Process for fabricating a monolayer or multilayer metal structure in LIGA technology, and structure obtained

Patent metadata

Field	Value
Publication number	US-9365941-B2
Application number	US-201113212636-A
Country	US
Kind code	B2
Filing date	Aug 18, 2011
Priority date	Mar 15, 2006
Publication date	Jun 14, 2016
Grant date	Jun 14, 2016

Abstract

The invention relates to a process for fabricating a monolayer or multilayer metal structure in LIGA technology, in which a photoresist layer is deposited on a flat metal substrate, a photoresist mold is created by irradiation or electron or ion bombardment, a metal or alloy is electroplated in this mold, the electroformed metal structure is detached from the substrate and the photoresist is separated from this metal structure, wherein the metal substrate is used as an agent involved in the forming of at least one surface of the metal structure other than that formed by the plane surface of the substrate.

First claim

The invention claimed is:

1. A metal structure which is a monolayer metal structure or a multilayer metal structure having entirely superposed layers,
wherein the metal structure has an insert attached thereto, wherein the insert is held integrally captive in the metal structure so that relative movement of the insert and the metal structure is prevented,
wherein the metal structure has been obtained by a process for fabricating at least one monolayer or multilayer metal structure in LIGA technology, comprising:
depositing a photoresist layer on a flat metal substrate,
creating at least one photoresist mold by irradiation or electron or ion bombardment,
electroplating a metal or alloy in the mold to form an electroformed metal structure,
detaching the electroformed metal structure and the photoresist layer from the substrate, and
separating the photoresist from the electroformed metal structure,
wherein a positioning member is fastened to the substrate before forming said electroformed metal structure, wherein the positioning member positions an insert on said substrate, wherein said insert is removably associated with said positioning member,
wherein said positioned insert becomes attached to said electroformed metal structure when said electroformed metal structure is formed, and
wherein the electroformed metal structure is detached from the substrate together with said insert attached to the metal structure and the photoresist layer, so that the obtained metal structure has the positioned insert attached thereto,
wherein the metal structure surrounds the insert so that the insert is anchored in the metal structure,
wherein the insert is a jewel bearing,
wherein a sidewall of the jewel has a symmetry of revolution around a main axis of the jewel, and wherein the sidewall has cross-sections of different diameters, so that the jewel is anchored in the metal structure,
wherein the insert has a groove and the metal structure forms an annular rib in the groove.

2. The metal structure as claimed in claim 1 , wherein the fabrication process comprises the following steps:
a) coating a bulk metal substrate with a photoresist layer;
c) exposing the photoresist layer to UV irradiation of 100 to 2000 mJ/cm 2 measured at a wavelength of 365 nm, through a mask corresponding to the desired impression;
e) carrying out development by dissolving the uncured or photodecomposed parts;
f) electrodepositing a metal or an alloy in the open parts of the photoresist mold,
g) levelling the electroformed metal structure by machining, so as to obtain a plane upper surface;
i) detaching the metal structure and the cured photoresist, by delamination from the bulk metal substrate, then separating the cured photoresist from the machined monolayer metal structure,
wherein the positioned insert is fastened to the substrate after steps a) to e).

3. The metal structure as claimed in claim 2 , wherein the fabrication process further comprises the following step:
b) heating the photoresist layer in order to evaporate the solvent.

4. The metal structure as claimed in claim 2 , wherein the fabrication process further comprises the following step:
d) annealing the layer obtained after step c) in order to complete the photocuring or the photodecomposition.

5. The metal structure as claimed in claim 1 which is a multilayer machined metal structure having entirely superposed layers in UV-LIGA technology, wherein the fabrication process comprises the following steps:
a) coating a bulk metal substrate with a photoresist layer;
c) exposing the photoresist layer to UV irradiation of 100 to 2000 mJ/cm 2 measured at a wavelength of 365 nm, through a mask corresponding to desired impression;
e) carrying out development by dissolving uncured or photodecomposed parts;
f) electrodepositing a metal or an alloy in open parts of the photoresist mold, wherein:
g) levelling the electroformed metal structure by machining, so as to obtain a plane upper surface;
h) repeating steps a), c), and e) and activating that surface of the electroformed metal which is not covered with cured photoresist;
i) repeating steps f) and g);
l) detaching the metal structure and the cured photoresist from the bulk metal substrate by delamination from the bulk metal substrate, then separating the cured photoresist from the multilayer electroformed metal structure having superposed layers.

6. The metal structure as claimed in claim 5 , wherein the fabrication process further comprises the following step:
b) heating the photoresist layer in order to evaporate the solvent.

7. The metal structure as claimed in claim 5 , wherein the fabrication process further comprises the following step:
d) annealing the layer obtained after step c) in order to complete the photocuring or the photodecomposition.

8. The metal structure as claimed in claim 5 , wherein the fabrication process further comprises the following steps:
j) repeating steps h) and i).

9. The metal structure as claimed in claim 5 , wherein the fabrication process further comprises the following step:
after detaching the metal structure and the cured photoresist from the bulk metal substrate by delamination and before separating the cured photoresist from the machined multilayer structure, carrying out at least one etching, surface-treatment, mechanical or laser marking operation on the detached metal structure.

10. The metal structure as claimed in claim 1 , in which the metal substrate is made of stainless steel.

11. The metal structure as claimed in claim 1 , in which the surface of the substrate has been worked by micropeening, chemical or mechanical etching, or by a laser so as to obtain the negative of a finished surface of the electroformed metal structure.

12. The metal structure as claimed in claim 1 , in which the metal substrate has an upper face polished to the degree of polishing desired for the adjacent face of said electroformed metal structure.

13. The metal structure as claimed in claim 1 , in which, after the metal structure and the cured photoresist have been detached, etching, surface treatment and mechanical or laser marking operations have been carried out on the detached metal structure.

14. The metal structure as claimed in claim 1 , wherein the fabrication process further comprises the following step:
after detaching the metal structure and the cured photoresist from the bulk metal substrate by delamination and before separating the cured photoresist from the monolayer structure, carrying out at least one etching, surface-treatment, mechanical or laser marking operation on the detached metal structure.

15. The metal structure as claimed in claim 1 , wherein the fabrication process further comprises the following step:
passivating the bulk metal substrate before depositing the photoresist layer.

16. The metal structure as claimed in claim 15 , wherein the metal substrate on which the photoresist layer is deposited is a bulk metal substrate which has been passivated by alkaline degreasing followed by acid neutralization.

17. The metal structure as claimed in claim 1 , wherein the bulk metal substrate has been passivated by alkaline degreasing followed by acid neutralization.

18. The metal structure as claimed in claim 1 , which is an escapement anchor for a clock movement.

19. A plurality of metal structures, each of the metal structures being a metal structure as claimed in claim 1 and being separate from the other metal structures, wherein the plurality of metal structures are obt

Assignees

• Saucy Clément
• Rolex Sa

Inventors

• Saucy Clément

Classifications

• G03F7/00

  Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor (using photoresist structures for special production processes, see the relevant places, e.g. B44C, H10P76/00, H05K) · CPC title

• C25D1/20

  Separation of the formed objects from the electrodes {with no destruction of said electrodes} · CPC title

• B81C2201/032

  LIGA process · CPC title

• B81C99/0085

  using moulds and master templates, e.g. for hot-embossing · CPC title

• B81B2201/035

  Microgears · CPC title