Semiconductor devices, methods of manufacture thereof, and methods of manufacturing capacitors

Patent metadata

Field	Value
Publication number	US-9368567-B2
Application number	US-201514695303-A
Country	US
Kind code	B2
Filing date	Apr 24, 2015
Priority date	May 15, 2012
Publication date	Jun 14, 2016
Grant date	Jun 14, 2016

Abstract

Semiconductor devices, methods of manufacture thereof, and methods of manufacturing capacitors are disclosed. In an embodiment, a method of manufacturing a capacitor includes: etching a trench in a workpiece. The trench may extend into the workpiece from a major surface of the workpiece. The method further includes lining the trench with a bottom electrode material and lining the bottom electrode material in the trench with a dielectric material. The dielectric material may have edges proximate the major surface of the workpiece. The method further includes forming a top electrode material over the dielectric material in the trench, and etching away a portion of the bottom electrode material and a portion of the top electrode material proximate the edges of the dielectric material.

First claim

What is claimed is:

1. A method of manufacturing a capacitor, the method comprising:
etching a workpiece to form a trench, the trench extending into the workpiece from a major surface of the workpiece;
lining the trench with a bottom electrode material;
lining the bottom electrode material in the trench with a dielectric material, the dielectric material having edges proximate the major surface of the workpiece;
forming a top electrode material over the dielectric material in the trench, the top electrode material filling the trench; and
etching away a portion of the bottom electrode material and a portion of the top electrode material proximate the edges of the dielectric material.

2. The method of claim 1 , wherein the workpiece comprises an insulating layer disposed over a semiconductor substrate, and wherein the etching the trench in the workpiece comprises etching the trench in the insulating layer, the trench exposing the semiconductor substrate of the workpiece.

3. The method of claim 1 , wherein the etching away the portion of the bottom electrode material and the portion of the top electrode material comprises using an isotropic etch process.

4. The method of claim 1 , wherein the etching away the portion of the bottom electrode material and the portion of the top electrode material comprises simultaneously etching away the portion of the bottom electrode material and the portion of the top electrode material.

5. The method of claim 1 , wherein the etching away the portion of the bottom electrode material and the portion of the top electrode material comprises removing the portion of the bottom electrode material and the portion of the top electrode material, wherein substantially no portion of the dielectric material is removed.

6. The method of claim 1 , wherein the etching away the portion of the bottom electrode material and the portion of the top electrode material comprises recessing the bottom electrode material and the top electrode material by a dimension in a range from about 5 to 300 Angstroms, the dimension measured from the major surface of the workpiece.

7. The method of claim 1 , further comprising:
after the etching away, electrically connecting the top electrode material to a conductive feature.

8. A method of manufacturing a capacitor, the method comprising:
forming a trench in an insulating layer, the trench exposing a surface of a semiconductor substrate;
lining the trench and a major surface of the insulating layer with a bottom electrode material;
lining the bottom electrode material with a capacitor dielectric layer;
forming a top electrode material over the capacitor dielectric layer, the top electrode material filling the trench;
removing portions of the top electrode material, the capacitor dielectric layer, and the bottom electrode material disposed outside the trench; and
simultaneously recessing a portion of the top electrode material and a portion of the bottom electrode material remaining in the trench using an etching process, wherein the etching process is selective to material of the capacitor dielectric layer.

9. The method of claim 8 , wherein the lining the trench and the major surface of the insulating layer with the bottom electrode material comprises conformally forming a first conductive layer over the insulating layer and conformally forming a second conductive layer over the first conductive layer, wherein the first conductive layer and the second conductive layer differ in composition.

10. The method of claim 9 , wherein the first conductive layer comprises a material selected from the group consisting essentially of Cu, Ti, Ta, W, Ru, WN, Jr, Pt, and combinations thereof.

11. The method of claim 9 , wherein the second conductive layer comprises a material selected from the group consisting essentially of TiN, TaN, W, WN, Ru, Jr, Pt, and combinations thereof.

12. The method of claim 9 , wherein the simultaneously recessing the portion of the top electrode material and the portion of the bottom electrode material remaining in the trench comprises simultaneously removing the portion of the top electrode material and a portion of the second conductive layer of the bottom electrode material, but not a portion of the first conductive layer of the bottom electrode material.

13. The method of claim 8 , wherein the forming the top electrode material over the capacitor dielectric layer comprises conformally forming a third conductive layer over the capacitor dielectric layer and conformally forming a fourth conductive layer over the third conductive layer, wherein the third conductive layer and the fourth conductive layer differ in composition.

14. The method of claim 13 , wherein the simultaneously recessing the portion of the top electrode material and the portion of the bottom electrode material remaining in the trench comprises simultaneously removing the portion of the bottom electrode material and a portion of the third conductive layer of the top electrode material, but not a portion of the fourth conductive layer of the top electrode material.

15. The method of claim 8 , wherein the removing portions of the top electrode material, the capacitor dielectric layer, and the bottom electrode material disposed outside the trench comprises using a chemical-mechanical polishing (CMP) process, wherein portions of the top electrode material, the capacitor dielectric layer, and the bottom electrode material remaining in the trench are substantially co-planar with the major surface of the insulating layer.

16. A method of manufacturing a capacitor, the method comprising:
forming a trench in a workpiece;
lining the trench and a major surface of the workpiece with a bottom electrode material;
lining the bottom electrode material with a dielectric material, the dielectric material having a first edge and a second edge opposite the first edge, the first edge and the second edge disposed outside the trench and over the major surface of the workpiece;
forming a top electrode material over the dielectric material; and
removing a portion of the bottom electrode material and a portion of the top electrode material proximate the first edge and the second edge of the dielectric material using an etch process.

17. The method of claim 16 , wherein the etch process is selective to material of the dielectric material.

18. The method of claim 16 , wherein the etch process comprises an isotropic etch process.

19. The method of claim 16 , wherein the etch process comprises applying a dilute aqueous solution of ammonium hydroxide and hydrogen peroxide or a diluted ammonia and peroxide mixture (DAPM).

20. The method of claim 16 , further comprising electrically connecting the top electrode material to a conductive via.

Assignees

• Taiwan Semiconductor Mfg

Inventors

• Tu Kuo-Chi

Classifications

• H10P50/667

  by liquid etching only · CPC title

• H10D1/716

  having vertical extensions · CPC title

• H10D1/694

  comprising noble metals or noble metal oxides · CPC title

• H10D1/692

  Electrodes · CPC title

• H10D1/68

  Capacitors having no potential barriers · CPC title