Carbon-supported catalysts for production of higher alcohols from syngas

Patent metadata

Field	Value
Publication number	US-8999876-B2
Application number	US-201113883681-A
Country	US
Kind code	B2
Filing date	Dec 1, 2011
Priority date	Dec 6, 2010
Publication date	Apr 7, 2015
Grant date	Apr 7, 2015

Abstract

Catalyst compositions comprising molybdenum, sulfur and an alkali metal ion supported on a nanofibrous, mesoporous carbon molecular sieve are useful for converting syngas to higher alcohols. The compositions are produced via impregnation and may enhance selectivity to ethanol in particular.

First claim

What is claimed is:

1. A catalyst composition comprising molybdenum, sulfur and an alkali metal ion on a nanofibrous, mesoporous carbon molecular sieve support.

2. The catalyst composition of claim 1 wherein the alkali metal ion is selected from the group of ions consisting of sodium, potassium, cesium, and combinations thereof, the molybdenum and the sulfur are combined as molybdenum sulfide, or both.

3. The catalyst composition of claim 1 wherein X-ray powder diffraction analysis exhibits strong reflections at angle 2-theta of 26.1; 36.9; and 53.8, and weak reflections at angle 2-theta of 23.3; 27.3; 34.4; 39.1; 46.2; 49.2; 49.3; 52.7; 55.1; and 58.8.

4. The catalyst composition of claim 1 wherein Brunauer-Emmett-Teller analysis shows a surface area from 300 to 1,000 m 2 /g.

5. A process for making the catalyst composition of claim 1 comprising impregnating a nanofibrous, mesoporous carbon molecular sieve support with molybdenum, sulfur and an alkali metal ion.

6. The process of claim 5 wherein the nanofibrous, mesoporous carbon molecular sieve support is prepared by (a) contacting a mesoporous silica template with a carbon source under conditions suitable to absorb the carbon source into the mesorporous silica template and polymerize the carbon source to form a nanofibrous, mesoporous carbon structure; (b) removing the mesoporous silica template by contacting the nanofibrous, mesoporous carbon structure with an aqueous acid or base under conditions suitable to dissolve the mesoporous silica template and obtain a nanofibrous, mesoporous carbon molecular sieve support; and (c) recovering the nanofibrous, mesoporous carbon molecular sieve support.

7. A process for converting a mixture of hydrogen gas and carbon monoxide gas to at least one higher alcohol comprising contacting, under conditions suitable to form at least one higher alcohol, a gas mixture, including at least hydrogen gas and carbon monoxide gas, and the catalyst composition of claim 1 .

8. The process of claim 7 wherein, at a gas hourly space velocity of 6,000 mL/g/h, the catalyst composition exhibits a productivity of the at least one higher alcohol ranging from 38.2 to 115.7 mg/g catalyst/h.

Assignees

• Jones Christopher W
• Agrawal Pradeep K
• Nguyen Tien Thao
• Georgia Tech Res Inst

Inventors

• Jones Christopher W
• Agrawal Pradeep K
• Nguyen Tien Thao

Classifications

• B01J23/28

  Molybdenum · CPC title

• C07C31/08

  Ethanol · CPC title

• B01J23/007

  Mixed salts · CPC title

• C07C29/153 Primary

  characterised by the catalyst used · CPC title

• B01J21/185

  Carbon nanotubes (carbon nanotubes per se C01B32/15) · CPC title