Catalyst for selective oxidation of sulphur compounds

Patent metadata

Field	Value
Publication number	US-9776176-B2
Application number	US-201214396221-A
Country	US
Kind code	B2
Filing date	Apr 23, 2012
Priority date	Apr 23, 2012
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

The present invention is related to a catalyst supported for the selective oxidation of sulphur compounds of the tail gas from the Claus process or streams with an equivalent composition to elemental sulphur or sulphur dioxide (SO 2 ). It is also the object of the present invention, a process for the preparation of a catalyst of this type, as well as the process of selective oxidation of sulphur compounds to elemental sulphur using the catalyst of the invention, as well as the process of catalytic incineration of the tail gas from the Claus process using the catalyst of the present invention.

First claim

The invention claimed is:

1. A catalyst for selective oxidation or incineration of compounds containing sulphur which are contained in a gas stream, the catalyst consisting of
a support material comprising clinoptilolite and a binder or agglomerant in an amount from 0% to 99% by weight with respect to the total weight of the support material; and
a catalytically active material consisting of cobalt oxide, which is supported on said support material; the cobalt content in the catalyst being comprised from 0.05% to 2% by weight based on the total weight of the support material;

where the catalyst has the following properties:
a specific surface area, measured with nitrogen porosimetry according to the ASTM D-3663 standard year 2003, and using the BET method, comprised from 10 to 150 m 2 /g;
a pore volume, measured with mercury intrusion porosimetry according to ASTM D-4284 standard year 2003, comprised from 0.05 to 10 cc/g;
an average pore diameter, measured with mercury intrusion porosimetry according to ASTM D-4284 standard year 2003, comprised from 2 to 50 nm; and
a crush strength measured according to the ASTM D-4179 standard year 2002, higher than 29.42 N.

2. The catalyst according to claim 1 , wherein the compounds containing sulphur are hydrogen sulphide (H 2 S), carbonyl sulphide (COS), carbonyl disulphide (CS 2 ), or a combination thereof.

3. The catalyst according to claim 1 , wherein the specific surface area of the catalyst is from 20 to 140 m 2 /g.

4. The catalyst according to claim 1 , where the catalytically active material is a mixture of CoO and Co 3 O 4 in a ratio by weight of between 10:1 and 1:10.

5. The catalyst according to claim 1 , wherein the cobalt content in the catalyst is comprised from 0.1% to 2% by weight based on the total weight of the support material.

6. A catalyst for selective oxidation or incineration of compounds containing sulphur which are contained in a gas stream, the catalyst consisting of
a support material comprising clinoptilolite and a binder or agglomerant in an amount from 0% to 99% by weight with respect to the total weight of the support material; and
a catalytically active material consisting of cobalt oxide, which is supported on said support material; the cobalt content in the catalyst being comprised from 0.1% to 2% by weight based on the total weight of the support material;
where the catalyst has the following properties:
a specific surface area, measured with nitrogen porosimetry according to the ASTM D-3663 standard year 2003, and using the BET method, comprised from 10 to 150 m 2 /g;
a pore volume, measured with mercury intrusion porosimetry according to ASTM D-4284 standard year 2003, comprised from 0.05 to 10 cc/g;
an average pore diameter, measured with mercury intrusion porosimetry according to ASTM D-4284 standard year 2003, comprised from 2 to 50 nm; and
a crush strength measured according to the ASTM D-4179 standard year 2002, higher than 29.42 N.

7. Process for the preparation of the catalyst defined in claim 1 , comprising the impregnation of a solution of a cobalt salt on the surface of a support material; followed by the drying and calcination of the catalyst.

8. Process for the selective oxidation of compounds that contain sulphur, comprising contacting a gas stream containing the sulphur compounds with a gas stream containing oxygen in the presence of a catalyst defined in claim 1 ; and a gaseous effluent with a reduced content of H 2 S is recovered.

9. Process according to claim 8 , where the gas stream containing sulphur compounds is a natural gas, a gas from refinery, a synthesis gas, a tail gas from a process of recovery of sulphur or a gas from a previous partial oxidation of a gas comprising H 2 S in which a substantial portion of H 2 S was oxidized to elemental sulphur followed by the separation of the same from said elemental sulphur.

10. Process according to claim 8 , where said gas stream containing sulphur compounds comprises from 0.01 to 4% of H 2 S; and the inlet temperature of the gas stream containing the sulphur compounds is 150 to 240° C.

11. Process according to claim 10 , where the gas stream containing sulphur compounds is a tail gas from the Claus process.

12. Process according to claim 8 , where said gas stream containing sulphur compounds comprises from 0.01 to 4% of H 2 S; and the inlet temperature of the gas stream containing the sulphur compounds is 210 to 400° C.

13. Process according to claim 12 , where the gas stream containing sulphur compounds is from a gas resulting from a previous partial oxidation of a gas comprising H 2 S in which a substantial portion of H 2 S was oxidized to elemental sulphur followed by the separation of the same from said elemental sulphur.

14. Process according to claim 13 , where said previous partial oxidation is carried out according to a process for the selective oxidation of compounds that contain sulphur, comprising contacting a gas stream containing the sulphur compounds with a gas stream containing oxygen in the presence of a catalyst; and a gaseous effluent with a reduced content of H 2 S is recovered.

Assignees

• Malango Tomas M
• Zafra María Dolores
• Roldán Rafael
• Repsol Sa

Inventors

• Malango Tomas M
• Zafra María Dolores
• Roldán Rafael

Classifications

• B01J21/04 Primary

  Alumina · CPC title

• B01D53/8612

  Hydrogen sulfide · CPC title

• B01J23/75

  Cobalt · CPC title

• B01J29/072

  Iron group metals or copper · CPC title

• C10L2290/54

  Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel · CPC title