Two part hybrid adhesive

Patent metadata

Field	Value
Publication number	US-9315701-B2
Application number	US-201414266137-A
Country	US
Kind code	B2
Filing date	Apr 30, 2014
Priority date	Mar 28, 2008
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

Provided are two part hybrid adhesives that comprise an organoborane amine complex, a polyamine, a component polymerizable by free radical polymerization, and a polyisocyanate component. An isocyanate terminated prepolymer can advantageously be used in the practice of the invention. The adhesive is particularly well suited for low surface energy plastic bonding.

First claim

The invention claimed is:

1. A polymerizable adhesive composition comprising an organoborane amine complex and a polyamine with a nitrogen to boron atomic ratio of less than 4, an isocyanate-terminated prepolymer made from an excess of isocyanate with polyol or polyamine, a free radically polymerizable component, and substantially no polyol, wherein the isocyanate-terminated prepolymer is present in an amount greater than 60 wt %.

2. A polymerizable adhesive composition comprising an organoborane amine complex, a polyamine component, a free radically polymerizable component, an isocyanate-terminated prepolymer made from an excess of isocyanate with polyol or polyamine, said composition comprising more than 50 wt % of urea, and substantially no polyol, wherein the isocyanate-terminated prepolymer is present in an amount greater than 60 wt %.

3. A polymerizable adhesive composition comprising an organoborane amine complex, a polyamine component, a free radically polymerizable component, and an isocyanate-terminated prepolymer made from an excess of isocyanate with polyol or polyamine, wherein the isocyanate-terminated prepolymer is present in an amount greater than 60 wt %.

4. The adhesive of claim 3 which is a two part adhesive comprising a part (A) and a part (B), wherein the ratio of part (A) to part (B) is from less than 4:1 to more than 1:4.

5. The adhesive of claim 4 , said composition comprising 60 to 100 wt % polyisocyanate in a second part (B).

6. A polymerizable adhesive composition comprising an organoborane amine complex and a polyamine with a nitrogen to boron atomic ratio of less than 4, a polyisocyanate component, a free radically polymerizable component, and substantially no polyol, wherein the polyisocyanate component is present in an amount greater than 60 wt %.

7. A polymerizable adhesive composition comprising an organoborane amine complex, a polyamine component, a free radically polymerizable component, and an isocyanate-terminated prepolymer made from an excess of isocyanate with polyol or polyamine, wherein the isocyanate-terminated prepolymer is present in an amount greater than 60 wt % and the adhesive is in a two part format, wherein the ratio of part (A) to part (B) is from less than 4:1 to more than 1:4.

8. A polymerizable adhesive composition comprising an organoborane amine complex, a polyamine component, a free radically polymerizable component, and a polyisocyanate, wherein the adhesive is a two part format, wherein the ratio of part (A) to part (B) is from less than 4:1 to more than 1:4 and part (B) comprises 60 to 100 wt % polyisocyanate.

Assignees

• Henkel IP & Holding GmbH

Inventors

• Wang Yongxia
• Paul Charles W

Classifications

• C08G18/36

  Hydroxylated esters of higher fatty acids · CPC title

• C08G18/5021 Primary

  having nitrogen · CPC title

• C08K5/55

  Boron-containing compounds {(C08K5/0091 takes precedence)} · CPC title

• C08G18/6225

  Polymers of esters of acrylic or methacrylic acid · CPC title

• C08G18/3268

  Salt complexes of polyamines · CPC title