Composition for soft skins and uses thereof

Patent metadata

Field	Value
Publication number	US-9862819-B2
Application number	US-201615175396-A
Country	US
Kind code	B2
Filing date	Jun 7, 2016
Priority date	Jun 12, 2015
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

A composition is disclosed, comprising a block copolymer, at least one homopolymer or copolymer of butene, and at least one olefin homopolymer or copolymer, wherein said block copolymer has hydrogenated low-vinyl polybutadiene end blocks with a specific gravity>0.85 g/cc, and a controlled distribution midblock of polyalkenyl arene/hydrogenated diene. Although the block copolymer has a preferred linear structure as a triblock copolymer, it may also be branched or radial coupled copolymer that has at least 2 arms or more. The composition is useful for rotational molding, slush molding, injection molding, extrusion or compression molding, or thermoforming or calendering for making articles that are resistant to chemicals such as diesel fuel, for the automotive market, for example. The MFR of the block copolymer is 1 to about 50 g/10 min. at 230° C., with a wt. of 2.16 kg.

First claim

What is claimed is:

1. A composition for producing an article by rotational molding or slush molding or injection molding or extrusion or compression molding or thermoforming or calendering, comprising:
from about 50 to about 70 wt. % block copolymer;
from about 15 to about 25 wt. % of at least one homopolymer or copolymer of butene; and
from about 12 to about 24 wt. % of at least one polyolefin homopolymer or polyolefin copolymer;
wherein said block copolymer has hydrogenated low-vinyl polybutadiene end blocks with a specific gravity>0.85 g/cc, and has a controlled distribution midblock of polyalkenyl arene/hydrogenated diene and wherein said composition total wt. equals 100 wt. %.

2. The composition of claim 1 , wherein said block copolymer has the structure of C-A/B-C or (C-A/B) n X wherein C is a hydrogenated, low vinyl, semi-crystalline polybutadiene block, AB is a controlled distribution polymer midblock of monalkenyl arene and butadiene having an elevated vinyl content, X is the residue of a coupling agent and n is from 2 to 6.

3. The composition of claim 1 , wherein said polyolefin homopolymer or polyolefin copolymer is polypropylene, high density polyethylene, medium density polyethylene, low density polyethylene, linear low density polyethylene, polyethylene copolymers, polypropylene copolymers, polybutene copolymers, or a mixture of 2 or more of these.

4. The composition of claim 1 , wherein said polyalkenyl arene is selected from the group of styrene, alpha methylstyrene, o-methylstyrene, p-methylstyrene, vinyl toluene, vinyl naphthalene, para-butyl styrene, or a mixture of 2 or more of these.

5. The composition of claim 4 , wherein said hydrogenated diene is selected from the group of hydrogenated butadiene, hydrogenated isoprene or a mixture of these.

6. The composition of claim 4 , wherein said block copolymer is C-S/EB-C, where C is hydrogenated, low vinyl, semi-crystalline polybutadiene, and S/EB is a controlled distribution polymer midblock of styrene and hydrogenated butadiene.

7. The composition of claim 1 , further including about 0.3 to about 3 wt. % of at least one stabilizer.

8. The composition of claim 6 , wherein said block copolymer has a melt flow index of about 1 to about 50 g/10 min. at 230° C., with a wt. of 2.16 kg.

9. The composition of claim 1 , wherein said composition has a melt flow rate range of 5 to 400 g/10 min. at 230° C. and 2.16 kg.

10. A process for making an article, comprising:
rotational molding, injection molding, extrusion, calendaring, thermoforming, or slush molding an article from a composition, comprising:
from about 50 to about 70 wt. % block copolymer;
from about 15 to about 25 wt. % of at least one homopolymer or copolymer of butene; and
from about 12 to about 24 wt. % of at least one polyolefin homopolymer or copolymer ;
wherein said block copolymer has hydrogenated low-vinyl polybutadiene end blocks with a specific gravity>0.85 g/cc, and has a controlled distribution midblock of polyalkenyl arene/hydrogenated diene and wherein said composition total wt. equals 100 wt. % and the composition is melt mixed prior to said step of rotational molding or slush molding or injection molding or extrusion or calendaring.

