selected from the group consisting of inorganic fillers and organic fillers.

15. The photocurable elastomer composition according to claim 14 , wherein: the component (E) is a fumed silica.

16. The photocurable elastomer composition according to claim 1 , the composition being for use in a seal material.

17. The photocurable elastomer composition according to claim 1 , the composition being for use in a gasket for hard disc drive.

18. A seal material using the photocurable elastomer composition according to claim 1 in at least a part thereof.

19. A gasket for hard disc drive, the gasket using the photocurable elastomer composition according to claim 1 in at least a part thereof.

20. An apparatus, the apparatus using the seal material according to claim 18 in at least a part thereof.

21. A hard disc drive, the hard disc drive using the gasket for hard disc drive according to claim 19 in at least a part thereof.

Assignees

• Bridgestone Corp

Inventors

• Kurata Toshihiko
• Sano Takehiro

Classifications

• C08L2203/20

  use in electrical or conductive gadgets · CPC title

• C08L51/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• C09D151/003

  grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds (C09D151/04, C09D151/06 take precedence) · CPC title

• C08F2/48

  by ultraviolet or visible light · CPC title

• C09K2003/1062

  UV-curable materials · CPC title