Precursor sol-gel solution, electromechanical transducer element, liquid droplet discharge head, and inkjet recording apparatus
US-2015307403-A1 · Oct 29, 2015 · US
US9175397B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9175397-B2 |
| Application number | US-201113048251-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 15, 2011 |
| Priority date | Mar 15, 2010 |
| Publication date | Nov 3, 2015 |
| Grant date | Nov 3, 2015 |
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A method of synthesizing multilayer heterostructures including an inorganic oxide layer residing on a solid substrate is described. Exemplary embodiments include producing an inorganic oxide layer on a solid substrate by a liquid coating process under relatively mild conditions. The relatively mild conditions include temperatures below 225° C. and pressures above 9.4 mb. In an exemplary embodiment, a solution of diethyl aluminum ethoxide in anhydrous diglyme is applied to a flexible solid substrate by slot-die coating at ambient atmospheric pressure, and the diglyme removed by evaporation. An AlO x layer is formed by subjecting material remaining on the solid substrate to a relatively mild oven temperature of approximately 150° C. The resulting AlO x layer exhibits relatively high light transmittance and relatively low vapor transmission rates for water. An exemplary embodiment of a flexible solid substrate is polyethylene napthalate (PEN). The PEN is not substantially adversely affected by exposure to 150° C.
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We claim: 1. A method comprising: providing an organometallic solution, the organometallic solution including an organometallic compound dissolved in a complexing solvent; distributing the organometallic solution on a solid substrate, wherein the solid substrate comprises an organic polymer and the distributing is by a first liquid coating process; removing the complexing solvent; and curing the organometallic compound to form a metallic oxide from the organometallic compoun…
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