Method of recovering acid and platinum group metal from leaching solution of spent catalyst

Patent metadata

Field	Value
Publication number	US-10190192-B2
Application number	US-201414787925-A
Country	US
Kind code	B2
Filing date	Apr 28, 2014
Priority date	Apr 29, 2013
Publication date	Jan 29, 2019
Grant date	Jan 29, 2019

Abstract

The present invention relates to a method of recovering acid and a platinum group metal from a leaching solution of a spent catalyst, more particularly, to a method of recovering acid and a platinum group metal from a leaching solution of a spent catalyst, the method including: filtering a leaching solution of a spent catalyst, providing the filtered leaching solution into a concentration chamber, and heating the filtered leaching solution to recover acid included in the leaching solution; providing a concentrated solution of the leaching solution into a substitution chamber after recovering the acid, and adding a metal for a substitution reaction; and cleaning a solid, which is separated by solid-liquid separation after the substitution reaction, with acid and recovering the platinum group metal.

First claim

The invention claimed is:

1. A method of recovering acid and a platinum group metal from a leaching solution of a spent catalyst, the method comprising:
filtering a leaching solution, in which a spent catalyst is leached, providing the filtered leaching solution into a concentration chamber, and heating the filtered leaching solution to recover acid included in the leaching solution;
providing a concentrated solution of the leaching solution into a substitution chamber after recovering the acid, and adding a metal having a higher ionization tendency than a platinum group metal for a substitution reaction; and
cleaning a solid, which is separated by solid-liquid separation after the substitution reaction, with acid and recovering the solid,
wherein the metal added when the substitution reaction is performed includes at least one selected from the group consisting of iron, aluminum and zinc.

2. The method according to claim 1 , wherein the spent catalyst is leached in 3 M to 12 M of hydrochloric acid (HCl).

3. The method according to claim 1 , wherein the filtered leached solution is heated at 90° C. to 180° C.

4. The method according to claim 1 , wherein, when the acid is recovered, a concentration of the acid is 13 M when 1% to 10% of the acid is recovered, the concentration of the acid is 9.7 M when 10% to 20% of the acid is recovered, the concentration of the acid is 6.4 M when 20% to 40% of the acid is recovered, the concentration of the acid is 5.95 M when 40% to 60% of the acid is recovered, and the concentration of the acid is 5.5 M when 60% to 80% of the acid is recovered.

5. The method according to claim 1 , wherein, when the substitution reaction is performed, an acid density of the concentration solution is 0.05 M to 1 M.

6. The method according to claim 1 , wherein the metal added to the concentration solution is 3 to 10 times of the platinum group metal included in the concentration solution based on an equivalence ratio.

7. The method according to claim 1 , wherein the substitution reaction is performed at 20° C. to 80° C.

8. The method according to claim 1 , wherein the acid used for cleaning the solid separated by the solid-liquid separation includes at least one selected from the group consisting of hydrochloric acid, nitric acid and sulfuric acid.

9. The method according to claim 8 , wherein a concentration of the acid is 0.1 M to 10 M.

10. The method according to claim 1 , wherein the platinum group metal includes at least one selected from the group consisting of platinum (Pt), palladium (Pd) and rhodium (Rh).

11. The method according to claim 1 , wherein the recovered acid is reused in a leaching process, a filtering process and a cleaning process.

Assignees

• Korea Inst Geoscience & Mineral Resources

Inventors

• Lee Jin-Young
• Chung Kyeong-Woo

Classifications

• C22B3/10

  Hydrochloric acid {, other halogenated acids or salts thereof} · CPC title

• C22B7/007

  by acid leaching · CPC title

• C22B3/46

  by substitution, e.g. by cementation · CPC title

• C22B3/22

  by physical processes, e.g. by filtration, by magnetic means {, or by thermal decomposition} (treatment or purification of solutions by liquid-liquid extraction C22B3/26) · CPC title

• Y02P10/234

  Cross-Sectional Technologies · mapped topic