Adhesive composition and use thereof

Patent metadata

Field	Value
Publication number	US-9376597-B2
Application number	US-201313836858-A
Country	US
Kind code	B2
Filing date	Mar 15, 2013
Priority date	Nov 19, 2010
Publication date	Jun 28, 2016
Grant date	Jun 28, 2016

Abstract

The invention provides adhesives comprising at least one polymer component which contains at least 65 weight percent propylene, at least one nucleator and at least one functionalized wax. The inventive adhesives have increased heat resistance and decreased set-time, making them particularly well suited for assembly and packaging applications.

First claim

We claim:

1. An adhesive comprising:
(a) a polymer component which contains, in polymerized form, at least 65 wt % of propylene, based on the total weight of the polymer component;
(b) from about 0.01 to about 1 wt % of a nucleator;
(c) from about 0.5 to up to 5 wt % of a functionalized polypropylene wax; and
(d) from 21 to about 60 wt % of a tackifier
wherein the total weight percent of the adhesive equals to 100 wt % and
wherein the adhesive has a heat resistance of at least 5° C. greater than an adhesive without the nucleator and the functionalized polypropylene wax.

2. The adhesive of claim 1 wherein the polymer component comprises a copolymer of propylene and at least one comonomer, wherein the comonomer is selected from ethylene and/or C 4-20 alpha-olefins.

3. The adhesive of claim 1 wherein the polymer component is a polymer blend which comprises a mixture of at least two (co)polymers and each of the (co)polymer contains in (co)polymerized form at least 65 wt % of propylene, based on the total weight of each polymer.

4. The adhesive of claim 1 wherein the polymer component is a polymer blend which comprises at least one thermomechanical degraded semi-crystalline polypropylene (co)polymer and at least one thermomechanical degraded elastomeric rubber.

5. The adhesive of claim 1 wherein the nucleator is selected from the group consisting of allose, altrose, fructose, galactose, glucose, gulose, idose, mannose, sorbose, talose, tagatose, arabinose, ribose, ribulose, xylose, xylulose, lyxose, erythrose, threose, sorbitol, xylitol and derivatives thereof and/or mixtures thereof.

6. The adhesive of claim 5 wherein the nucleator is selected from the group consisting of 1,3: 2,4 dibenzylidene sorbitol, 1,2,3,4-di-para-methylbenzylidene sorbitol, 1,2,3,4-di-meta, para-methylbenzylidene sorbitol, bis(4-propylbenzylidene) propyl sorbitol and mixtures thereof.

7. An adhesive comprising:
(i) a polymer blend that comprises at least one thermomechanical degraded semi-crystalline polypropylene (co)polymer and at least one thermomechanical degraded elastomeric rubber;
(ii) from about 0.01 to about 1 wt % of a nucleator selected from the group consisting of organic acid salts, phosphoric acids, ethylene-(meth)acrylic acid ionomers, multiple amides components, sorbitols and their corresponding derivatives thereof;
(iii) from about 0.5 to up to 5 wt % of a functionalized polypropylene wax which is a wax grafted with at least one olefinically unsaturated dicarboxylic anhydride of less than 12 carbon atoms; and
(iv) from 21 to about 60 wt % of a tackifier
wherein the total weight percent of the adhesive equals to 100 wt % and
wherein the adhesive has a heat resistance of at least 5° C. greater than an adhesive without the nucleator and the functionalized polypropylene wax.

8. The adhesive of claim 7 wherein the polymer component comprises a copolymer of propylene and at least one comonomer, wherein the comonomer is selected from ethylene and/or C 4-20 alpha-olefins.

9. The adhesive of claim 7 wherein the polymer component is a polymer blend which comprises a mixture of at least two (co)polymers and each of the (co)polymer contains in (co)polymerized form at least 65 wt % of propylene, based on the total weight of each polymer.

10. An adhesive consisting essentially of:
(a) from about 30 to 78 wt % based on the total weight of the adhesive, of a polymer component which contains, in polymerized form, at least 65 wt % of propylene, based on the total weight of the polymer component;
(b) from about 0.05 to about 1 wt %, based on the total weight of the adhesive, of at least one nucleator;
(c) from about 0.01 to up to 5 wt %, based on the total weight of the adhesive, of at least one functionalized polypropylene wax;
(d) from 21 to about 50 wt %, based on the total weight of the adhesive, of a tackifier, and
(e) from 0 to about 10 wt %, based on the total weight of the adhesive, of a plasticizer, stabilizer, and/or additive;
wherein the total weight percent of the adhesive equals to 100 weight percent and wherein the adhesive has a heat resistance of at least 5° C. greater than an adhesive without the nucleator and the functionalized polypropylene wax.

11. The adhesive of claim 10 wherein the polymer component comprises a copolymer of propylene and at least one comonomer, wherein the comonomer is selected from ethylene and/or C 4-20 alpha-olefins.

12. The adhesive of claim 10 wherein the polymer component is a polymer blend which comprises a mixture of at least two (co)polymers and each of the (co)polymer contains in (co)polymerized form at least 65 wt % of propylene, based on the total weight of each polymer.

13. The adhesive of claim 10 wherein the polymer component is a polymer blend which comprises at least one thermomechanical degraded semi-crystalline polypropylene (co)polymer and at least one thermomechanical degraded elastomeric rubber.

14. The adhesive of claim 10 wherein the nucleator is selected from the group consisting of allose, altrose, fructose, galactose, glucose, gulose, idose, mannose, sorbose, talose, tagatose, arabinose, ribose, ribulose, xylose, xylulose, lyxose, erythrose, threose, sorbitol, xylitol and derivatives thereof and/or mixtures thereof.

15. The adhesive of claim 14 wherein the nucleator is selected from the group consisting of 1,3: 2,4 dibenzylidene sorbitol, 1,2,3,4-di-para-methylbenzylidene sorbitol, 1,2,3,4-di-meta, para-methylbenzylidene sorbitol, bis(4-propylbenzylidene) propyl sorbitol and mixtures thereof.

Assignees

• Henkel Ag & Co Kgaa
• Henkel IP & Holding GmbH

Inventors

• Ellis Richard
• Paul Charles W
• Kasper Dirk
• Padurschel Petra
• Eodice Andrea

Classifications

• C09J123/12

  Polypropene · CPC title

• C09J7/35

  Heat-activated · CPC title

• C09J7/245

  Vinyl resins, e.g. polyvinyl chloride [PVC] · CPC title

• Y10T428/1352

  Polymer or resin containing [i.e., natural or synthetic] · CPC title

• C09J7/243

  Ethylene or propylene polymers · CPC title