Scintillation compositions and related hydrogels for neutron and gamma radiation detection, and related detection systems and methods

Patent metadata

Field	Value
Publication number	US-2025020815-A1
Application number	US-202418422242-A
Country	US
Kind code	A1
Filing date	Jan 25, 2024
Priority date	Jan 25, 2023
Publication date	Jan 16, 2025
Grant date	—

Abstract

Scintillation compositions comprising one or more different types of quantum dots dispersed in a polymer matrix material, the quantum dots having a core-shell structure, and optionally a neutron-capturing isotope. Hydrogels comprising the quantum dots and optional neutron-capturing isotope in a polymerized matrix are also disclosed, as are related detection systems and methods.

First claim

What is claimed is:

1 . A scintillation composition comprising one or more different types of quantum dots dispersed in a polymer matrix material, the quantum dots comprising a core-shell structure.

2 . The scintillation composition of claim 1 , wherein the one or more different types of quantum dots comprise a narrow band gap semiconductor material and a wide band gap semiconductor material.

3 . The scintillation composition of claim 1 , wherein the one or more different types of quantum dots comprise CuF, CuCl, CuBr, CuI, AgF, AgCl, AgBr, AgI, CdO, CdSe, CdS, CdTe, CdZnTe, HgO, HgS, HgSe, HgTe, BeO, BeS, BeSe, BeTe, MgO, MgS, MgSe, MgTe, CdSeTe, ZnO, ZnSe, ZnTe, ZnS, ZnCdSe, ZnCdS, InAs, InP, InN, GaN, InSb, InAsP, InGaAs, GaAs, GaP, GaSb, AIP, AlN, AIAs, AlSb, BP, BaS, BSb, PbSe, PbTe, PbS, PbSnTe, Tl 2 SnTe 5 , GeS, GeSe, SnS, SnSe, GeTe, SnTe, PbO, CuInS, CuInSe, CuInTe, AgInS, AgInSe, AgInTe, SbSI, SbSBr, SbSeI, SbSeBr, SbTeI, BiSCl, BiSBr, BiSeCl, BiSeBr, BiSeI, CuInGaS, CuInGaSe, CuInGaTe, CuInS 2 , CuInSe 2 , CuInTe 2 , CuGaS 2 , CuGaSe 2 , CuAlSe 2 , CuGaTe 2 , CuAlTe 2 , AgInGaS, AgInGaSe, AgInGaTe, AgInS 2 , AgInSe 2 , AgInTe 2 , AgGaS 2 , AgGaSe 2 , AgAlSe 2 , AgGaTe 2 , AgAlTe 2 , or combinations thereof.

4 . The scintillation composition of claim 1 , wherein the one or more different types of quantum dots comprise a core comprising one or more of Cd, Se, In, and P, and a shell comprising one or more of Zn and S.

5 . The scintillation composition of claim 1 , wherein the polymer matrix material comprises acrylamide, bis-acrylamide, N,N-methylene bisacrylamide, poly(N-vinylcarbazole), silicone, non-plasticizing silicone gel, two-part components of a polyurethane, or combinations thereof.

6 . The scintillation composition of claim 1 , further comprising a neutron-capturing isotope.

7 . The scintillation composition of claim 1 , further comprising one or more of thallium doped cesium iodide, thallium doped sodium iodide, and cerium doped lutetium iodide.

8 . A hydrogel comprising a polymerized matrix material and one or more different types of quantum dots in the polymer matrix material.

