Polymers having chelating functionality

Patent metadata

Field	Value
Publication number	US-9346899-B2
Application number	US-201214354618-A
Country	US
Kind code	B2
Filing date	Oct 31, 2012
Priority date	Oct 31, 2011
Publication date	May 24, 2016
Grant date	May 24, 2016

Abstract

The present invention provides novel polymers having chelating functionality and comprising units derived from an ethylenically unsaturated aminocarboxylate monomer which comprises units derived from ethylenediamine triacetic acid or its salt and a polymerizable vinyl monomer. The polymerizable vinyl monomer may be selected from (0-, m-, p-)DVBMO, allyl glycidyl ether, and glycidyl (meth)acrylate. The polymer may also comprise units derived from one or more ethylenically unsaturated monomers.

First claim

We claim:

1. A polymer having chelating functionality consisting essentially of units derived from
(a) an ethylenically unsaturated aminocarboxylate monomer having the following general structure:

wherein X 1 , X 2 and X 3 are each, independently, hydrogen or a mono- or polyvalent cation and the total charge on the monomer is zero; and one, and only one, of R 1 and R 2 is an —OH group, and the other is a polymerizable arm comprising a vinyl group and derived from one or more ethylenically unsaturated monomers, wherein the polymerizable arm has one of the following structures:

wherein R 4 is hydrogen or —CH 3 .

2. The polymer according to claim 1 , wherein the mono- or polyvalent cation may be selected from the group consisting of: Na + , K + , NH 4 + , organic ammonium ions, Ca 2+ and Mg 2+ .

3. The polymer according to claim 1 , wherein the polymerizable arm is derived from an ethylenically unsaturated monomer comprising an allyl glycidyl ether and has the following structure:

4. The polymer according to claim 1 , wherein the polymerizable arm is derived from an ethylenically unsaturated monomer comprising glycidyl (meth)acrylate monomer and has the following structure:

wherein R 4 is hydrogen or —CH 3 .

5. The polymer according to claim 1 , further comprising units derived from:
(b) one or more ethylenically unsaturated monomers.

6. The polymer according to claim 5 , wherein the one or more ethylenically unsaturated monomers selected from the group consisting of carboxylic acids, esters of carboxylic acids, carboxylic acid anhydrides, imides, amides, styrenes, sulfonic acids, and combinations thereof.

7. The polymer according to claim 5 , comprising (a) 0.5-99.5%, by weight, of the ethylenically unsaturated aminocarboxylate monomer, and (b) 99.5-0.5%, by weight, of the one or more ethylenicaly unsaturated monomers, based on the total weight of the polymer.

8. The polymer of claim 1 wherein the ethylenically unsaturated aminocarboxylate monomer has the following structure:

wherein each X is, independently, at least one cation selected from the group consisting of: Na + , K + , NH 4 + , organic ammonium ions, Ca 2+ and Mg 2+ .

9. The polymer of claim 1 wherein the ethylenically unsaturated aminocarboxylate monomer has the following structure:

wherein each X is, independently, at least one cation selected from the group consisting of: Na + , K + , NH 4 + , organic ammonium ions, Ca 2+ and Mg 2+ .

Assignees

• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Backer Scott
• Bulick Allen
• Manna Joseph
• Rand Cynthia
• Xie Jia

Classifications

• C08F212/28

  Amines · CPC title

• C08F212/22

  Oxygen · CPC title

• C08F220/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C02F5/12

  containing nitrogen (C02F5/14 takes precedence) · CPC title

• C08F16/28

  Monomers containing nitrogen · CPC title