Adhesive article comprising an acrylic foam layer

Patent metadata

Field	Value
Publication number	US-9376599-B2
Application number	US-201013203839-A
Country	US
Kind code	B2
Filing date	Feb 23, 2010
Priority date	Mar 5, 2009
Publication date	Jun 28, 2016
Grant date	Jun 28, 2016

Abstract

The present disclosure provides an adhesive article comprising a foam layer having first and second major sides and a pressure sensitive adhesive layer associated with at least one of the major sides for the foam layer, said pressure sensitive adhesive layer comprising a cross-linked rubber and wherein the foam layer comprises an acrylic polymer obtainable by polymerization a polymerizable composition comprising one or more alkyl acrylates having an average of 3 to 14 carbon atoms in the alkyl groups, one or more polar monomers and one or more multi-functional monomers having at least two free radical polymerizable groups.

First claim

The invention claimed is:

1. Adhesive article comprising a foam layer having first and second major sides and a pressure sensitive adhesive layer associated with at least one of the major sides for the foam layer, said pressure sensitive adhesive layer comprising a cross-linked rubber and wherein the foam layer comprises an acrylic polymer obtainable by polymerization of a polymerizable composition comprising one or more alkyl acrylates having an average of 3 to 14 carbon atoms in the alkyl groups, one or more polar monomers and one or more multi-functional monomers having at least two free radical polymerizable groups, a fluoroaliphatic surfactant; and at least 0.20 wt % of a cross linking agent, wherein said polymerizable composition comprises 83 to 97% by weight of said alkyl acrylates, 3 to 16% by weight of said polar monomers and 0.01 to 1% by weight of said multi-functional monomers.

2. Adhesive article according to claim 1 wherein said pressure sensitive adhesive layer comprises an acrylic pressure sensitive adhesive component.

3. Adhesive article according to claim 2 wherein said acrylic pressure sensitive adhesive component comprises an acrylic polymer having repeating units derived from one or more alkyl acrylates having 3 to 14 carbon atoms in the alkyl group and one or more polar monomers.

4. Adhesive article according to claim 1 wherein cross-linked rubber comprises a cross-linked block copolymer having a rubbery block and a glassy block.

5. Adhesive article according to claim 4 wherein said rubbery block comprises a first polymerized conjugated diene, a hydrogenated derivative thereof, or combinations thereof and wherein said glassy block comprises a monovinyl aromatic monomer.

6. Adhesive article according to claim 1 wherein each of said first and second major side of said adhesive article have associated with them said pressure sensitive adhesive layer.

7. Adhesive article according to claim 1 wherein said adhesive article has said pressure sensitive adhesive layer associated with said first major side and wherein said second major side does not have an adhesive layer associated with it.

8. Adhesive article according to claim 1 wherein said adhesive article has said pressure sensitive adhesive layer associated with said first major side and wherein said second major side has a further adhesive layer associated with it.

9. Adhesive article according to claim 8 wherein said further adhesive layer comprises a pressure sensitive adhesive component or a heat activatable adhesive component.

10. Method of making an adhesive article as claimed in claim 1 comprising:
making a foam layer having first and second major sides by (a) providing a polymerizable composition comprising one or more alkyl acrylates having an average of 3 to 14 carbon atoms in the alkyl groups, one or more polar monomers and one or more multi-functional monomers having at least two free radical polymerizable groups and a fluoroaliphatic surfactant, (b) frothing said polymerizable composition and (c) polymerizing said polymerizable composition;
(ii) applying a pressure sensitive adhesive composition comprising a cross-linkable rubber on one or both of said first and second major sides of said foam layer so as to form a pressure sensitive adhesive layer; and
(iii) cross-linking said cross-linkable rubber.

11. Method according to claim 10 wherein said cross-linking comprises exposing said cross-linkable rubber to e-beam radiation.

12. Use of an adhesive article according to claim 1 comprising adhering said adhesive article to a substrate through said pressure sensitive adhesive layer.

Assignees

• Welke Siegfried K
• Paschmann Volker
• 3M Innovative Properties Co

Inventors

• Welke Siegfried K
• Paschmann Volker

Classifications

• C09J2409/00

  Presence of diene rubber · CPC title

• C09J2433/00

  Presence of (meth)acrylic polymer · CPC title

• C09J2453/00

  Presence of block copolymer · CPC title

• C08F220/1804

  C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate · CPC title

• C08J2309/00

  Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title