Methods of removing a protective layer

Patent metadata

Field	Value
Publication number	US-9347139-B2
Application number	US-201313955511-A
Country	US
Kind code	B2
Filing date	Jul 31, 2013
Priority date	Jul 11, 2011
Publication date	May 24, 2016
Grant date	May 24, 2016

Abstract

A method of removing a metal protective layer from a surface of a reactor component comprising treating the metal protective layer with one or more chemical removal agents to remove at least a portion of the metal protective layer from the reactor component. A method of removing a metal protective layer from a surface of a reactor component comprising treating the metal protective layer to remove the metal protective layer from the reactor component, and determining a thickness of the reactor component following treatment.

First claim

What is claimed is:

1. A method of removing a first metal protective layer from a surface of a component of a catalytic reforming reactor comprising:
converting at least a portion of a hydrocarbon feed stream to provide aromatic hydrocarbons by contacting the hydrocarbon feed stream with a first reforming catalyst in the catalytic reforming reactor, wherein the hydrocarbon feed and the aromatic hydrocarbons contact the first metal protective layer;
removing the first reforming catalyst from the catalytic reforming reactor;
treating the first metal protective layer of the component of the catalytic reforming reactor with a mechanical removal agent to remove at least a portion of the first metal protective layer from the surface of the component of the catalytic reforming reactor;
heating the component of the catalytic reforming reactor to a temperature from about 120° F. to about 2,000° F. for from about 1 hour to about 500 hours following application of the mechanical removal agent;
after heating the component, treating the first metal protective layer with one or more chemical removal agents in an amount of from about 0.1 ppm to about 50,000 ppm to remove a remaining portion of the first metal protective layer from the reactor component at a temperature from about 200° F. to about 1,600° F. for from about 1 hour to about 500 hours; and
loading the catalytic reforming reactor with a second reforming catalyst comprising a zeolitic reforming catalyst or a bimetallic reforming catalyst,
wherein the first metal protective layer comprises stannides.

2. The method of claim 1 wherein the first. reforming catalyst is a zeolit.ie reforming catalyst selected from the group consisting of rhenium on an alumina support, iridium on an alumina support, platinum on a type X zeolite, platinum on a type Y zeolite, platinum on a cation exchanged type L zeolite, and a large-pore zeolite including an alkali or alkaline earth metal charged with one or more Group VIII metals.

3. The method of claim 1 wherein the second reforming catalyst is a bimetallic reforming catalyst comprising:
platinum, palladium, or rhodium;
at least one metal promoter, metallic activating element, or a combination thereof; and
a halogen promoter.

4. The method of claim 1 wherein the second reforming catalyst is a sulfur-tolerant bimetallic reforming catalyst.

5. The method of claim 1 further comprising a step of sequestering a movable metal compound, the one or more chemical removal agents, or the combination thereof resulting from treating the metal protective layer.

6. The method of claim 1 wherein the. one or more chemical removal agents comprise halogen-containing compounds, sulfur-containing compounds, oxygen containing compounds, or combinations thereof.

7. The method of claim 1 wherein the one or more chemical removal agents comprise elemental halogens, acid halides, alkyl halides, aromatic halides, organic halides, inorganic halide salts, halocarbons, or combinations thereof.

8. The method of claim 1 wherein the one or more chemical removal agents comprise chlorine gas, hydrochloric acid, hydrofluoric acid, sulfonyl chloride, oxygen, sulfuric acid, or combinations thereof.

9. The method of claim 1 wherein the mechanical removal agent comprises abrasive blasting, hydroblasting, an abrasive material, or combinations thereof.

10. The method of claim I wherein the mechanical removal agent comprises an abrasive blast pig, a hydroblast pig, or combinations thereof.

11. The method of claim 1 further comprising heating the component of the catalytic reforming reactor to a temperature of from about 100° F. to about 2000° F. prior to applying the mechanical removal agent.

12. The method of claim 1 wherein the metal protective layer further comprises antimonides, bismuthides, silicon, lead, mercury, arsenic, gallium, indium, tellurium, copper, selenium, thallium, intermetallic alloys, or combinations thereof.

13. The method of claim 1 further comprising a step of determining a thickness of the metal protective layer and the reactor component prior to said treating and determining the thickness of the reactor component following said treating.

14. A method of removing a metal protective layer from a surface of a component of a catalytic reforming reactor consisting of
treating the metal protective layer of the component of the catalytic reforming reactor by contacting the metal protective layer with a mechanical removal agent to remove the metal protective layer from the reactor component, wherein the metal protective layer comprises stannides; and
heating the component of the catalytic reforming reactor to a temperature of from about 120° F. to about 2000° F. for from about 1 hour to about 500 hours following application of the mechanical removal agent.

15. The method of claim 14 wherein the mechanical removal agent comprises abrasive blasting, hydroblasting, an abrasive material, an abrasive blast pig, a hydroblast pig, or combinations thereof.

16. The method of claim 15 wherein the metal protective layer further comprises antimonides, bismuthides, silicon, lead, mercury, arsenic, gallium, indium, tellurium, copper, selenium, thallium, inter metallic alloys, or combinations thereof.

17. The method of claim 16 wherein the. component is a heat exchanger, a furnace interior wall, a furnace tube, a furnace liner, a reactor interior wall, a flow distributor, a riser, a scallop, or a. center pipe.

18. The method of claim 17 wherein the step of heating is performed to a temperature of from about 150° F. to about 2000° F.

Assignees

• Chevron Phillips Chemical Co

Inventors

• Holtermann Dennis L
• Cheung Tin-Tack Peter
• Blessing Christopher D
• Huff Lawrence E
• Bergmeister Iii Joseph
• Hise Robert L
• Scanlon Geoffrey E
• Dockter David W

Classifications

• C23F1/12 Primary

  Gaseous compositions · CPC title

• C23G5/024 Primary

  containing hydrocarbons · CPC title

• C23G1/02

  with acid solutions · CPC title

• C10G35/065

  containing crystalline zeolitic molecular sieves, other than aluminosilicates · CPC title

• C10G35/09

  Bimetallic catalysts in which at least one of the metals is a platinum group metal · CPC title