Process for fabricating a monolayer or multilayer metal structure in LIGA technology, and structure obtained

Patent metadata

Field	Value
Publication number	US-9284654-B2
Application number	US-95282510-A
Country	US
Kind code	B2
Filing date	Nov 23, 2010
Priority date	Mar 15, 2006
Publication date	Mar 15, 2016
Grant date	Mar 15, 2016

Abstract

The invention relates to a process for fabricating a monolayer or multilayer metal structure in LIGA technology, in which a photoresist layer is deposited on a flat metal substrate, a photoresist mold is created by irradiation or electron or ion bombardment, a metal or alloy is electroplated in this mold, the electroformed metal structure is detached from the substrate and the photoresist is separated from this metal structure, wherein the metal substrate is used as an agent involved in the forming of at least one surface of the metal structure other than that formed by the plane surface of the substrate.

First claim

The invention claimed is:

1. A process for fabricating simultaneously a plurality of monolayer or multilayer metal structures in LIGA technology, comprising, in sequence:
a) depositing a photoresist layer on a flat bulk metal substrate,
b) creating a plurality of photoresist molds by irradiation or electron or ion bombardment,
c) electroplating a metal or alloy in these molds to form electroformed metal structures,
d) carrying out one or more machining operations on the upper face of the electroformed metal structures,
e) detaching the electroformed metal structures and the photoresist layer from the substrate, wherein the photoresist layer is un-separated from the metal structures,
f) carrying out at least one of (i) etching the electroplated metal or alloy of the detached metal structures, (ii) activating the electroplated metal or alloy of the detached metal structures by applying a reverse current, (iii) marking the electroplated metal or alloy of the detached metal structures by mechanical marking, and (iv) marking the electroplated metal or alloy of the detached metal structures by laser marking operations on the detached metal structures, wherein the photoresist layer is un-separated from the metal structures,

and
g) separating the photoresist from the metal structures,
wherein the bulk metal substrate on which the photoresist layer is deposited is a passivated bulk metal substrate for separating the metal structures and the photoresist from the bulk metal substrate by delamination.

2. The fabrication process as claimed in claim 1 , wherein:
step a) comprises:
a1) coating the bulk metal substrate with the photoresist layer;
step b) comprises:
b1) exposing the photoresist layer to UV irradiation of 100 to 2000 mJ/cm 2 measured at a wavelength of 365 nm, through a mask corresponding to the desired impression, and
b2) carrying out development by dissolving the uncured or photodecomposed parts;
step c) comprises:
c1) electrodepositing the metal or alloy in the open parts of the photoresist mold, and
step d) comprises:
d1) levelling the electroformed metal structures by machining, so as to obtain a plane upper surface;
step e) comprises:
e1) detaching the metal structures and the cured photoresist, by delamination from the bulk metal substrate; and
step g) comprises:
g1) separating the cured photoresist from the machined monolayer metal structures.

3. The process as claimed in claim 2 for fabricating a multilayer machined metal structure having entirely superposed layers in UV-LIGA technology, which comprises the following steps after step d1):
h) repeating steps a1), b1) and b2) and activating that surface of the electroformed metal which is not covered with cured photoresist;
i) repeating steps c1) and d1);
and wherein step g1) comprises separating the cured photoresist from the multilayer electroformed metal structures having superposed layers.

4. The process as claimed in claim 1 , in which the metal substrate is made of stainless steel.

5. The process as claimed in claim 1 , in which the surface of the substrate is worked by micropeening, chemical or mechanical etching, or by a laser so as to obtain the negative of a finished surface of the electroformed metal structures.

6. The process as claimed in claim 1 , in which the metal substrate has an upper face polished to the degree of polishing desired for the adjacent face of said electroformed metal structures.

7. The process as claimed in claim 2 , in which a positioning member, for positioning an element attached to said electroformed metal structures, is fastened to said substrate, after steps a1), b1) and b2), said attached element is removably associated with said positioning member and, once said electroformed metal structures have been deposited, these metal structures, together with said attached element and the cured photoresist are detached, by delamination, from the metal substrate.

8. The process as claimed in claim 2 , in which at least one tapped hole is made through the metal substrate, after steps a1), b1) and b2), a screw is placed in the tapped hole, making it extend beyond the surface of the substrate, said metal structures are deposited, this screw is unscrewed, and the metal structure and the cured photoresist are detached by delamination from the metal substrate, so as to obtain metal structures having at least one threaded hole.

9. The fabrication process as claimed in claim 2 , wherein step b) further comprises:
b3) heating the photoresist layer in order to evaporate the solvent.

10. The fabrication process as claimed in claim 2 , wherein step b) further comprises:
b4) annealing the layer obtained after step b2) in order to complete the photocuring or the photodecomposition.

11. The fabrication process as claimed in claim 3 , wherein step b) further comprises:
b3) heating the photoresist layer in order to evaporate the solvent.

12. The fabrication process as claimed in claim 3 , wherein step b) further comprises:
b4) annealing the layer obtained after step b2) in order to complete the photocuring or the photodecomposition.

13. The process as claimed in claim 3 , which further comprises the following step:
j) repeating steps h) and i).

14. The fabrication process as claimed in claim 1 , which further comprises the following steps:
providing an unpassivated bulk metal substrate, and
passivating the bulk metal substrate before depositing the photoresist layer.

15. The fabrication process as claimed in claim 14 , wherein the bulk metal substrate is passivated by alkaline degreasing followed by acid neutralization.

16. The fabrication process as claimed in claim 1 , wherein the bulk metal substrate has been passivated by alkaline degreasing followed by acid neutralization.

17. The fabrication process as claimed in claim 1 , wherein step (f) includes carrying out at least one of (iii) marking the electroplated metal or alloy of the detached metal structures by mechanical marking, and (iv) marking the electroplated metal or alloy of the detached metal structures by laser marking operations on the detached metal structures.

Assignees

• Saucy Clément
• Rolex Sa

Inventors

• Saucy Clément

Classifications

• G04B15/14

  Component parts or constructional details, e.g. construction of the lever or the escape wheel {(assembly and manufacture of the spring G04B1/145; assembly and manufacture of components, e.g. pinions, spindles G04B13/02; lubrication of clockwork bearings G04B31/008; oils for clockwork bearings in general G04B31/08)} · CPC title

• G03F7/00

  Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor (using photoresist structures for special production processes, see the relevant places, e.g. B44C, H10P76/00, H05K) · CPC title

• B81C2201/032

  LIGA process · CPC title

• B81B2201/035

  Microgears · CPC title

• B81C99/0085

  using moulds and master templates, e.g. for hot-embossing · CPC title