Sintered cobalt ferrites composite material with high magnetostriction

Patent metadata

Field	Value
Publication number	US-9263174-B2
Application number	US-201314372644-A
Country	US
Kind code	B2
Filing date	Jan 17, 2013
Priority date	Jan 17, 2012
Publication date	Feb 16, 2016
Grant date	Feb 16, 2016

Abstract

Disclosed herein is a sintered cobalt ferrite composite material comprising of nano and micron sized powders of cobalt ferrite with high magnetostriction. The present invention further discloses preparation of nano and micron sized powders of cobalt ferrite, in particular, the auto combustion process using glycine as fuel for preparing nano sized cobalt ferrite powders.

First claim

We claim:

1. Sintered cobalt ferrite composite material comprising of nano and/or micron sized powders of cobalt ferrite, wherein particle size of the nano sized powder of cobalt ferrite powder is in the range 3 to 40 nm and particle size of micron sized powder of cobalt ferrite is in the range of 1 to 10 μm, wherein the ratio of nano sized powder of cobalt ferrite to the micron sized powder of cobalt ferrite in said composite is in the ratio ranging between 70:30 to 95:5, and the ratio of nano-nano sized powder of cobalt ferrite in said composite is in the ratio ranging between 90:10 to 50:50 wherein said composite material has density in the range of 79-84% compared to theoretical density and magnetostriction is in the range of 240-400 ppm.

2. The sintered cobalt ferrite composite material according to claim 1 , wherein the grain size of the sintered composite is in the range of 1 to 10 μm.

3. A process for preparation of sintered cobalt ferrite composite material as claimed in claim 1 , wherein said process comprising the steps of:
a. dissolving cobalt nitrate (Co(NO 3 ) 2 . 6H 2 O ) and Ferric nitrate (Fe(NO 3 ) 3 .9H 2 O) in the molar ratio ranging between 1:1.5 to 1:2 in minimum amount of distilled water;
b. adding glycine solution in minimum amount of water with solution of step (a) wherein the metal ion to glycine is in the molar ratio of 1:0.125 to 1:1.25 followed by mixing to obtain a uniform solution;
c. evaporating the solution of step (c) on a hot plate at temperature in the range of 180 to 220°C. to obtain the thick mass which is burnt spontaneously to obtain nano sized cobalt ferrite powder;
d. mixing CoCO 3 and Fe 2 O 3 in the molar ratio ranging between 1:1.5 to 1:2 followed by heating at temperature in the range of 900 to 1100° C. for period in the range of 11to 13 hours;
e. grinding immediately the mixture as obtained in step (d) followed by heating for period in the range of 23 to 25 hrs at temperature in the range of 900 to 1100° C.;
f. heating the resulting powder at temperature in the range of 1000 to 1100° C. for period in the range of 70 to 72 hours with two intermediate grindings to obtain micron sized cobalt ferrite powder;
g. mixing nano sized powder of cobalt ferrite as obtained in step (c) and micron sized powder of cobalt ferrite as obtained in step (f) in the ratio ranging between 70:30 to 95:5 to obtain mixture or mixing nano-nano sized powder of cobalt ferrite of step (c) in the ratio ranging between 90:10 to 50:50;
h. pressing the mixture as obtained in step (g) to obtain pellets; and
i. sintering the pellets as obtained in step (h) at a temperature in the range of 1200-1500° C. for period in the range of 5 to 60 minutes to obtain sintered cobalt ferrite composite material.

4. The process as claimed in claim 3 , wherein sintered pellets of nano sized cobalt ferrite powder has magnetostriction in the range of 200 to 310 ppm.

5. The sintered cobalt ferrite composite material according to claim 1 , wherein nano sized cobalt ferrite powder is prepared by an auto combustion process using glycine as a fuel, wherein the metal ion to glycine is in a molar ratio of 1:0.125 to 1:1.25.

6. A process for preparation of nano sized cobalt ferrite powder of claim 1 , comprising dual sintering of nano sized cobalt ferrite powder prepared by auto combustion process, said process comprising;
a. mixing metal ion, glycine in a molar ratio of 1:0.25 and subjecting to auto combustion followed by cold uniaxial pressing to form the pellets and
b. dual sintering at temperature in the range of 1100 to 1500° C., cooling, heating at lower temperature in the range of 1000-1400 ° C. for a period in the range of 10 to 60 hours to obtain dual sintered cobalt ferrite composites.

Assignees

• Council Scient Ind Res

Inventors

• Pattayil Alias Joy
• Khaja Mohaideen Kamal

Classifications

• C01P2002/60

  Compounds characterised by their crystallite size · CPC title

• B82Y25/00

  Nanomagnetism, e.g. magnetoimpedance, anisotropic magnetoresistance, giant magnetoresistance or tunneling magnetoresistance · CPC title

• C04B2235/781

  Nanograined materials, i.e. having grain sizes below 100 nm · CPC title

• C04B35/64

  Burning or sintering processes (C04B33/32 takes precedence {; powder metallurgy B22F}) · CPC title

• C04B35/6261

  Milling · CPC title