Lithium-containing scintillators for thermal neutron, fast neutron, and gamma detection

Patent metadata

Field	Value
Publication number	US-9274237-B2
Application number	US-201414253754-A
Country	US
Kind code	B2
Filing date	Apr 15, 2014
Priority date	Jul 26, 2013
Publication date	Mar 1, 2016
Grant date	Mar 1, 2016

Abstract

In one embodiment, a scintillator includes a scintillator material; a primary fluor, and a Li-containing compound, where the Li-containing compound is soluble in the primary fluor, and where the scintillator exhibits an optical response signature for thermal neutrons that is different than an optical response signature for fast neutrons and gamma rays.

First claim

What is claimed is:

1. A thermal neutron capture reagent, comprising:
a lithium-containing compound selected from a group consisting of: Li-3-phenylsalicylate, Li-3,5-di-tert-butylsalicylate, Li-acetylsalicylic acid, and combinations thereof,
wherein the lithium-containing compound is soluble in a fluor,
wherein the thermal neutron capture reagent exhibits an optical response signature for thermal neutrons.

2. A scintillator, comprising:
a scintillator material;
a primary fluor; and
a Li-containing compound,
wherein the Li-containing compound is soluble in the primary fluor,
wherein the scintillator exhibits an optical response signature for thermal neutrons that is different than an optical response signature for fast neutrons and gamma rays,
wherein the Li-containing compound is selected from a group consisting of: Li-3-phenylsalicylate, Li-3,5-di-tert-butylsalicylate, Li-acetylsalicylic acid, and combinations thereof.

3. The scintillator as recited in claim 2 , wherein the scintillator material is optically transparent.

4. The scintillator as recited in claim 2 , wherein the primary fluor is 2,5-diphenyloxazole (PPO).

5. The scintillator as recited in claim 2 , further comprising a coordinating solvent, wherein the Li-containing compound is soluble in the coordinating solvent.

6. The scintillator as recited in claim 5 , wherein the coordinating solvent is selected from a group consisting of: acetone, methanol, and dimethoxyethane.

7. The scintillator as recited in claim 2 , further comprising a secondary fluor, wherein the secondary fluor has a longer wavelength than the primary fluor.

8. The scintillator as recited in claim 7 , wherein the secondary fluor is present in an amount of less than 2 wt %.

9. The scintillator as recited in claim 7 , wherein the secondary fluor is selected from a group consisting of: 9,10-diphenylanthracene and p-bis-(o-methylstyryl)-benzene.

10. The scintillator as recited in claim 2 , wherein the scintillator material comprises a polymer matrix.

11. The scintillator as recited in claim 10 , wherein the polymer matrix includes one or more aromatic groups.

12. The scintillator as recited in claim 10 , wherein the polymer matrix is selected from a group consisting of: polystyrene, polyvinyltoluene, and poly(methylmethacrylate).

13. The scintillator as recited in claim 10 , wherein the polymer matrix comprises an initiator and a cross-linker, wherein the initiator is present in an amount ranging from about 0.001 wt % to about 1 wt %, and wherein the cross-linker is present in an amount ranging from about 0.05 wt % to about 5 wt %.

14. The scintillator as recited in claim 2 , wherein the scintillator material comprises a liquid scintillator material.

15. The scintillator as recited in claim 14 , wherein the liquid scintillator material includes one or more aromatic groups.

16. The scintillator as recited in claim 14 , wherein the liquid scintillator material includes a xylene-based liquid.

17. A system comprising:
the scintillator of claim 2 ; and
a photodetector for detecting the response of the scintillator to at least one or neutron and gamma ray irradiation.

18. A method for fabricating a scintillator, the method comprising:
forming a precursor mixture; and
heating the precursor mixture until a polymerization process is complete,
wherein the precursor mixture comprises:
a monomer;
one or more fluors;
a coordinating solvent; and
a Li-containing compound selected from a group consisting of: Li-3-phenylsalicylate, Li-3,5-di-tert-butylsalicylate, Li-acetylsalicylic acid, and combinations thereof,
wherein the Li-containing compound is soluble in at least one of the one or more fluors.

Assignees

• L Livermore Nat Security Llc

Inventors

• Zaitseva Natalia P
• Carman M Leslie
• Faust Michelle A
• Glenn Andrew M
• Martinez H Paul
• Payne Stephen A

Classifications

• C09K2211/1011

  Condensed systems · CPC title

• C09K11/06

  containing organic luminescent materials · CPC title

• C09K2211/1018

  Heterocyclic compounds · CPC title

• G01T3/06

  with scintillation detectors · CPC title

• G21K4/00

  Conversion screens for the conversion of the spatial distribution of X-rays or particle radiation into visible images, e.g. fluoroscopic screens (photographic processes using X-ray intensifiers G03C5/17; discharge tubes comprising luminescent screens H01J1/62; cathode ray tubes for X-ray conversion with optical output H01J31/50) · CPC title