Pressure-sensitive adhesives based on natural rubber and polyacrylates

Patent metadata

Field	Value
Publication number	US-9499726-B2
Application number	US-200913130477-A
Country	US
Kind code	B2
Filing date	Dec 7, 2009
Priority date	Dec 17, 2008
Publication date	Nov 22, 2016
Grant date	Nov 22, 2016

Abstract

A pressure-sensitive adhesive consisting of a homogeneous mixture of at least one natural rubber component and at least one polyacrylate component displays significantly improved properties in cohesion and aging and weathering resistance compared to the individual components. Particularly good properties are achieved when the adhesive contains x % by weight of at least one natural rubber component, y % by weight of at least one polyacrylate component, v % by weight of at least one adhesive resin component and w % by weight of additives, where 10≦×x≦80, 10≦y<95, 0≦v≦50, 0≦w≦10 and x+y+v+w=100. A single- or double-sided adhesive tape consisting of at least one support and at least one layer of such a pressure-sensitive adhesive therefore likewise has good cohesion and aging resistance properties.

First claim

The invention claimed is:

1. A pressure-sensitive adhesive consisting of a homogeneous mixture of between 20 to 50 wt. % of at least one natural rubber component and between 50 to 80 wt. % of one polyacrylate component, wherein the one polyacrylate component is a polymer consisting of a monomer selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate, n-butyl acrylate, n-butyl methacrylate, n-pentyl acrylate, n-hexyl acrylate, n-heptyl acrylate, n-octyl acrylate, n-octyl methacrylate, n-nonyl acrylate, lauryl acrylate, stearyl acrylate, behenyl acrylate, isobutyl acrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, isooctyl acrylate, isooctyl methacrylate, cyclohexyl methacrylate, isobornyl acrylate, isobornyl methacrylate, 3,5-dimethyladamantyl acrylate, and mixtures thereof, and contains no further components other than said natural rubber component and said polvacrylate component.

2. A method for producing a pressure-sensitive adhesive of claim 1 , comprising the steps of:
a) providing the natural rubber and the acrylate polymer and
b) mixing the components provided in step a) in an extruder to give a homogeneous mixture, and
wherein the method is carried out at a temperature of more than 100° C., and at an extruder speed of more than 50 rpm.

3. The method of claim 2 , wherein
c) the mixture obtained in step b) is shaped to a pressure-sensitively adhesive layer by application with a layer thickness of 15 to 200 g/m 2 .

4. The method of claim 2 , wherein the mixture, subsequently to step c), is subjected to an electron beam cure.

5. A single- or double-sided adhesive tape composed of at least one carrier and at least one layer of the pressure-sensitive adhesive of claim 1 .

6. A single- or double-sided adhesive tape comprising at least one carrier and at least one layer of the pressure-sensitive adhesive produced by a method as claimed in claim 2 .

Assignees

• Zmarsly Franziska
• Thormeier Sabine
• Kreft Christian
• Burmeister Axel
• Bünz Stephan
• Tesa Se

Inventors

• Zmarsly Franziska
• Thormeier Sabine
• Kreft Christian
• Burmeister Axel
• Bünz Stephan

Classifications

• C09J193/00

  Adhesives based on natural resins; Adhesives based on derivatives thereof · CPC title

• C09J2407/00

  Presence of natural rubber · CPC title

• C09J161/00

  Adhesives based on condensation polymers of aldehydes or ketones (with polyalcohols C09J159/00; with polynitriles C09J177/00); Adhesives based on derivatives of such polymers · CPC title

• C09J7/22

  Plastics; Metallised plastics · CPC title

• C09J133/08 Primary

  Homopolymers or copolymers of acrylic acid esters · CPC title