One component polyurethane dispersion for vinyl windows and other substrates

Patent metadata

Field	Value
Publication number	US-11059935-B2
Application number	US-201916549285-A
Country	US
Kind code	B2
Filing date	Aug 23, 2019
Priority date	Aug 2, 2017
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

The present invention provides an aqueous polyurethane dispersion (PUD) comprising an amorphous polyester having a glass transition temperature (T g ) as determined by differential scanning calorimetry of less than −30° C.; wherein the aqueous polyurethane dispersion (PUD) has a glass transition temperature (T g ) as determined by differential scanning calorimetry (DSC) of 0° C. to 20° C. and a hard block content of greater than 50%. Coatings, adhesives, sealants, paints, primers and topcoats, made from the inventive aqueous polyurethane dispersion (PUD) pass detergent resistance testing according to the American Architectural Manufacturers Association's standard, AAMA 615-13, have a pencil hardness according to ASTM D3363 of at least 3H, and are particularly suited for use on low surface energy substrates such as vinyl and other surfaces including floors, windows, doors, window frames, door frames, window shutters, railing, gates, pillars, arbors, pergolas, trellises, gazebos, posts, fencing, pipes and fittings, wire and cable insulation, automobile components, credit cards, and siding.

First claim

What is claimed is:

1. A coating composition, comprising:
an aqueous polyurethane dispersion (PUD) comprising the reaction product of:
(i) a polyisocyanate,
(iii) a compound comprising at least one isocyanate-reactive group and an anionic group or potentially anionic group,
(iv) an amorphous polyester having a glass transition temperature (Tg) as determined by differential scanning calorimetry (DSC) of less than −30° C. and comprising ortho-phthalic anhydride,
(v) water,
(vi) a mono functional polyalkylene ether,
(vii) a polyol having a molecular weight of less than <400 g/mol, and
(viii) a polyamine or amino alcohol having a molecular weight of 32 to 400 g/mol,
wherein the aqueous polyurethane dispersion (PUD) has a glass transition temperature (Tg) as determined by differential scanning calorimetry (DSC) of 0° C. to 20° C. and a hard block content of greater than 50%; and

a pigment;
wherein the coating composition has a solids content of at least 30 wt % based on a total weight of the coating composition.

2. The coating composition of claim 1 , wherein PUD solids comprise from about 40 wt % to about 70 wt % of total solids content of the coating composition.

3. The coating composition of claim 1 , wherein the polyisocyanate (i) is selected from the group consisting of 1,6-hexamethylene diisocyanate (HDI), pentamethylene diisocyanate (PDI), isophorone diisocyanate (IPDI), 2,2,4- and 2,4,4-trimethyl-hexamethylene diisocyanate, isomeric bis-(4,4′-isocyanatocyclohexyl)methanes or mixtures thereof of any desired isomer content, 1,4-cyclohexylene diisocyanate, 1,4-phenylene diisocyanate, 2,4- and 2,6-toluene diisocyanate or hydrogenated 2,4- and 2,6-toluene diisocyanate, 1,5-naphthalene diisocyanate, 2,4′- and 4,4′-diphenylmethane diisocyanate, 1,3- and 1,4-bis-(2-isocyanato-prop-2-yl)-benzene (TMXDI), 1,3-bis(isocyanato-methyl)benzene (XDI), and (S)-alkyl 2,6-diisocyanatohexanoates or (L)-alkyl 2,6-diisocyanatohexanoates.

4. The coating composition of claim 1 , wherein the polymeric polyol has a hydroxyl number of from about 20 to about 400 KOH/g of polymeric polyol.

5. The coating composition of claim 1 , wherein the amorphous polyester has a molecular weight of from about 300 g/mol to about 3000 g/mol.

6. The coating composition of claim 1 , wherein the pigment is present in the coating composition in an amount of from about 5 wt % to about 40 wt % based on a total weight of the coating composition.

7. The coating composition of claim 1 , further comprising a thickener in an amount of from about 0.1 wt % to about 3 wt % based on a total weight of the coating composition.

8. The coating composition of claim 1 , further comprising a matting agent in an amount of from about 0.1 wt % to about 3 wt % based on a total weight of the coating composition.

9. The coating composition of claim 1 , further comprising a thickener and a matting agent.

10. The coating composition of claim 9 , wherein the matting agent and the thickener are present in the coating composition at a weight ratio of from about 1:2 to about 2:1.

11. The coating composition of claim 1 , further comprising a wetting agent in an amount from about 0.5 wt % to about 3 wt % based on a total weight of the composition.

12. The coating composition of claim 1 , further comprising a leveling agent in an amount of from about 0.1 wt % to about 1 wt % based on a total weight of the composition.

13. The coating composition of claim 1 , wherein the coating composition includes from about 35 wt % to about 70 wt % solids based on a total weight of the coating composition.

14. The coating composition of claim 1 , wherein the coating composition has a pigment volume concentration of from about 20% to about 40%.

15. The coating composition of claim 1 , wherein the coating composition has a density of from about 5 pounds per gallon (lbs/gal) to about 15 lbs/gal.

16. A coated substrate, comprising:
a substrate; and
a coating composition according to claim 1 applied to a surface of the substrate to form a surface coating.

17. The coated substrate of claim 16 , wherein a primer composition is applied between the substrate and the coating composition.

18. The coated substrate of claim 16 , wherein the surface coating has a 60° gloss value of less than or equal to 25.

19. The coated substrate of claim 16 , wherein the surface coating has a dirt pick-up resistance (DPUR) value of less than or equal to 10.

Assignees

• Covestro Llc

Inventors

• Nakao Makoto
• Kasardo Tina

Classifications

• G01N25/4866

  by using a differential method · CPC title

• C08G18/348

  Hydroxycarboxylic acids · CPC title

• C08G18/3206

  aliphatic · CPC title

• C08G18/6603

  with compounds of group C08G18/32 or polyamines of C08G18/38 · CPC title

• C08G18/4825

  Polyethers containing two hydroxy groups (C08G18/4833 - C08G18/5096 take precedence) · CPC title