Method for making solid electrolyte

Patent metadata

Field	Value
Publication number	US-9359454-B2
Application number	US-201213652824-A
Country	US
Kind code	B2
Filing date	Oct 16, 2012
Priority date	Dec 17, 2011
Publication date	Jun 7, 2016
Grant date	Jun 7, 2016

Abstract

A method for making a solid electrolyte includes the following steps. A first monomer, a second monomer, an initiator and a lithium salt are provided. Wherein the first monomer is R 1 —O CH 2 —CH 2 —O n R 2 , the second monomer is R 3 —O CH 2 —CH 2 —O m R 4 , each “R 1 ”, “R 2 ” and “R 3 ” includes —C═C— group or —C≡C— group, “R 4 ” is an alkyl group or a hydrogen (H), and “m” and “n” represents an integer number, molecular weights of the first and second monomers are greater than or equal to 100, and less than or equal to 800. The first and second monomers, the initiator and the lithium salt are mixed to form a mixture, and a weight ratio of the first monomer to the second monomer is less than or equal to 50%. The first and second monomers are polymerized to form an interpenetrating polymer network, and the lithium salt is transformed into a solid solution and dispersing in the interpenetrating polymer network.

First claim

What is claimed is:

1. A method for making a solid electrolyte, comprising:
providing a first monomer, a second monomer, an initiator, and a lithium salt; wherein the first monomer is R 1 —O CH 2 —CH 2 —O n R 2 , the second monomer is R 3 —O CH 2 —CH 2 —O m R 4 , each “R 1 ”, “R 2 ” and “R 3 ” comprises —C═C— group or —C≡C— group, “R 4 ” is an alkyl group or a hydrogen (H), “m” and “n” respectively represents an integer number, and a molecular weight of the first monomer or a molecular weight of the second monomer is greater than or equal to 100, and less than or equal to 800;
providing a plasticizer;
mixing the plasticizer with the first monomer, the second monomer, the initiator, and the lithium salt to form a mixture; wherein the first monomer is less than or equal to 50% of the second monomer by weight, and the plasticizer is a four-arm macromolecule material or a six-arm macromolecule material; and
polymerizing the first monomer with the second monomer to form an interpenetrating polymer network, and transforming the lithium salt into a solid solution and dispersing in the interpenetrating polymer network, thereby forming the solid electrolyte.

2. The method of claim 1 , wherein each “R 1 ”, “R 2 ” and “R 3 ” comprises an unsaturated chain hydrocarbon group or an unsaturated chain hydrocarbon group with carbonyl.

3. The method of claim 2 , wherein each “R 1 ”, “R 2 ” and “R 3 ” comprises ethenyl (—CH═CH 2 ), ethynyl (—C≡CH), allyl (—CH═CH—CH 3 , or —(CH 3 )C═CH 2 ), propinyl (—C≡C—CH 3 ), or ethenyl ketonic group

4. The method of claim 1 , wherein the molecular weight of the first monomer or the molecular weight of the second monomer is greater than or equal to 200 and less than or equal to 600.

5. The method of claim 1 , wherein the lithium salt is selected from the group consisting of lithium perchlorate, lithium hexafluoro-phosphate, lithium tetrafluoro-borate, lithium bis(oxalate)-borate, lithium manganate, lithium iron phosphate, lithium nickelate, lithium cobalt oxide, and combinations thereof.

6. The method of claim 1 , wherein the providing the plasticizer comprises:
dropping a phloroglucionl-acetonitrile solution into phosphorus oxychloride to form a primary mixture;
stirring the primary mixture to obtain an intermediate solution;
dissolving methyl polyethylene glycol-400 into an acetonitrile to form a secondary mixture;
adding the secondary mixture into the intermediate solution; and
removing evaporated solution after about 48 hours, thereby obtaining a six-arm macromolecule material.

7. The method of claim 1 , wherein the initiator is a photo-initiator selected from the group consisting of 1-hydroxy-cyclohexyl phenyl ketone, 2-methyl-1-[4-(methylthio)-phenyl]-2-morpholino-propiopheno, and dimethylol propionic acid.

8. The method of claim 7 , wherein the polymerizing the first monomer with the second monomer to form the interpenetrating polymer network comprises a step of: putting the mixture into a protective gas, and using a UV light to irradiate the mixture for a period to polymerize the first monomer with the second monomer under the photo-initiator.

9. The method of claim 8 , wherein the protective gas is nitrogen gas, helium gas, neon gas, argon gas, krypton gas or xenon gas.

10. The method of claim 8 , wherein the period is in a range from about 30 minutes to about 2 hours.

11. The method of claim 8 , wherein the first monomer is polyethyleneglycol (200) dimethacrylate, the second monomer is methoxy polyethylene glycol (350) monoacrylate, and the photo-initiator is dimethylol propionic acid.

12. The method of claim 11 , wherein the mixing the first monomer, the second monomer, the initiator and the lithium salt to form the mixture comprises steps of mixing polyethyleneglycol (200) dimethacrylate with methoxy polyethylene glycol (350) monoacrylate with a predetermined ratio to form a middle mixture, and then adding lithium perchlorate and dimethylol propionic acid into the middle mixture.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Wang Li
• He xiang-ming
• Li Jian-Jun
• Gao Jian
• Jiang Chang-Yin

Classifications

• C08F220/286

  and containing polyethylene oxide in the alcohol moiety, e.g. methoxy polyethylene glycol (meth)acrylate · CPC title

• C08F299/024

  the unsaturation being in acrylic or methacrylic groups · CPC title

• H01M2300/0082

  Organic polymers · CPC title

• C08F2/48 Primary

  by ultraviolet or visible light · CPC title

• H01M10/0565

  Polymeric materials, e.g. gel-type or solid-type · CPC title