Curable coating compositions

Patent metadata

Field	Value
Publication number	US-2025145851-A1
Application number	US-202318832987-A
Country	US
Kind code	A1
Filing date	Jan 17, 2023
Priority date	Jan 31, 2022
Publication date	May 8, 2025
Grant date	—

Abstract

A coating composition includes: (a) a polymeric resin including hydroxyl functional groups; (b) a polyisocyanate crosslinker; (c) a thiol including at least 2 active hydrogen groups, where the active hydrogen groups include a thiol group or a combination of a thiol and a hydroxyl group; and (d) a tin-based catalyst. The ratio of the number of moles of thiol to the number of moles of tin in the coating composition is less than or equal to 100:1 and the amount of (d) the tin-based catalyst is less than or equal to 0.25% by weight relative to the total resin solids, and/or the ratio of the number of moles of thiol to the number of moles of tin ranges from 3:1 to 50:1 and the amount of (d) the tin-based catalyst is less than or equal to 0.4% by weight relative to the total resin solids.

First claim

1 . A coating composition comprising:
(a) a polymeric resin comprising hydroxyl functional groups; (b) a polyisocyanate crosslinker; (c) a thiol comprising at least 2 active hydrogen groups, wherein the active hydrogen groups comprise a thiol group or a combination of a thiol group and a hydroxyl group, and (d) a tin-based catalyst, wherein the ratio of the number of moles of thiol to the number of moles of tin is less than or equal to 100:1 and the amount of (d) the tin-based catalyst is less than or equal to 0.25% by weight relative to the total resin solids, and/or wherein the ratio of the number of moles of thiol to the number of moles of tin ranges from 3:1 to 50:1 and the amount of (d) the tin-based catalyst is less than or equal to 0.4% by weight relative to the total resin solids.

2 . The coating composition of claim 1 , wherein the amount of (d) the tin-based catalyst is greater than or equal to 0.05% by weight relative to the total resin solids.

3 - 5 . (canceled)

6 . The coating composition of claim 1 , wherein (a) the polymeric resin comprising hydroxyl functional groups comprises a polyester polymer, an (meth)acrylic polymer, and/or a polyurethane polymer.

7 . The coating composition of claim 6 , wherein the (a) polymeric resin comprising hydroxyl functional groups comprises a hydroxyl equivalent weight of up to 1,000 grams per equivalent based on the total resin solids of the polymeric resin.

8 . The coating composition of claim 1 , wherein (b) the polyisocyanate crosslinker comprises an aliphatic polyisocyanate.

9 . The coating composition of claim 1 , wherein (b) the polyisocyanate crosslinker comprises an average isocyanate functionality of greater than 2.

10 . The coating composition of claim 1 , wherein (c) the thiol comprising at least 2 active hydrogen groups comprises at least three thiol groups.

11 . The coating composition of claim 1 , wherein (c) the thiol comprising at least 2 active hydrogen groups comprises at least four thiol groups.

12 . The coating composition of claim 11 , wherein the (c) the thiol comprising at least 2 active hydrogen groups comprises at least four thiol groups and comprises an equivalent weight of at least 100 grams per equivalents based on the total resin solids of the thiol comprising at least 2 active hydrogen groups.

13 . The coating composition of claim 1 , wherein (c) the thiol comprising at least 2 active hydrogen groups comprises at least 3 active hydrogen groups.

14 . The coating composition of claim 1 , wherein (c) the thiol comprising at least 2 active hydrogen groups comprises pentaerythritol tetrakis(3-mercaptoacetate), 1-thioglycerol, trimethylolpropane tri (3-mercaptopropionate), 2,3-bis((2-mercaptoethyl)thio)-1-propanethiol, and/or some combination thereof.

15 . The coating composition of claim 1 , wherein (d) the tin-based catalyst comprises dibutyltin dilaurate, dibutyltin diacetate, dibutyltin mercaptide, dibutyltin diacetate, dibutyl tin dimaleate, dimethyl tin diacetate, dimethyl tin dilaurate, tin octoate, and/or some combination thereof.

16 . (canceled)

17 . The coating composition of claim 1 , wherein the coating composition exhibits a viscosity of less than 220 centipoise after 120 minutes, as measured according to ASTM D4287 and at 23° C.

18 . The coating composition of claim 17 , wherein when the coating composition is applied to a substrate and cured, the coating exhibits:
an appearance of greater than 75 in distinctness of image (DOI), as measured according to ASTM E430; an appearance of not greater than 50 in the shortwave (SW); and a 7 day hardness value of at least 45, as measured according to ASTM D4366-16.

19 . A multi-layer coating system comprising:
(1) a substrate; (2) a first coating layer formed over at least a portion of the substrate, the first coating layer obtained from a first coating composition; and (3) a second coating layer formed over at least a portion of the first coating layer, the second coating layer obtained from a second coating composition that is different from the first coating composition, wherein at least one of the first coating composition and the second coating composition comprises the coating composition of claim 1 .

20 . The multi-layer coating system of claim 19 , wherein the substrate comprises a vehicle component.

21 . (canceled)

22 . (canceled)

23 . The multi-layer coating system of claim 19 , wherein the second coating layer is an outermost layer.

24 . The multi-layer coating system of claim 23 , wherein the second coating layer comprises a clearcoat layer.

25 . The multi-layer coating system of claim 23 , wherein the second coating layer comprises a pigmented top coat layer.

26 . The multi-layer coating system of claim 23 , wherein the multi-layer coating system exhibits:
an appearance of greater than 75 in distinctness of image (DOI), as measured according to ASTM E430; an appearance of not greater than 50 in the shortwave (SW); and a 7 day hardness value of at least 45, as measured according to ASTM D4366-16.

27 - 35 . (canceled)

Assignees

• Ppg Ind Ohio Inc

Inventors

• Wo Yaqi
• Fenn David Robert
• Landis Chad Alan
• Ro Hyun Wook
• Stibbard Mitchell Ryan
• Verardi Christopher A

Classifications

• C08G18/65

  Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen {(C08G18/2805 takes precedence)} · CPC title

• C08G18/6229

  Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols · CPC title

• C08G18/3876

  containing mercapto groups · CPC title

• C08G18/246

  containing also tin-carbon bonds · CPC title

• B05D7/14

  to metal, e.g. car bodies (involving a chemical reaction between the metal and the coating C23) · CPC title