Process for producing nanoparticles and their use in the production of high-temperature superconductors

Patent metadata

Field	Value
Publication number	US-9257628-B2
Application number	US-201314386534-A
Country	US
Kind code	B2
Filing date	Mar 20, 2013
Priority date	Mar 21, 2012
Publication date	Feb 9, 2016
Grant date	Feb 9, 2016

Abstract

Known processes for the production of nanoparticles of compounds of the transition metals Zr, Ti, Ta, rare earths (RE), Mn, and Fe via microemulsions lead to products that contain impurities from the reactants, particularly water, which make the further use of said nanoparticles difficult, for instance in high-temperature super conductors (HTSC). It is proposed that the nanoparticles be produced via anhydrous microemulsions having an outer phase composed of a nonpolar solvent and inner phase composed of a polar anhydrous solvent. The nanoparticles thus obtained exhibit good monodispersity and can be used in the production of REBa 2 Cu 3 O 7 super conductors by incorporation into the precursor coating solution.

First claim

The invention claimed is:

1. A process for producing nanoparticles comprising a compound comprising a metal, the process comprising:
preparing a w/o microemulsion with at least one precursor of the metal in a dispersed polar phase with an aid of a surfactant, and
adding a precipitant to a continuous nonpolar phase, wherein the metal is a transition metal Zr, Hf, Ti, Ta, Sc, Y or La, an element with an atomic number 58 (Ce) to 71 (Lu), Mn, or Fe,
a solvent for the at least one precursor in the dispersed polar phase is a polar solvent having a water content of <1 mol-% and
the precipitant in the continuous nonpolar phase is a base.

2. The process according to claim 1 ,
wherein the compound is an oxide of the transition metal and/or a hydroxide of the transition metal.

3. The process according to claim 1 ,
wherein the dispersed polar phase comprises precursors of several metals.

4. The process according to claim 1 ,
wherein the polar solvent is an alkyl nitrile or aryl nitrile.

5. The process according to claim 1 ,
wherein the precipitant is added as a solution or in dilution.

6. The process according to claim 1 ,
wherein the precipitant is a short-chain organic amine.

7. The process according to claim 6 ,
wherein the precipitant is a C1 to C6 amine.

8. The process according to claim 1 ,
wherein the continuous nonpolar phase comprises a nonpolar alkane solvent having 6 to 10 carbon atoms.

9. The process according to claim 1 ,
wherein the at least one precursor is a nitrate, chloride and/or oxide chloride of the transition metal.

10. The process according to claim 1 , further comprising:
separating the nanoparticles from the continuous nonpolar phase and
drying the nanoparticle.

11. The process according to claim 1 ,
wherein the surfactant is a nonionic surfactant.

12. A process for producing a high temperature superconductor material comprising a mixed copper oxide, the process comprising:
incorporating nanoparticles produced by the process of claim 1 into the mixed copper oxide of a high temperature superconductor, and
forming the high temperature superconductor material by applying a solution of at least one precursor of mixed copper oxide components to a substrate together with or separately from the nanoparticles and by carrying out a thermal treatment.

13. The process according to claim 12 ,
wherein the at least one precursor of the mixed copper oxide components is applied in a third solvent to the substrate.

14. The process according to claim 12 ,
wherein the mixed copper oxide is a rare earth metal- barium-copper oxide.

15. The process according to claim 12 ,
wherein a precursor solution for the mixed copper oxide is mixed with at least one suspension of the nanoparticles in the continuous nonpolar phase to form a hybrid solution.

16. The process according to claim 12 ,
wherein the third solvent is at least one selected from the group consisting of aliphatic alcohol, ketone and carboxylic acid, each having 4 to 12 carbon atoms.

17. A layer arrangement comprising a high temperature superconductor layer produced in the process according to claim 12 .

Assignees

• Basf Se

Inventors

• Freudenberg Thomas
• Holzapfel Bernhard
• Brunkahl Oliver
• Baecker Michael

Classifications

• C04B2235/449

  Organic acids, e.g. EDTA, citrate, acetate, oxalate · CPC title

• C01G3/006

  Compounds containing copper, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• C01B13/328

  by processes making use of emulsions, e.g. the kerosine process · CPC title

• C04B2235/445

  Fluoride containing anions, e.g. fluosilicate · CPC title

• C04B2235/443

  Nitrates or nitrites · CPC title