Precursors and transport methods for hydrothermal liquid phase sintering (HLPS)

Patent metadata

Field	Value
Publication number	US-9266147-B2
Application number	US-201314041869-A
Country	US
Kind code	B2
Filing date	Sep 30, 2013
Priority date	Oct 1, 2012
Publication date	Feb 23, 2016
Grant date	Feb 23, 2016

Abstract

A method of producing a monolithic ceramic body from a porous matrix includes providing a porous matrix having interstitial spaces, providing an infiltrating medium comprising a solvent and at least one reactive species, and infiltrating at least a portion of the interstitial space of the porous matrix with the infiltrating medium. The solvent is an inert medium that is not chemically reactive with the porous matrix, and is in a liquid phase when in the portion of the interstitial space of the porous matrix. The infiltrating medium is mechanically convected through the porous matrix. The at least one reactive species, when in a portion of the interstitial space of the porous matrix, reacts with a portion of the porous matrix to form a product, and the product fills at least a portion of the interstitial space.

First claim

What is claimed is:

1. A method of producing a monolithic ceramic body from a porous matrix, comprising:
providing a porous matrix having interstitial spaces, wherein the porous matrix further comprising a deliquescent solid;
providing an infiltrating medium comprising a solvent and at least one reactive species; wherein the solvent is an inert medium that is not chemically reactive with the porous matrix;
infiltrating at least a portion of the interstitial space of the porous matrix with the infiltrating medium;
wherein the solvent is in a liquid phase when in the portion of the interstitial space of the porous matrix;
wherein the infiltrating medium flows through the porous matrix;
wherein the at least one reactive species, when in a portion of the interstitial space of the porous matrix, reacts with a portion of the porous matrix to form a product, wherein the product fills at least a portion of the interstitial space.

2. The method according to claim 1 , wherein the solvent and at least one reactive species are in a gaseous phase.

3. The method according to claim 1 , wherein the solvent and at least one reactive species are in a liquid phase.

4. The method according to claim 1 , wherein the solvent is in a liquid phase and the at least one reactive species is in a gaseous phase.

5. The method according to claim 1 , wherein the infiltrating medium is mechanically convected through the porous matrix.

6. The method according to claim 5 , wherein the mechanically convected comprises one of pressurized flow, capillary electro-osmotic flow, magneto-osmotic flow, and temperature- and chemical-gradient driven flow.

7. The method according to claim 1 , the monolithic ceramic body has a degree of pore saturation value of from about 15% to about 70%.

8. The method according to claim 7 , the degree of pore saturation value is about 50%.

9. A method of forming a monolithic body from a porous matrix comprising:
providing a porous matrix having interstitial spaces;
introducing a deliquescent solid into at least a portion of the interstitial spaces of the porous matrix;
infiltrating at least a portion of the porous matrix with an infiltrating medium, wherein the infiltrating medium comprises a solvent and at least one reactive species, wherein the solvent is an inert medium that is not chemically reactive with the porous matrix, and wherein the solvent contacts the deliquescent solid;
wherein the at least one reactive species, when in a portion of the interstitial space of the porous matrix, reacts with a portion of the porous matrix to form a product, wherein the product fills at least a portion of the interstitial space.

10. The method according to claim 9 , wherein the solvent and at least one reactive species are in a gaseous phase.

11. The method according to claim 9 , wherein the solvent and at least one reactive species are in a liquid phase.

12. The method according to claim 9 , wherein the solvent is in a liquid phase and the at least one reactive species is in a gaseous phase.

13. The method according to claim 9 , wherein the infiltrating at least a portion of the porous matrix with an infiltrating medium further comprises mechanically convecting the infiltrating medium through the porous matrix.

14. The method according to claim 13 , wherein the mechanically convecting comprising one of pressurized flow, electro-osmotic flow, magneto-osmotic flow, or temperature- and chemical-gradient driven flow.

15. The method according to claim 9 , the monolithic ceramic body has a degree of pore saturation value of from about 15% to about 70%.

16. The method according to claim 15 , the degree of pore saturation value is about 50%.

17. The method according to claim 9 , wherein, after the solvent contacts the deliquescent solid, the solvent and the deliquescent solid are in a liquid phase.

Assignees

• Univ Rutgers

Inventors

• Riman Richard E
• Atakan Vahit
• Kuppler John P
• Smith Kenneth M

Classifications

• C04B35/057

  based on calcium oxide · CPC title

• B05D7/22 Primary

  to internal surfaces, e.g. of tubes · CPC title

• C04B2235/608

  Green bodies or pre-forms with well-defined density · CPC title

• C04B2235/3454

  Calcium silicates, e.g. wollastonite · CPC title

• C04B2235/77

  Density · CPC title