Purification method and system for aqueous hydrogen peroxide solution

Patent metadata

Field	Value
Publication number	US-2025042737-A1
Application number	US-202418787111-A
Country	US
Kind code	A1
Filing date	Jul 29, 2024
Priority date	Jul 31, 2023
Publication date	Feb 6, 2025
Grant date	—

Abstract

The present disclosure relates to a method and a system for purifying an aqueous hydrogen peroxide solution. According to the present disclosure, it is possible to provide a method and a system for purifying an aqueous hydrogen peroxide solution, which may achieve the purity required in fine chemical fields such as the semiconductor industry field by preventing layer separation of a mixed ion-exchange resin consisting of a cation-exchange resin and an anion-exchange resin and reducing the leaching of ions from the resin during a purification process.

First claim

What is claimed is:

1 . A method for purifying an aqueous hydrogen peroxide solution, comprising steps of:
(a) preparing a mixed ion-exchange resin by injecting a gas into a mixture of a cation-exchange resin, an anion-exchange resin, and water, thereby bubbling the mixture; (b) passing the aqueous hydrogen peroxide solution through the mixed ion-exchange resin; and (c) discharging the aqueous hydrogen peroxide solution that passed through the mixed ion-exchange resin.

2 . The method of claim 1 , wherein a ratio of a volume of the water (V W ) to a total volume (V R ) of the cation-exchange resin and the anion-exchange resin, (V W /V R ), in step (a), is 0.1 to 0.3.

3 . The method of claim 1 , wherein step (a) is performed in a resin mixing tank, and the method further comprises, after step (a) and before step (b), step (a-2) of introducing the prepared mixed ion-exchange resin into a purification tower.

4 . The method of claim 1 , wherein the cation-exchange resin and the anion-exchange resin in step (a) are included at a volume ratio of 0.8:1.0 to 1.0:0.8.

5 . The method of claim 1 , wherein the water in step (a) has a resistivity of 18 MΩ·cm or more.

6 . The method of claim 1 , wherein the gas in step (a) is an unreactive gas or air.

7 . The method of claim 6 , wherein the unreactive gas is at least one selected from the group consisting of nitrogen, helium, neon, argon, krypton, xenon, and SF 6 .

8 . The method of claim 1 , wherein the gas in step (a) is injected at a pressure of 0.5 to 1.5 kgf/cm 2 .

9 . The method of claim 1 , wherein step (a) is performed for 24 hours or more.

10 . The method of claim 1 , further comprising, after step (c), steps of:
(d) transferring the aqueous hydrogen peroxide solution discharged in step (c) to an intermediate storage tank; and (e) transferring the aqueous hydrogen peroxide solution in the intermediate storage tank to a subsequent process or a final storage tank through a transfer pipe including a pump.

11 . The method of claim 10 , wherein a level of the aqueous hydrogen peroxide solution in the intermediate storage tank is 30% or more of an internal height of the intermediate storage tank.

12 . The method of claim 10 , wherein step (e) is performed using a transfer driving force provided by the pump.

13 . A system for purifying an aqueous hydrogen peroxide solution, comprising:
a purification tower having a gas injection pipe connected thereto; and a discharge pipe connected to a rear end of the purification tower, wherein a mixed ion-exchange resin is prepared by introducing a mixture of a cation-exchange resin, an anion-exchange resin and water into the purification tower, and then injecting a gas into the mixture through the gas injection pipe, thereby bubbling the mixture, and the aqueous hydrogen peroxide solution is introduced into the purification tower and passed through the mixed ion-exchange resin.

14 . The system of claim 13 , wherein a ratio of a volume of the water (V W ) to a total volume (V R ) of the cation-exchange resin and the anion-exchange resin, (V W /V R ), in the mixture, is 0.1 to 0.3.

15 . The system of claim 13 , wherein the cation-exchange resin and the anion-exchange resin are included at a volume ratio of 0.8:1.0 to 1.0:0.8.

16 . The system of claim 13 , wherein the water has a resistivity of 18 MΩ·cm or more.

17 . The system of claim 13 , wherein the gas is an unreactive gas or air.

18 . The system of claim 17 , wherein the unreactive gas is at least one selected from the group consisting of nitrogen, helium, neon, argon, krypton, xenon, and SF 6 .

19 . The system of claim 13 , wherein the gas is injected at a pressure of 0.5 to 1.5 kgf/cm 2 .

20 . The system of claim 13 , wherein the gas is injected for 24 hours or more.

21 . The system of claim 13 , further comprising:
an intermediate storage tank connected to a rear end of the discharge pipe; and a transfer pipe connected to a rear end of the intermediate storage tank and including a pump.

22 . The system of claim 21 , wherein a level of the aqueous hydrogen peroxide solution in the intermediate storage tank is 30% or more of an internal height of the intermediate storage tank.

23 . A system for purifying an aqueous hydrogen peroxide solution, comprising:
a resin mixing tank having a gas injection pipe and resin transfer pipe connected thereto; a purification tower provided downstream of the resin mixing tank; and a discharge pipe connected to a rear end of the purification tower, wherein a mixed ion-exchange resin is prepared by introducing a mixture of a cation-exchange resin, an anion-exchange resin and water into the resin mixing tank, and then injecting a gas into the mixture through the gas injection pipe, thereby bubbling the mixture, the prepared mixed ion-exchange resin is introduced into the purification tower through the resin transfer pipe, and the aqueous hydrogen peroxide solution is introduced into the purification tower and passed through the mixed ion-exchange resin.

Assignees

• Dongwoo Fine Chem Co Ltd

Inventors

• Min Hong-Ki
• Seo Dong-Seok
• Lee Uk

Classifications

• C01P2006/80

  Compositional purity · CPC title

• B01J47/04

  Mixed-bed processes · CPC title

• C01B15/0135 Primary

  Purification by solid ion-exchangers or solid chelating agents · CPC title

• C01B15/013

  Separation; Purification; Concentration · CPC title

• C01B2210/001

  by making use of membranes · CPC title