Carbon dioxide reduction in steelworks

Patent metadata

Field	Value
Publication number	US-9322597-B2
Application number	US-201214128104-A
Country	US
Kind code	B2
Filing date	Jun 12, 2012
Priority date	Jun 20, 2011
Publication date	Apr 26, 2016
Grant date	Apr 26, 2016

Abstract

A method reduces carbon dioxide resulting from a steel production process. The carbon dioxide is reacted with an electropositive metal in combustion to produce carbon monoxide. The resultant carbon monoxide is fed back into the steel production process. In this method, the carbon monoxide can be used in a direct reduction method as a reduction gas or can be fed to a blast furnace process. The reacted metal can also be recovered by electrochemical conversion from its oxides or salts. In particular, a form of regenerative energy can be used to recycle the electropositive metal.

First claim

The invention claimed is:

1. A method for reducing carbon dioxide, comprising:
receiving carbon dioxide which is formed in a steel production process;
combusting the carbon dioxide with an electropositive metal to convert the carbon dioxide and produce a first combustion product and thermal energy; and
feeding the first combustion product and the thermal energy back into the steel production process.

2. The method as claimed in claim 1 , wherein the electropositive metal is a metal selected from the group consisting of metals the first main group of the periodic table, metals of the second main group of the periodic table and metals with a normal potential which is less than zero volts.

3. The method as claimed in claim 1 , wherein the electropositive metal is lithium.

4. The method as claimed in claim 1 , wherein
the first combustion product comprises carbon monoxide, and
the carbon monoxide is fed back into the steel production process and used for reducing iron oxide.

5. The method as claimed in claim 4 , wherein the first combustion product is supplied to a blast furnace of the steel production process and used to replace a portion of a fuel used in the blast furnace.

6. The method as claimed in claim 5 , wherein the fuel is at least one of coal and coke.

7. The method as claimed in claim 4 , wherein
the first combustion product is supplied to a direct reduction process in the steel production process, and
in the direct reduction process the first combustion product functions as reducing gas.

8. The method as claimed in claim 7 , wherein
a carbon monoxide-hydrogen gas mixture is used as the reducing gas.

9. The method as claimed in claim 1 , wherein
combusting the carbon dioxide with the electropositive metal also produces a second combustion product, and
the second combustion product is supplied to a reconversion process in which regenerative energy is used to electrochemically reconvert the second combustion product.

10. The method as claimed in claim 9 , wherein
the second combustion product comprises an oxide and/or a salt of the electropositive metal, and
the second combustion product is converted into the electropositive metal in the reconversion process.

11. A steelworks system, comprising:
a combustion chamber to receive carbon dioxide from a first steelworks device and to combust the carbon dioxide with an electropositive metal to produce a first combustion product and thermal energy;
a second steelworks device to receive the first combustion product from the combustion chamber; and
a heat transporting device to connect the combustion chamber with the second steelworks device to transport the thermal energy from the combustion chamber to the second steelworks device.

12. The system as claimed in claim 11 , wherein the second steelworks device is a blast furnace or a fluidized bed reactor.

13. The system as claimed in claim 11 , wherein
combusting the carbon dioxide with the electropositive metal produces the first combustion product and an oxide and/or of a salt of the electropositive metal, and
the system further comprises a recycling device to electrochemically reconvert the oxide and/or the salt of the electropositive metal into the electropositive metal.

14. The system as claimed in claim 13 , wherein
the recycling device uses energy from a regenerative energy source to electrochemically reconvert the oxide and/or the salt of the electropositive metal.

Assignees

• Baldauf Manfred
• Schmid Günter
• Siemens Ag

Inventors

• Baldauf Manfred
• Schmid Günter

Classifications

• Y02P10/132

  Cross-Sectional Technologies · mapped topic

• Y02P10/122

  by capturing or storing CO2 · CPC title

• F27D17/00 Primary

  Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases · CPC title

• C21B7/002

  Evacuating and treating of exhaust gases · CPC title

• B01D53/62

  Carbon oxides · CPC title