Processes for recovering rhodium from hydroformylation processes

Patent metadata

Field	Value
Publication number	US-2025137091-A1
Application number	US-202218686705-A
Country	US
Kind code	A1
Filing date	Oct 13, 2022
Priority date	Nov 11, 2021
Publication date	May 1, 2025
Grant date	—

Abstract

The process disclosure relates to processes for recovering rhodium from a hydroformylation process. In one aspect, a tails stream from a product-catalyst separation zone is provided to at least one organic solvent nanofiltration separation membrane, wherein a final permeate stream exits a final organic solvent nanofiltration separation membrane, wherein the rhodium concentration in the final permeate stream is lower than the rhodium concentration in the tails stream. The permeate stream is incinerated on-site to create a rhodium-containing ash.

First claim

What is claimed is:

1 . A process for recovering rhodium from a hydroformylation process that comprises producing at least one aldehyde in a reaction zone, the reaction zone comprising a C 6 to C 22 olefin, hydrogen and carbon monoxide in the presence of a catalyst, wherein the catalyst comprises rhodium and an organophosphorus ligand, the process comprising:
(a) receiving a tails stream from a product-catalyst separation zone, wherein the tails stream comprises aldehydes, heavies, rhodium, and an organophosphorous ligand; (b) providing at least a portion of the tails stream to at least one organic solvent nanofiltration (OSN) separation membrane, wherein a final permeate stream exits a final OSN separation membrane, the final permeate stream comprising aldehydes, heavies, rhodium, and an organophosphorous ligand, wherein the rhodium concentration in the final permeate stream is lower than the rhodium concentration in the tails stream; and (c) incinerating the final permeate stream on-site to create a rhodium-containing ash.

2 . The process of claim 1 , wherein the process uses one OSN separation membrane.

3 . The process of claim 1 , wherein the process uses two OSN separation membranes.

4 . The process of claim 3 , wherein all of the permeate stream from the first OSN separation membrane is provided to the second OSN separation membrane.

5 . The process of claim 1 , wherein the incinerator in which the final permeate stream is incinerated to create the rhodium-containing ash is located within a ten mile radius of the product-catalyst separation zone.

6 . The process of claim 1 , further comprising recovering rhodium from the rhodium-containing ash.

7 . The process of claim 1 , further comprising passing at least a portion of retentate from at least one OSN separation membrane through a first OSN separation membrane.

8 . The process of claim 1 , wherein the final permeate stream is incinerated within 90 days of the tails stream leaving the product-catalyst separation zone.

9 . The process of claim 1 further comprising treating the final permeate stream to be incinerated prior to incineration to recover residual aldehyde product.

Assignees

• Dow Technology Investments Llc

Inventors

• Brammer Michael A
• Liu Yujun
• Singh Amarnath
• Miller Glenn A
• Backes Adrian Francis
• Betham Michael

Classifications

• C22B7/005

  Separation by a physical processing technique only, e.g. by mechanical breaking · CPC title

• C22B1/02

  Roasting processes (C22B1/16 takes precedence) · CPC title

• C07C45/786

  by membrane separation process, e.g. pervaporation, perstraction, reverse osmosis · CPC title

• C07C45/50

  by oxo-reactions · CPC title

• B01J31/185

  Phosphites ((RO)3P) , their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof · CPC title