Zero emissions sulphur recovery process with concurrent hydrogen production

Patent metadata

Field	Value
Publication number	US-9242859-B2
Application number	US-201214115812-A
Country	US
Kind code	B2
Filing date	May 7, 2012
Priority date	May 6, 2011
Publication date	Jan 26, 2016
Grant date	Jan 26, 2016

Abstract

Disclosed is a process for the concurrent production of hydrogen and sulphur from a H 2 S-containing gas stream, with zero emissions. The method comprises the thermal oxidative cracking of H 2 S so as to form H 2 and S 2 . Preferably, the oxidation is conducted using oxygen-enriched air, preferably pure oxygen. The ratio H 2 S/O 2 in the feedstock is higher than 2:1, preferably in the range of 3:1-5:1.

First claim

The invention claimed is:

1. A method for the production of hydrogen from a feedstock comprising an H 2 S-containing gas stream and an O 2 containing gas stream, said method comprising subjecting the feedstock to thermal oxidative cracking in the absence of catalyst so as to form H 2 and S 2 , according to the reactions:
H 2 S H 2 +0.5 S 2 (dissociation or cracking reaction)  (4); and

4 H 2 S+O 2 2 H 2 +2 H 2 O+2 S 2 (H 2 formation reaction)  (5).

2. A method according to claim 1 , wherein the thermal oxidative cracking is conducted with a molar ratio H 2 S/O 2 in the feedstock higher than 2:1.

3. A method according to claim 2 , wherein the ratio H 2 S/O 2 is in the range of from 4:1 to 4.5:1.

4. A method according to claim 1 , wherein the oxygen-containing gas-stream comprises at least 40% oxygen.

5. A method according to claim 4 , wherein the oxygen-containing gas-stream contains oxygen having a purity of from 90%-100%.

6. A method according to claim 1 , wherein the thermal oxidative cracking is conducted substantially autothermally at a temperature of from 1100 to 1550° C.

7. A method according to claim 1 , comprising a further step of subjecting any formed SO 2 to hydrogenation.

8. A method according to claim 1 , wherein gas produced from the thermal oxidative cracking is, substantially without delay, quenched to a temperature below 950° C.

9. A method according to claim 8 wherein the residence time in the quench zone is from 10 ms to 300 ms.

10. A method according to claim 8 wherein the quenching is done by direct mixing with water in the final part of the reaction chamber.

11. A method according to claim 1 , wherein the thermal oxidative cracking is followed by a Claus catalytic reaction which is conducted employing a gas reheater, Claus catalytic reactor and sulphur condenser.

12. The method of claim 1 for the combined production of hydrogen and sulphur from a H 2 S-containing gas stream.

13. The method of claim 2 wherein the molar ratio H 2 S/O 2 in the feedstock is in the range 3:1 to 4.5:1.

14. The method of claim 4 wherein the oxygen-containing gas-stream comprises at least 60% oxygen.

15. The method of claim 6 wherein the thermal oxidative cracking is conducted substantially autothermally at a temperature of from 1100 to 1400° C.

16. The method of claim 8 wherein gas produced from the thermal oxidative cracking is, substantially without delay, quenched to a temperature between 750° C.-850° C.

17. The method of claim 9 wherein the residence time in the quench zone is from 10 ms to 100 ms.

18. The method of claim 17 wherein the residence time in the quench zone is from 10 ms to 50 ms.

Assignees

• Molinari Lucio
• Angelini Fabio
• Barbato Lucia
• Stamicarbon

Inventors

• Molinari Lucio
• Angelini Fabio
• Barbato Lucia

Classifications

• C01B2203/06

  Integration with other chemical processes · CPC title

• C01B17/0495

  by dissociation of hydrogen sulfide into the elements · CPC title

• C01B2203/0255

  containing a non-catalytic partial oxidation step · CPC title

• B01D53/8612 Primary

  Hydrogen sulfide · CPC title

• B01D2256/16

  Hydrogen · CPC title