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Production method for dodecacarbonyl triruthenium
US9266916B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9266916-B2 |
| Application number | US-201414655076-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 20, 2014 |
| Priority date | Jan 21, 2013 |
| Publication date | Feb 23, 2016 |
| Grant date | Feb 23, 2016 |
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Abstract
Official abstract text for this publication.
The present invention is a method for producing dodecacarbonyl triruthenium (DCR) including a process of carbonylating ruthenium chloride with carbon monoxide, in which an amine is added to a reaction system at 0.8 molar equivalent or more with respect to chlorine of the ruthenium chloride and the carbonylation is conducted at a reaction temperature of 50 to 100° C. and a reaction pressure of 0.2 to 0.9 MPa. According to the present invention, it is possible to produce dodecacarbonyl triruthenium having less residual impurity metals without applying a reaction condition of a high pressure.
First claim
Opening claim text (preview).
The invention claimed is: 1. A method for producing dodecacarbonyl triruthenium having the following Formula, the method comprising a process of carbonylating ruthenium chloride with carbon monoxide, wherein an amine is added to a reaction system at 0.8 molar equivalent or more with respect to chlorine of the ruthenium chloride and the carbonylation is conducted at a reaction temperature of 50 to 100° C. and a reaction pressure of 0.2 to 0.9 MPa 2. The method for producing dodecacarbonyl triruthenium according to claim 1 , wherein an amine to be added is an amine having 3 to 36 carbon atoms. 3. The method for producing dodecacarbonyl triruthenium according to claim 1 , wherein a reaction time is 10 to 30 hours. 4. The method for producing dodecacarbonyl triruthenium according to claim 1 , wherein ruthenium chloride is a ruthenium chloride solution including ruthenium chloride and an organic solvent, and the organic solvent is methanol, ethanol, propanol and butanol. 5. The method for producing dodecacarbonyl triruthenium according to claim 4 , wherein the organic solvent is an organic solvent having a water content of 5% by mass or less. 6. The method for producing dodecacarbonyl triruthenium according to claim 2 , wherein a reaction time is 10 to 30 hours. 7. The method for producing dodecacarbonyl triruthenium according to claim 2 , wherein ruthenium chloride is a ruthenium chloride solution including ruthenium chloride and an organic solvent, and the organic solvent is methanol, ethanol, propanol and butanol. 8. The method for producing dodecacarbonyl triruthenium according to claim 3 , wherein ruthenium chloride is a ruthenium chloride solution including ruthenium chloride and an organic solvent, and the organic solvent is methanol, ethanol, propanol and butanol.
Assignees
Inventors
Classifications
- C07F15/0046Primary
Ruthenium compounds · CPC title
characterized by the use of precursors specially adapted for ALD · CPC title
Carbonyls · CPC title
from metal carbonyl compounds · CPC title
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- What does patent US9266916B2 cover?
- The present invention is a method for producing dodecacarbonyl triruthenium (DCR) including a process of carbonylating ruthenium chloride with carbon monoxide, in which an amine is added to a reaction system at 0.8 molar equivalent or more with respect to chlorine of the ruthenium chloride and the carbonylation is conducted at a reaction temperature of 50 to 100° C. and a reaction pressure of 0…
- Who is the assignee on this patent?
- Tanaka Precious Metal Ind
- What technology area does this patent fall under?
- Primary CPC classification C07F15/0046. Mapped technology areas include Chemistry & Metallurgy.
- When was this patent published?
- Publication date Tue Feb 23 2016 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
- What related patents are in patentsdb?
- We list 8 related publications on this page (citations in our corpus or others sharing the same primary CPC).