Catalyst compositions for converting syngas to produce higher alcohols

Patent metadata

Field	Value
Publication number	US-9636665-B2
Application number	US-201113883686-A
Country	US
Kind code	B2
Filing date	Dec 1, 2011
Priority date	Dec 6, 2010
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

Catalyst compositions for production of higher alcohols comprise a hydrotalcite or hydrotalcite-like support impregnated with molybdenum and an alkali metal. When the compositions are used to convert syngas, selectivity to higher (C2+) alcohols is increased in comparison to conversions accomplished over many other catalyst systems.

First claim

What is claimed is:

1. A catalyst composition prepared by a process comprising
(a) calcining a hydrotalcite or hydrotalcite-like support by heating it at a temperature ranging from 200° C. to 600° C., under conditions suitable to form a calcined support exhibiting a powder X-ray diffraction pattern obtained using copper K-alpha radiation having d-spacings at angles 2-theta of 43.4, 62.5 and, optionally, 35.1; and
(b) impregnating the calcined support with a molybdenum source and an alkali metal source,
under conditions suitable to form a catalyst composition.

2. The catalyst composition of claim 1 wherein at least a portion of the molybdenum source is in the form of molybdenum sulfide.

3. The catalyst composition of claim 2 wherein the catalyst composition comprises
from 5 weight percent to 20 weight percent of molybdenum sulfide, and
from 2.5 weight percent to 2 weight percent of alkali metal from the alkali metal source;
both based on the weight of the catalyst composition as a whole.

4. The catalyst composition of claim 1 wherein step (b) occurs under at least one condition selected from
a temperature ranging from 30° C. to 120° C.,
a time ranging from 1 hour to 4 hours, and
combinations thereof.

5. The catalyst composition of claim 1 wherein the hydrotalcite or hydrotalcite-like support is prepared by co-precipitation of salt solutions containing divalent magnesium, nickel or cobalt ions and trivalent aluminum or cobalt ions, provided the divalent and trivalent ions represent different elements; alkali metal ions; and at least one carbonate anion; to form a product having the formula:
M 2+ 1−x M 3+ x (OH) 2 (CO 3 ) x/2 .m H 2 O,

wherein M 2+ is a divalent magnesium, nickel or cobalt ion, and M 3+ is a trivalent aluminum or cobalt ion, provided M 2+ and M 3+ represent different elements; x is the number of moles of the trivalent aluminum or nickel ion; m is the number of moles of waters of hydration; and wherein the carbonate anion may optionally be replaced, in whole or part, by an anion selected from the group consisting of phosphate, molydate, sulfate, nitrate, chlorate, chloride, bromide, fluoride, iodide, and combinations thereof.

6. A process for preparing a higher alcohol comprising contacting
(a) a catalyst composition prepared by a process comprising
(a) calcining a hydrotalcite or hydrotalcite-like support by heating it at a temperature ranging from 200° C. to 600° C., under conditions suitable to form a calcined support exhibiting a powder X-ray diffraction pattern obtained using copper K-alpha radiation having d-spacings at angles 2-theta of 43.4, 62.5 and, optionally, 35.1; and
(b) impregnating the calcined support with a molybdenum source and an alkali metal source;
under conditions suitable to form a catalyst composition; and

(b) a gas mixture, including at least hydrogen gas and carbon monoxide gas;
under conditions suitable to form a product comprising at least one higher alcohol.

7. The process of claim 6 wherein the gas mixture is part of a feed that further comprises hydrogen sulfide in an amount ranging from 20 ppm to 250 ppm.

Assignees

• Jones Christopher W
• Agrawal Pradeep K
• Nguyen Tien Thao
• Georgia Tech Res Inst

Inventors

• Jones Christopher W
• Agrawal Pradeep K
• Nguyen Tien Thao

Classifications

• B01J23/007 Primary

  Mixed salts · CPC title

• C07C31/10

  containing three carbon atoms · CPC title

• B01J23/28

  Molybdenum · CPC title

• C07C27/06

  by hydrogenation of oxides of carbon · CPC title

• C07C31/08

  Ethanol · CPC title