Even tungsten etch for high aspect ratio trenches

Patent metadata

Field	Value
Publication number	US-9190293-B2
Application number	US-201414215417-A
Country	US
Kind code	B2
Filing date	Mar 17, 2014
Priority date	Dec 18, 2013
Publication date	Nov 17, 2015
Grant date	Nov 17, 2015

Abstract

Methods of evenly etching tungsten liners from high aspect ratio trenches are described. The methods include ion bombardment of a patterned substrate having high aspect ratio trenches. The ion bombardment includes fluorine-containing ions and the ion bombardment may be stopped before breaking through the horizontal liner portion outside the trenches but near the opening of the trenches. The methods then include a remote plasma etch using plasma effluents formed from a fluorine-containing precursor. Plasma effluents from the remote plasma are flowed into a substrate processing region where the plasma effluents react with the tungsten. The plasmas effluents react with exposed surfaces and remove tungsten from outside the trenches and on the sidewalls of the trenches. The plasma effluents pass through an ion suppression element positioned between the remote plasma and the substrate processing region.

First claim

The invention claimed is:

1. A method of etching tungsten, the method comprising:
transferring a patterned substrate into a substrate processing region, wherein the patterned substrate has a tungsten lining layer coating a high aspect ratio trench having a depth more than five times a width of the high aspect ratio trench, wherein the high aspect ratio trench is disposed between two adjacent stacks and one or both of the two adjacent stacks comprises at least ten alternating layers of dielectric and tungsten;
flowing a first fluorine-containing precursor into the substrate processing region while applying a bias plasma power to bombard the patterned substrate with fluorine-containing ions;
flowing a second fluorine-containing precursor into a remote plasma region fluidly coupled to a substrate processing region via perforations in a perforated plate;
forming a remote plasma in the remote plasma region to produce plasma effluents from the second fluorine-containing precursor and flowing the plasma effluents into the substrate processing region through the perforations; and
etching the tungsten lining layer, wherein, after etching the tungsten lining layer, a top sidewall thickness of the tungsten lining layer measured on a sidewall of the high aspect ratio trench near the opening of the high aspect ratio trench is within 20% of a bottom sidewall thickness of the tungsten lining layer measured on the sidewall of the high aspect ratio trench near the bottom of the high aspect ratio trench.

2. The method of claim 1 wherein the depth of the high aspect ratio trench is greater than one micron.

3. The method of claim 1 wherein the width of the high aspect ratio trench is less than one hundred nanometers.

4. The method of claim 1 wherein the operation of forming the remote plasma occurs after the operation of applying a bias plasma power.

5. The method of claim 1 wherein no bias plasma power is applied during the operation of forming the remote plasma.

6. The method of claim 1 wherein the bias plasma power is between 20 watts and 500 watts.

7. The method of claim 1 wherein the remote plasma is formed by applying a remote plasma power greater than 50 watts capacitively to the remote plasma region.

8. The method of claim 1 wherein the first fluorine-containing precursor comprises at least one precursor selected from the group consisting of atomic fluorine, diatomic fluorine, bromine trifluoride, chlorine trifluoride, nitrogen trifluoride, hydrogen fluoride, sulfur hexafluoride and xenon difluoride.

9. The method of claim 1 wherein a temperature of the patterned substrate is between 30° C. and 400° C. during the operation of etching the tungsten lining layer.

10. A method of etching tungsten, the method comprising:
transferring a patterned substrate into a substrate processing region, wherein the patterned substrate has a tungsten lining layer coating two adjacent stacks and a high aspect ratio trench between the two adjacent stacks, and wherein one or both of the two adjacent stacks comprises at least ten alternating layers of dielectric and tungsten;
flowing a first fluorine-containing precursor into the substrate processing region while applying local plasma power which accelerates fluorine-containing ions toward the patterned substrate;
flowing a second fluorine-containing precursor into a remote plasma region fluidly coupled to a substrate processing region via perforations in a perforated plate;
forming a remote plasma in the remote plasma region to produce plasma effluents from the second fluorine-containing precursor and flowing the plasma effluents into the substrate processing region through the perforations; and
etching the tungsten lining layer, wherein etching the tungsten lining layer reduces a thickness of the tungsten lining layer on a sidewall of the high aspect ratio trench.

11. The method of claim 10 wherein the first fluorine-containing precursor is the same as the second fluorine-containing precursor.

12. The method of claim 10 wherein etching the tungsten lining layer reduces a thickness of the tungsten lining layer at a top rate near the outermost portion of the sidewall of the high aspect ratio trench which is within 20% of a bottom rate near the innermost portion of the sidewall of the high aspect ratio trench.

13. The method of claim 10 wherein the second fluorine-containing precursor is nitrogen trifluoride.

14. A method of etching tungsten, the method comprising:
transferring a patterned substrate into a substrate processing region, wherein the patterned substrate has a tungsten lining layer coating a high aspect ratio trench having a depth more than five times a width of the high aspect ratio trench, wherein the high aspect ratio trench is disposed between two adjacent stacks and one or both of the two adjacent stacks comprises at least ten alternating layers of dielectric and tungsten;
flowing a fluorine-containing precursor into the substrate processing region while applying local plasma power capacitively between a perforated plate and a substrate susceptor supporting the patterned substrate to create and accelerate fluorine-containing ions toward the patterned substrate;
flowing nitrogen trifluoride into a remote plasma region fluidly coupled to a substrate processing region via perforations in the perforated plate;
forming a remote plasma in the remote plasma region to produce plasma effluents from the nitrogen trifluoride and flowing the plasma effluents into the substrate processing region through the perforations; and
etching the tungsten lining layer, wherein etching the tungsten lining layer reduces a thickness of the tungsten lining layer on a sidewall of the high aspect ratio trench at a top rate near the outermost portion of the sidewall of the high aspect ratio trench which is within 20% of a bottom rate near the innermost portion the sidewall of the high aspect ratio trench.

Assignees

• Applied Materials Inc

Inventors

• Wang Xikun
• Liu Jie
• Wang Anchuan
• Ingle Nitin K

Classifications

• H01J37/32357

  Generation remote from the workpiece, e.g. down-stream · CPC title

• H01J2237/334

  Etching · CPC title

• H10P50/267 Primary

  using plasmas · CPC title

• H01L21/32136 Primary

  Electricity · mapped topic