Adhesive composition and image display device using same

Patent metadata

Field	Value
Publication number	US-9657201-B2
Application number	US-201214344382-A
Country	US
Kind code	B2
Filing date	Sep 27, 2012
Priority date	Sep 29, 2011
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

The present invention provides an adhesive composition which has a cured product exhibiting high transparency and a high refractive index, and which has high adhesive strength and experiences little reduction in the adhesive strength, even when exposed to high temperatures. In order to achieve the above the adhesive composition includes: (1) a hydrocarbon polymer having a total light transmittance of visible light, as measured according to JIS K7361-1, of at least 80%; (2) at least one kind of (meth)acrylic monomer selected from a mono(meth)acrylic monomer having one (meth)acrylic group in a molecule and a di(meth)acrylic monomer having two (meth)acrylic groups in a molecule; and (3) a photoinitiator; wherein 30-190 parts by weight of component (2) are included relative to 100 parts by weight of component (1).

First claim

The invention claimed is:

1. An adhesive composition comprising:
(1) a hydrocarbon polymer having a total light transmittance in a visible light region at a thickness of 1 mm as measured according to JIS K7361-1 of 80% or more;
(2) at least one (meth)acrylic monomer selected from the group consisting of a monofunctional (meth)acrylic monomer having one (meth)acrylic group in a molecule and a bifunctional (meth)acrylic monomer having two (meth)acrylic groups in a molecule;
(3) a photoinitiator; and
(4) a copolymer of a C 4-6 unsaturated aliphatic hydrocarbon having one or two carbon-carbon double bonds in a molecule and isopropenyl toluene, the copolymer having a number-average molecular weight (Mn) of 400 to 1,200 and a molecular weight distribution (Mw/Mn) represented by a ratio of weight-average molecular weight (Mw) to number-average molecular weight (Mn) of 2 or less,
wherein the content of the component (2) is 30 parts by weight or more and less than 190 parts by weight relative to 100 parts by weight of the component (1).

2. The adhesive composition according to claim 1 , wherein, in an image display apparatus comprising a protective member and a base having an image display part, the adhesive composition is arranged between the protective member and the base.

3. The adhesive composition according to claim 1 , wherein the component (1) has a softening point of 70 to 130° C.

4. The adhesive composition according to claim 1 , wherein a storage modulus E′ (25) of a cured product of the adhesive composition as measured at 25° C. and 10 Hz is more than 1.0×10 7 Pa and 1.0×10 9 Pa or less.

5. The adhesive composition according to claim 1 , wherein the component (1) is one or more polymers selected from the group consisting of polyisopropyltoluene, an alicyclic saturated hydrocarbon resin, and a terpene hydride.

6. The adhesive composition according to claim 5 , wherein the component (1) is polyisopropyltoluene having a number-average molecular weight (Mn) of 400 to 1,200 and a molecular weight distribution (Mw/Mn) represented by a ratio of weight-average molecular weight (Mw) to number-average molecular weight (Mn) of 2 or less.

7. The adhesive composition according to claim 6 , wherein the component (1) is polyisopropyltoluene prepared by polymerizing isopropenyl toluene with a Friedel-Crafts catalyst.

8. The adhesive composition according to claim 1 , wherein the monofunctional (meth)acrylic monomer is represented by the following general formula (1):

wherein R 1 represents a C 4-18 hydrocarbon group, and R 2 represents a hydrogen atom or a methyl group.

9. The adhesive composition according to claim 1 , wherein the bifunctional (meth)acrylic monomer is represented by the following general formula (2):

wherein R 3 represents a C 4-12 hydrocarbon group, and R 4 and R 5 independently represent a hydrogen atom or a methyl group.

10. The adhesive composition according to claim 1 , wherein the adhesive composition has a viscosity at 25° C. and 10 rpm as measured by an R-type viscometer of 0.5 to 10 Pa·s.

11. An image display apparatus comprising:
a protective member;
a base having an image display part; and
a filler interposed between the protective member and the base,
wherein the filler is a cured product of the adhesive composition according to claim 1 .

12. A method for producing an image display apparatus comprising a protective member, a base having an image display part, and a filler interposed between the protective member and the base, the method comprising:
interposing the adhesive composition according to claim 1 between the protective member and the base; and
curing the adhesive composition by light irradiation.

Assignees

• Mitsui Chemicals Inc

Inventors

• Mizuta Yasushi
• Gomi Toshikazu

Classifications

• C09J11/06

  organic · CPC title

• C09J5/00

  Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers · CPC title

• C09J11/08

  Macromolecular additives · CPC title

• Y10T428/31935

  Ester, halide or nitrile of addition polymer · CPC title

• C09J151/003

  grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds (C09J151/04, C09J151/06 take precedence) · CPC title