Rare earth magnet material and method for producing the same

Patent metadata

Field	Value
Publication number	US-9242296-B2
Application number	US-201013384901-A
Country	US
Kind code	B2
Filing date	Sep 10, 2010
Priority date	Oct 10, 2009
Publication date	Jan 26, 2016
Grant date	Jan 26, 2016

Abstract

A method for producing a rare earth magnet material which allows efficient Dy or the like diffusion into an inside thereof. This method includes a preparation step of preparing a powder mixture of magnet powder including one or more rare earth elements including neodymium, boron, and the remainder being iron; and neodymium fluoride powder; a heating step of heating a compact of the powder mixture and causing oxygen around magnet powder particles to react with the fluoride powder, thereby obtaining a lump rare earth magnet material in which neodymium oxyfluoride is wholly distributed. The fluoride powder traps oxygen enclosed in the powder mixture and fixes the oxygen as stable NdOF. When Dy is diffused into this rare earth magnet material, Dy smoothly enters into its inside without being oxidized at grain boundaries. Consequently, coercivity of the entire rare earth magnet material can be efficiently increased without wasting scarce Dy.

First claim

The invention claimed is:

1. A method for producing a rare earth magnet material, comprising:
a preparation step of preparing a powder mixture of:
magnet powder being powder of a magnet alloy comprising a first rare earth element (hereinafter referred to as “R1”) which is one or more rare earth elements, boron (B), and the remainder being iron (Fe) and inevitable impurities with or without a reforming element; and
fluoride powder being powder of a fluoride,
at least one of the magnet powder and the fluoride powder containing neodymium (Nd);

a heating step of heating a compact of the powder mixture, thereby obtaining a lump rare earth magnet material in which neodymium oxyfluoride which is a reaction product of oxygen or an oxide in the vicinity of particles of the magnet powder and the fluoride is distributed over all parts including not only a surface part but also an inner part thereof; and
a diffusing step of diffusing a diffusing element comprising a third rare earth element (hereinafter referred to as “R3”) which is one or more rare earth elements, from a surface to the inner part of the rare earth magnet material, wherein
the diffusing element is dysprosium (Dy) or terbium (Tb),
a ratio of fluoride powder to be mixed in the magnet powder relative to 100 atomic % of the total powder mixture is 0.1 to 10 atomic %, and
the preparing step comprises adjusting the amount of the fluoride powder to be mixed in the powder mixture in accordance with an estimated amount of oxygen atoms to be contained in the rare earth magnet material.

2. The method for producing a rare earth magnet material according to claim 1 , wherein the R1 is Nd.

3. The method for producing a rare earth magnet material according to claim 1 , wherein the fluoride powder is powder of rare earth fluoride comprising a second rare earth element (hereinafter referred to as “R2”) which is one or more rare earth elements, and fluorine (F).

4. The method for producing a rare earth magnet material according to claim 3 , wherein the R2 is Nd.

5. The method for producing a rare earth magnet material according to claim 1 , wherein the heating step is a sintering step for obtaining a sintered body of a compact of the powder mixture.

6. The method for producing a rare earth magnet material according to claim 1 , wherein the magnet powder is NdFeB powder comprising an NdFeB alloy containing 27 to 35% by mass (hereinafter referred to as %) Nd and 0.8 to 1.5% B relative to 100% of the total mass of the magnet powder, and
the fluoride powder is neodymium fluoride powder comprising neodymium fluoride.

Assignees

• Kaneko Yuji
• Takada Yukio
• Toyota Chuo Kenkyusho Kk

Inventors

• Kaneko Yuji
• Takada Yukio

Classifications

• B22F1/145

  Chemical treatment, e.g. passivation or decarburisation · CPC title

• H01F41/0246

  Manufacturing of magnetic circuits by moulding or by pressing powder (magnetic cores made by moulding or by pressing powder H01F27/255; soft magnetic particles H01F1/20, H01F1/36) · CPC title

• C22C33/0278

  with at least one alloying element having a minimum content above 5% · CPC title

• H01F41/0293

  diffusion of rare earth elements, e.g. Tb, Dy or Ho, into permanent magnets · CPC title

• H01F1/0577

  sintered · CPC title