Sustainable range of dyestuffs for textile and paper dyeing

Patent metadata

Field	Value
Publication number	US-9340674-B2
Application number	US-201214119836-A
Country	US
Kind code	B2
Filing date	May 23, 2012
Priority date	May 27, 2011
Publication date	May 17, 2016
Grant date	May 17, 2016

Abstract

The invention refers to the manufacturing of a novel group of sulfur dyes in which are used, as raw material, different kind of natural “biomass”, usually existing in the nature, and transforming them into soluble dyestuffs, capable to dye textile fibers, preferably cellulose fibers and derivatives, as cotton, viscose, paper, tencel, with high strength and fast color properties. For this purpose, the concept “Biomass”, is defined as the residual product obtained from the usual human crop activities, in agricultural and forestry sectors.

First claim

The invention claimed is:

1. A process for manufacturing a dyestuff comprising:
(i) providing vegetal biomass;
(ii) pretreating said vegetal biomass with an aqueous alkaline medium and/or with an amino and/or polyamino compound, at an elevated temperature;
(iii) mixing pretreated vegetal biomass with at least one sulfurization agent selected from the group consisting of sulfur, sulfide, and polysulfide;
(iv) heating said mixture to a temperature of from 120° C. to 350° C. for at least 2 hours; and
(v) dissolving the mixture in aqueous medium and optionally removing undissolved solid particles.

2. The process as claimed in claim 1 , wherein the vegetal biomass is a plant product from forest or agricultural crop activities and/or from marine sources.

3. The process as claimed in claim 1 , wherein the vegetal biomass is at least one selected from the group consisting of plant products comprising from about 3% to 50% by weight, based on dry mass, of lignin, plant products comprising from about 5% to 50% by weight, based on dry mass, of phenols and polyphenols, a mixture of these plant products, and marine plants.

4. The process as claimed in claim 1 , wherein in (ii), the pretreating of the vegetal biomass is carried out in an alkaline aqueous medium having a pH of at least 9.

5. The process as claimed in claim 4 , wherein in (ii), the amount by weight between the vegetal biomass and the alkaline aqueous medium is from 1:10 to 10:1.

6. The process as claimed in claim 1 , wherein in (ii), the amino and/or polyamino compound is used and are selected from the group consisting of monoalkylamines, monoalkylamino alcohols, ethylenediamine, propylenediamines, butylenediamines, C 5 -C 18 -alkylenediamines, urea, guanidine, dicyandiamide, di(C 1 C 4 -alkylene)triamines and tri (C 1 -C 4 -alkylene)tetramines.

7. The process as claimed in claim 1 , wherein the temperature of the pretreating is from 40° C. to 200° C.

8. The process as claimed in claim 1 , wherein the duration of the pretreating is from 1 hour to 48 hours.

9. The process as claimed in claim 1 , wherein the relative amount by weight between the sulfurization agent and the vegetal biomass after said pretreating, calculated on dry weight, is from 1:10 to 10:1.

10. An aqueous solution of a dyestuff prepared by the process as claimed in claim 1 .

11. The solution as claimed in claim 10 , comprising free sulfide in an amount of not more than 3% by weight, based on total weight of the aqueous solution.

12. An aqueous solution as claimed in claim 10 , capable of being used for dyeing cellulose material and/or cellulose-containing material.

13. A cellulose material and/or cellulose-containing material dyed with an aqueous solution as claimed in claim 10 .

14. The cellulose material and/or cellulose-containing material as claimed in claim 13 , comprising a cotton textile material.

15. The cellulose material and/or cellulose-containing material as claimed in claim 14 , wherein the cotton textile material comprises Denim jeans, dyed in brown and/or olive shades and wherein the vegetal biomass is from shells of dry fruits, fruit pits and/or from coffee ground.

16. An aqueous solution as claimed in claim 11 , capable of being used for dyeing cellulose material and/or cellulose-containing material.

17. A cellulose material and/or cellulose-containing material dyed with an aqueous dye solution as claimed in claim 11 .

18. The process of claim 1 , further comprising said removing undissolved solid particles.

19. The process of claim 1 , wherein the at least one sulfurization agent is sulfur.

20. The process of claim 1 , wherein the at least one sulfurization agent is sulfide.

Assignees

• Domingo Manuel Jose
• Blanquera Joan Manel
• Garcia Yolanda
• Clariant Int Ltd

Inventors

• Domingo Manuel Jose
• Blanquera Joan Manel
• Garcia Yolanda

Classifications

• C09B49/00 Primary

  Sulfur dyes · CPC title

• D06P1/34

  using natural dyestuffs · CPC title

• C09B61/00 Primary

  Dyes of natural origin prepared from natural sources {, e.g. vegetable sources} · CPC title

• D06P1/30

  using sulfur dyes · CPC title

• D06P3/58

  Material containing hydroxyl groups · CPC title