Curable resin compositions

Patent metadata

Field	Value
Publication number	US-9057002-B2
Application number	US-201214236933-A
Country	US
Kind code	B2
Filing date	Jul 18, 2012
Priority date	Aug 18, 2011
Publication date	Jun 16, 2015
Grant date	Jun 16, 2015

Abstract

A curable epoxy resin composition including (a) at least one epoxy resin; and (b) at least one hardener; wherein the curable epoxy resin composition has at least two exotherm peaks representing at least two distinct chemical reactions and wherein the exothermic peak difference of the two exotherm peaks is sufficient to allow the curable epoxy resin composition of being B-staged.

First claim

The invention claimed is:

1. A curable epoxy resin composition comprising (a) at least one epoxy resin; and (b) at least one hardener; wherein the curable epoxy resin composition is at least a three-component composition, such that the three-component composition includes (i) (a1) at least a first epoxy resin; and (a2) at le second epoxy resin different from the first epoxy resin and at least one hardener component (b); or (ii) at least one epoxy resin component (a) and (b1) at least a first hardener, and (b2) at least a second hardener different from the first hardener; wherein the curable epoxy resin composition has at least two exotherm peaks representing at least two distinct chemical reactions and wherein the exothermic peak difference of the two exotherm peaks, when measured by differential scanning calorimetry with a heating rate of 10° C./minute, is greater than or equal to 20° C. and sufficient to allow the curable epoxy resin composition to be B-staged.

2. The composition of claim 1 , wherein the at least one epoxy resin component (a) comprises (a1) at least a first epoxy resin; and (a2) at least a second epoxy resin different from the first epoxy resin; and wherein the at least one hardener comprises at least a first hardener component (b).

3. The composition of claim 1 , wherein the at least one epoxy resin component (a) comprises at least a first epoxy resin: and wherein the at least one hardener component (b) comprises (b1) at least a first hardener, and (b2) at least a second hardener different from the first hardener.

4. The composition of claim 3 , wherein the molar ratio of the first hardener to the second hardener is from 0.001 to 1,000.

5. The composition of claim 3 , wherein each of the first and second hardeners contain reactive amine hydrogens.

6. The composition of claim 3 , wherein the first hardener contains reactive amine hydrogens and the second hardener contains reactive phenol hydrogens.

7. The composition of claim 1 , wherein the composition has a viscosity of less than 50,000 mPa-s under processing conditions of the B-stageable composition.

8. The composition of claim 2 , wherein the first epoxy resin; and the second epoxy resin each separately and individually is selected from the group consisting of a divinylarene dioxide, a polyglycidyl ether, or a combination thereof.

9. The composition of claim 3 , wherein the first and second hardeners each separately and individually is selected from the group consisting of aliphatic amines, aromatic amines, cycloaliphatic amines, carbodiimides, ureas, guanidines, phenols, aliphatic alcohols, mercaptans, anhydrides, and mixtures thereof.

10. The composition of claim 1 , wherein the at least two distinct chemical reactions that the composition is capable of undergoing is first a B-staging reaction and second a C-staging reaction, wherein the B-staging reaction and the C-staging reaction are two distinct chemical reactions.

11. The composition of claim 10 , wherein the B-staging takes place at a first temperature, T 1 ; and the C-staging takes place at a second temperature, T 2 ; wherein T 2 is different from T 1 ; and wherein T 2 is a higher temperature than T 1 .

12. The composition of claim 11 , wherein T 1 is greater than or equal to 20° C. and T 2 is greater than 20° C. but less than 300° C.

13. A process comprising the steps of:
(i) coating reinforcing fibers with a composition of claim 1 , and
(ii) B-staging the composition coating the reinforcing fibers of step (i) to form a prepreg.

14. The process of claim 13 , including step (iii) C-staging the prepreg of step (ii) to form a laminate.

Assignees

• Padilla-Acevedo Angela I
• Valette Ludovic
• Mullins Michael J
• Verghese Kandathil E
• Wilson Mark B
• Dow Global Technologies Llc

Inventors

• Padilla-Acevedo Angela I
• Valette Ludovic
• Mullins Michael J
• Verghese Kandathil E
• Wilson Mark B

Classifications

• C09D137/00 Primary

  Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a heterocyclic ring containing oxygen (based on polymers of cyclic esters of polyfunctional acids C09D131/00; based on polymers of cyclic anhydrides of unsaturated acids C09D135/00); Coating compositions based on derivatives of such polymers · CPC title

• C08G59/50

  Amines · CPC title

• C08L63/00

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title

• C08G59/56

  together with other curing agents · CPC title

• C08J2363/00

  Characterised by the use of epoxy resins; Derivatives of epoxy resins · CPC title