9 . The hydrogel of claim 8 , wherein the one or more different types of quantum dots comprise CuF, CuCl, CuBr, CuI, AgF, AgCl, AgBr, AgI, CdO, CdSe, CdS, CdTe, CdZnTe, HgO, HgS, HgSe, HgTe, BeO, BeS, BeSe, BeTe, MgO, MgS, MgSe, MgTe, CdSeTe, ZnO, ZnSe, ZnTe, ZnS, ZnCdSe, ZnCdS, InAs, InP, InN, GaN, InSb, InAsP, InGaAs, GaAs, GaP, GaSb, AIP, AlN, AIAs, AlSb, BP, BaS, BSb, PbSe, PbTe, PbS, PbSnTe, Tl 2 SnTe 5 , GeS, GeSe, SnS, SnSe, GeTe, SnTe, PbO, CuInS, CuInSe, CuInTe, AgInS, AgInSe, AgInTe, SbSI, SbSBr, SbSeI, SbSeBr, SbTeI, BiSCl, BiSBr, BiSeCl, BiSeBr, BiSeI, CuInGaS, CuInGaSe, CuInGaTe, CuInS 2 , CuInSe 2 , CuInTe 2 , CuGaS 2 , CuGaSe 2 , CuAlSe 2 , CuGaTe 2 , CuAlTe 2 , AgInGaS, AgInGaSe, AgInGaTe, AgInS 2 , AgInSe 2 , AgInTe 2 , AgGaS 2 , AgGaSe 2 , AgAlSe 2 , AgGaTe 2 , AgAlTe 2 , or combinations thereof.

10 . The hydrogel of claim 8 , wherein the one or more different types of quantum dots comprise a core-shell structure.

11 . The hydrogel of claim 10 , wherein the one or more different types of quantum dots comprise a core comprising one or more of Cd, Se, In, and P, and a shell comprising one or more of Zn and S.

12 . The hydrogel of claim 8 , further comprising a neutron-capturing isotope.

13 . The hydrogel of claim 12 , wherein the neutron-capturing isotope is 6 Li, 10 B, 113 Cd, or 157 Gd.

14 . The hydrogel of claim 8 , wherein the polymerized matrix material comprises acrylamide, bis-acrylamide, N,N-methylene bisacrylamide, poly(N-vinylcarbazole), silicone, non-plasticizing silicone gel, two-part components of a polyurethane, or combinations thereof; and the polymer matrix material is polymerized with ammonium persulfate, N,N,N′,N′-tetramethylethylenediamine (TEMED), or a combination thereof.

15 . The hydrogel of claim 8 , wherein the hydrogel is rigid and substantially maintains its shape.

16 . A detection system comprising:
an enclosure, at least one photomultiplier tube in the enclosure, and a hydrogel in proximity to the at least one photomultiplier tube, the hydrogel of the detection system configured to detect at least one of neutron radiation and gamma radiation, and the hydrogel comprising:
one or more different types of quantum dots and a polymerized matrix material.

17 . The detection system of claim 16 , wherein the detection system has an active volume of about 1 m 3 or less.

18 . The detection system of claim 16 , wherein the hydrogel further comprises a neutron-capturing isotope.

19 . A method of detecting radiation emitting from an article, comprising:
positioning an article emitting one or more of neutron radiation and gamma radiation proximal to a hydrogel in a detection system, the hydrogel comprising a polymerized matrix material comprising one or more different types of quantum dots and an optional neutron-capturing isotope; and detecting the one or more of the neutron radiation and gamma radiation.

20 . The method of claim 19 , wherein positioning an article emitting one or more of neutron radiation and gamma radiation proximal to a hydrogel comprises positioning the article proximal to the hydrogel comprising quantum dots having a core-shell structure, wherein the core comprises one or more of Cd, Se, In, and P, and the shell comprises one or more of Zn and S.

Assignees

• Battelle Energy Alliance Llc

Inventors

• Riddle Catherine L
• Scates Dawn M
• Fronk Ryan G
• Demmer Rick L
• Ghosh Priyarshini

Classifications

• C09K11/025

  non-luminescent particle coatings or suspension media · CPC title

• C09K11/02

  Use of particular materials as binders, particle coatings or suspension media therefor · CPC title

• C09K11/883

  with zinc or cadmium · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• G01T1/2042 Primary

  Composition for liquid scintillation systems · CPC title