Materials, fabrication equipment, and methods for stable, sensitive photodetectors and image sensors made therefrom
US-9209331-B2 · Dec 8, 2015 · US
US9312422B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9312422-B2 |
| Application number | US-201113991129-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 29, 2011 |
| Priority date | Dec 1, 2010 |
| Publication date | Apr 12, 2016 |
| Grant date | Apr 12, 2016 |
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A light receiving element includes an InP substrate that is transparent to light having a wavelength of 3 to 12 μm, a buffer layer located in contact with the InP substrate, and a light-receiving layer having a multiple quantum well structure, the light-receiving layer having a cutoff wavelength of 3 μm or more and being lattice-matched with the buffer layer. In the light receiving element, the buffer layer is epitaxially grown on the InP substrate while the buffer layer and the InP substrate exceed a range of a normal lattice-matching condition, and the buffer layer is constituted by a GaSb layer.
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The invention claimed is: 1. A light receiving element formed by using a group III-V compound semiconductor, the light receiving element comprising: an InP substrate that is transparent to light having a wavelength of 3 to 12 μm; a buffer layer having a thickness of 2 μm or more and located in contact with the InP substrate; and a light-receiving layer having a multiple quantum well structure and located in contact with the buffer layer, wherein the light-receiving layer has a cutoff wavelength of 3 μm or more and is lattice-matched with the buffer layer, the buffer layer is epitaxially grown on the InP substrate while a value |a 2 −a 1 |/a 1 exceeds a range of a normal lattice-matching condition, where a 2 represents a lattice parameter of the buffer layer and a 1 represents a lattice parameter of the InP substrate, the buffer layer is constituted by a GaSb layer doped with Te, and the buffer layer has a carrier concentration of 1E18 cm −3 or more, and the light receiving element has a structure in which light is incident from a rear surface of the InP substrate. 2. The light receiving element according to claim 1 , wherein the InP substrate that is transparent to light having a wavelength of 3 to 12 μm is an InP substrate to which sulfur (S) is not added. 3. The light receiving element according to claim 1 , wherein the InP substrate that is transparent to light having a wavelength of 3 to 12 μm is an Fe-containing InP substrate or an undoped InP substrate. 4. The light receiving element according to claim 1 , wherein the light-receiving layer has a p-n junction therein. 5. The light receiving element according to claim 1 , wherein the light-receiving layer includes an insertion layer that is composed of a group III-V compound semiconductor and that is lattice-matched with the light-receiving layer, and a insertion layer conduction band bottom is higher than a light-receiving layer conduction band bottom. 6. The light receiving element according to claim 1 , wherein the multiple quantum well structure is a type-II multiple quantum well structure selected from {(InAs/GaSb), (InAs/InGaSb), (InAsSb/GaSb), and (InAsSb/InGaSb)}. 7. A detecting device comprising the light receiving element according to claim 1 ; and a read-out integrated circuit (ROIC), wherein a pixel electrode in the light receiving element is connected to a read-out electrode in the ROIC with a bump interposed therebetween. 8. The light receiving element according to claim 1 , wherein the buffer layer consists essentially of GaSb. 9. A semiconductor epitaxial wafer formed by using a group III-V compound semiconductor, the semiconductor epitaxial wafer comprising: an InP substrate that is transparent to light having a wavelength of 3 to 12 μm; and a buffer layer having a thickness of 2 μm or more and located in contact with the InP substrate, wherein a value of |a 2 −a 1 |/a 1 exceeds a range of a normal lattice-matching condition, where a 2 represents a lattice parameter of the buffer layer and a 1 represents a lattice parameter of the InP substrate, and the buffer layer is constituted by a GaSb layer doped with Te, and the buffer layer has a carrier concentration of 1E18 cm −3 or more. 10. The semiconductor epitaxial wafer according to claim 9 , wherein the InP substrate that is transparent to light having a wavelength of 3 to 12 μm is an Fe-containing InP substrate or an undoped InP substrate. 11. The semiconductor epitaxial wafer according to claim 9 , further comprising a first semiconductor layer including a multiple quantum well structure, the first semiconductor layer being lattice-matched with the buffer layer. 12. The semiconductor epitaxial wafer according to claim 11 , wherein the multiple quantum well structure is a type-II multiple quantum well structure selected from {(InAs/GaSb), (InAs/InGaSb), (InAsSb/GaSb), and (InAsSb/InGaSb)}. 13. The semiconductor epitaxial wafer according to claim 9 , wherein the buffer layer consists essentially of GaSb.
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