Topography minimization of neutral layer overcoats in directed self-assembly applications
US-9147574-B2 · Sep 29, 2015 · US
US9250533B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9250533-B2 |
| Application number | US-200913060203-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 23, 2009 |
| Priority date | Aug 20, 2008 |
| Publication date | Feb 2, 2016 |
| Grant date | Feb 2, 2016 |
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The method of fabricating a multi-level, metallic microstructure includes the steps consisting in structuring a first layer of photosensitive resin so as to obtain a first level of a resin mould, the aperture in the first resin layer revealing a conductive surface of a substrate, structuring a second photosensitive resin layer over the first level of a resin mould so as to obtain a multi-level resin mould, the apertures in the multi-level mould revealing the conductive surface of the substrate, galvanically depositing a metal or alloy in the apertures of the multi-level resin mould and separating a multi-level metallic structure formed by the metal or alloy deposited in the apertures from the substrate and the multi-level resin mould.
Opening claim text (preview).
The invention claimed is: 1. A method of fabricating a multi-level, metallic microstructure by a UV photolithographic and galvanic deposition technique, wherein it includes the steps of: a) providing a top planar substrate that has a conductive surface; b) covering the top planar conductive surface with a first layer of photosensitive resin; c) irradiating the first layer of photosensitive resin through a mask that matches a desired pattern cavity; d) developing the first layer so as to hollow out apertures therein and thus obtain a first level of a resin mould, the apertures in the first resin layer revealing the conductive surface of the top planar substrate; e) depositing a second layer of photosensitive resin over the first developed layer of photosensitive resin and the revealed top planar conductive surface of the substrate, so as to cover the first developed layer of photosensitive resin and the revealed top planar conductive surface and, to fill the apertures of the first developed layer of photosensitive resin; f) irradiating the second photosensitive resin layer through a mask that matches a desired pattern cavity; g) developing the second photosensitive resin layer so as to hollow out apertures therein and to obtain a multi-level resin mould, the apertures in the multi-level mould formed by the developed first and second resin layers, revealing the top planar conductive surface of the substrate; h) galvanically depositing a metal or alloy in the apertures of the multi-level resin mould formed by the developed first and second resin layers; i) separating the substrate, then removing the first and second resin layers so as to reveal the multi-level metallic structure formed by the metal or alloy deposited in the apertures. 2. The method according to claim 1 , wherein, after step b), the method includes the step of forming a partially opened conductive surface on the first photosensitive resin layer. 3. The method according to claim 1 , wherein, after step c), the method includes the step of forming a partially opened conductive surface on the first layer of photosensitive resin. 4. The method according to claim 1 , wherein, after step d), the method includes the step of forming a conductive surface on the remaining parts of the surface of resin layer developed in the preceding step. 5. The method according to claim 1 , wherein, after step g), the method includes the step of forming a conductive surface at the bottom of the apertures. 6. The method according to claim 1 , wherein once step g) is completed, steps e) to g) are repeated prior to passing to step h) so as to add an additional layer to the multi-level mould. 7. The method according to claim 1 , wherein the conductive surfaces of the substrate are formed of a stack of chromium and gold layers. 8. The method according to claim 1 , wherein, after step h), the method further includes a step that consists in flattening the deposited metal or alloy and the multi-level resin mould to make the multi-level resin mould and the deposited metal or alloy the same level. 9. The method according to claim 1 , wherein the photosensitive resin deposited in step e) is a “solid” resin and it is applied by lamination.
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After-treatment (C23C2/14 takes precedence) · CPC title
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