Coating composition comprising autoxidisable component

Patent metadata

Field	Value
Publication number	US-9580620-B2
Application number	US-201314017990-A
Country	US
Kind code	B2
Filing date	Sep 4, 2013
Priority date	Mar 31, 2008
Publication date	Feb 28, 2017
Grant date	Feb 28, 2017

Abstract

An aqueous emulsion coating composition comprising an autoxidisable vinyl oligomer having ≧20 wt % of unsaturated fatty acid residue; Tg from −50 to +15° C.; Mw from 2,500 to 40,000 g/mol; polydispersity from 2 to 12, said composition having ≦15% co-solvent by weight of solids, ≦13% NMP by weight of solids ≧38% solids by weight of composition; said composition when in the form of a coating having a telegraphing value defined as the difference in gloss at a 20° angle of between a film cast on rough PVC and a film cast on smooth PVC of 10 gloss units.

First claim

The invention claimed is:

1. An aqueous emulsion, coating composition that comprises an autoxidisable vinyl oligomer, wherein:
I) said autoxidisable vinyl oligomer has:
i) fatty acid residue in an amount greater than or equal to 20% by weight of the autoxidisable vinyl oligomer;
ii) a glass transition temperature (Tg) from −50° C. to +15° C.;
iii) an acid value less than 40 mg KOH/g;
iv) a weight average molecular weight (Mw) from 2,500 to 40,000 g/mol; and
v) a polydispersity (PDi) from 2 to 12; and wherein

II) said composition has:
a) a co solvent content less than 25% by weight of solids;
b) a N methylpyrrolidone content less than 13% by weight of solids;
c) a solids content greater than or equal to 38% by the total weight of said composition;
d) 38% to 65% of the autoxidisable vinyl oligomer;
e) 0 to 20% of co-solvent; and
f) 15% to 58% of water, wherein
the percentages of d), e) and f) are by weight of the composition and d)+e)+f)=100%, and wherein

III) said composition when in the form of a film has a telegraphing value of less than 10 gloss units, wherein the telegraphing value is a difference between an initial smooth gloss value of the film minus an initial rough gloss value of the film, where
(1) the initial smooth gloss value is the gloss when the film is cast on a smooth PVC substrate with Rz=1 μm±0.25 μm and the initial rough gloss value is the gloss when the film is cast on a rough PVC substrate with Rz=25 μm±5 μm, wherein Rz is an average of five greatest peak-to-valley separations in a scanned surface area of 1.9×2.5 mm of the PVC substrate as analyzed with an optical profilometer at a magnification of 2.5;
(2) each film has a dry film thickness of 52 μm±6 μm; and
(3) each initial gloss value is measured at a 20° angle, 24 hours after the film has been cast onto the PVC substrate.

2. The aqueous autoxidisable coating composition according to claim 1 , wherein the composition comprises an autoxidisable vinyl oligomer obtained by a process comprising steps of:
I) polymerising ethylenically unsaturated vinyl monomers comprising:
i) 30% to 70% of at least one monomer G selected from hydroxylalkyl(meth)acrylates and epoxy functional vinyl monomers;
ii) 30% to 70% of at least one other ethylenically unsaturated vinyl monomer; and
iii) <1% of chlorine containing monomers;
where the percentages are by weight of total monomers;

II) reacting the oligomer obtained in step I) with fatty acids having an average iodine value in the range of 80 to 180 g I2/100 g fatty acid;
where the autoxidisable vinyl oligomer has
i) oligomeric backbone in an amount from 35% to 62% by weight of the oligomer;
ii) fatty acid residue in an amount from 38% to 65% by weight of the oligomer;
iii) a Tg from −50 to 15° C.;
iv) a Mw from 6500 to 25000 g/mol; and
v) a PDi from 2 to 8;

said composition having
a) a co solvent content <15 wt % by weight of solids;
b) a N methylpyrrolidone content <13 wt % by weight of solids;
c) heterocyclic amine containing solvent content of 0 wt % by weight of solids;
d) a solids content >38 wt %;
e) a pH in the range of from 4.1 to 8.4; and wherein

said composition when in the form of a coating has a telegraphing value of less than 10 gloss units.

3. The aqueous autoxidisable coating composition according to claim 1 , wherein 0% of glycidyl esters of unsaturated fatty acids are used in the preparation of the autoxidisable vinyl oligomer.

4. The aqueous autoxidisable coating composition according claim 1 , wherein the autoxidisable vinyl oligomer, if carboxylic acid functional conforms to the following relationship:
ND×AV≦ 22

where ND=neutralization degree of the acid groups on the oligomer and AV=acid value.

5. The aqueous autoxidisable coating composition according to claim 1 , wherein the composition comprises <5% of N methylpyrrolidone by weight of solids.

6. The aqueous autoxidisable coating composition according to claim 1 , wherein the composition comprises <13% by weight of solids, of nitrogen-containing molecules with an evaporation rate <0.1 as determined by ASTM D3539 relative to the evaporation rate of n-butyl acetate=1.00 which are either aromatic, heterocyclic or which are aromatic and aliphatic primary and secondary (di)amines with the proviso that the amount of nitrogen in such molecules is >5% by weight of the molecule.

7. The aqueous autoxidisable coating composition according to claim 1 , wherein said composition comprises:
i) 20% to 45% of TiO 2 ;
ii) 20% to 45% of the autoxidisable vinyl oligomer;
iii) 0 to 10% of co solvent;
iv) 0.1% to 3% of thickener;
v) 0 to 5% of dispersing agent; and
vi) 25% to 60% water;
where the percentages are by weight of the composition and i)+ii)+iii)+iv)+v)=100%.

8. A method of coating a substrate comprising the steps of:
i) applying a coating composition as claimed in claim 1 to a substrate; and
ii) drying the substrate to form a coating thereon; wherein
the coating has a telegraphing value of less than 10 gloss units.

Assignees

• Dsm Ip Assets Bv

Inventors

• Van Casteren Ilse
• Overbeek Gerardus Cornelis
• Tennebroek Ronald

Classifications

• C08F120/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08F2810/50

  wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority · CPC title

• C08F8/44

  Preparation of metal salts or ammonium salts · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• C09D139/06

  Homopolymers or copolymers of N-vinyl-pyrrolidones · CPC title