11. A process for making an article of claim 10 , wherein said polyolefin homopolymer or polyolefin copolymer is polypropylene, high density polyethylene, medium density polyethylene, low density polyethylene, linear low density polyethylene, polyethylene copolymers, polypropylene copolymers, polybutene copolymers, or a mixture of 2 or more of these.

12. The process for making an article according to claim 10 , wherein said polyalkenyl arene is selected from the group of styrene, alpha methylstyrene, o-methylstyrene, p-methylstyrene, vinyl toluene, vinyl naphthalene, para-butyl styrene, or a mixture of 2 or more of these.

13. The process for making an article according to claim 10 , wherein said hydrogenated diene is selected from the group of hydrogenated butadiene, hydrogenated isoprene or a mixture of these.

14. A process for coating a fabric, foam, or rigid sheet substrate with a composition, comprising:
coating a fabric, foam, or rigid sheet substrate by extrusion or calendering to make an article, said composition comprising:
from about 50 to about 70 wt. % block copolymer;
from about 15 to about 25 wt. % of at least one homopolymer or copolymer of butene;
from about 12 to about 24 wt. % of at least one polyolefin homopolymer or copolymer;
wherein said block copolymer has hydrogenated low-vinyl polybutadiene end blocks with a specific gravity>0.85 g/cc, and has a controlled distribution midblock of polyalkenyl arene/hydrogenated diene and wherein said composition total wt. equals 100 wt. % and the composition is melt mixed, prior to said step of coating a fabric, foam, or rigid sheet substrate.

15. A process for coating a fabric, foam, or rigid sheet substrate according to claim 14 , wherein said polyolefin homopolymer or polyolefin copolymer is polypropylene, high density polyethylene, medium density polyethylene, low density polyethylene, linear low density polyethylene, polyethylene copolymers, polypropylene copolymers, polybutene copolymers, or a mixture of 2 or more of these.

16. A process for coating a fabric, foam, or rigid sheet substrate according to claim 15 , wherein said polyalkenyl arene is selected from the group of styrene, alpha methylstyrene, o-methylstyrene, p-methylstyrene, vinyl toluene, vinyl naphthalene, para-butyl styrene, or a mixture of 2 or more of these.

17. A process for coating a fabric, foam, or rigid sheet substrate according to claim 15 , wherein said hydrogenated diene is selected from hydrogenated butadiene, hydrogenated isoprene or a mixture of these.

18. A process for making a molded article by injection molding, extrusion, thermoforming, rotational molding, or slush molding with a composition comprising:
from about 50 to about 70 wt. % block copolymer;
from about 15 to about 25 wt. % of at least one homopolymer or copolymer of butene;
from about 12 to about 24 wt. % of at least one polyolefin homopolymer or copolymer;
wherein said block copolymer has hydrogenated low-vinyl polybutadiene end blocks with a specific gravity>0.85 g/cc, and has a controlled distribution midblock of polyalkenyl arene/hydrogenated diene and wherein said composition total wt. equals 100 wt. % and the composition is melt mixed, prior to said step of forming the molded article.

19. An article comprising a composition, wherein the composition comprises:
(i) from about 50 to about 70 wt. %, based on the total weight of the composition, of a block copolymer, wherein said block copolymer has two end-blocks and at least one mid-block, wherein the end-blocks are hydrogenated low-vinyl polybutadiene end-blocks having a specific gravity greater than 0.85 g/cc, and the mid-block is a controlled distribution mid-block comprising a polyalkenyl arene and a hydrogenated diene; and
(ii) from about 30 to about 50 wt. %, based on the total weight of the composition, of at least one polyolefin homopolymer, a copolymer of propylene, or a copolymer of butene;
wherein total wt. % of the composition equals 100 wt. %, and wherein the composition has a melt flow rate of about 5 to about 100 g/10 min. measured at 230°C. with a 2.16 kg mass.

Assignees

• Kraton Polymers Us Llc

Inventors

• Wright Kathryn J

Classifications

• B29C48/022 Primary

  characterised by the choice of material · CPC title

• C08J9/365

  Coating · CPC title

• B29K2023/0633

  LDPE, i.e. low density polyethylene · CPC title

• B29K2025/08

  Copolymers of styrene, e.g. AS or SAN, i.e. acrylonitrile styrene (B29K2055/02 takes precedence) · CPC title

• C08J2409/00

  Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title