Composition for an additive manufacturing process

Patent metadata

Field	Value
Publication number	US-2025011620-A1
Application number	US-202218694681-A
Country	US
Kind code	A1
Filing date	Sep 30, 2022
Priority date	Oct 8, 2021
Publication date	Jan 9, 2025
Grant date	—

Abstract

The present invention concerns a composition comprising at least one polymer, wherein the polymer solidifies from a molten material in a substantially amorphous or completely amorphous form. The present invention further concerns a process for the production of the composition in accordance with the invention, as well as a structural component comprising a composition in accordance with the invention and the use of the composition in accordance with the invention.

First claim

1 . A composition comprising:
at least one polymer, wherein the polymer is in the form of polymer particles and wherein the polymer is selected from at least one thermoplastic polymer,
wherein the at least one polymer solidifies from a molten material in at least a substantially amorphous or completely amorphous form and is producible as such,
wherein a melting temperature of the polymer is at least 280° C.,
and/or
in that a specific melting enthalpy of the polymer is at least 28 J/g and/or wherein a specific melting enthalpy of the polymer is up to 150 J/g.

2 . A composition of claim 1 ,
wherein the composition can be obtained by means of precipitation from a first moderate solvent or a mixture of the first and at least one further moderate solvent, and wherein the first moderate solvent and/or the further moderate solvent is selected from at least one organic moderate solvent.

3 . The composition of claim 1 , wherein the thermoplastic polymer is selected from at least one polyetherimide, polycarbonate, polyarylethersulphone, polyphenylene oxide, acrylonitrile-butadiene-styrene copolymerisate, acrylonitrile-styrene-acrylate copolymerisate, polyvinylchloride, polyacrylate, polyester, polyamide, polyaryletherketone, polyether, polyurethane, polyimide, polyamideimide, polyolefin, polyarylene sulphide, polysiloxane as well as their copolymers and/or at least one polymer blend based on the polymers and/or copolymers cited above.

4 . The composition of claim 1 , wherein the thermoplastic polymer comprises at least one partially crystalline polymer and/or at least one partially crystalline copolymer and/or at least one partially crystalline polymer blend.

5 . The composition of claim 1 , wherein the thermoplastic polymer comprises at least one polyetherimide, and wherein the polyetherimide has repeating units in accordance with

and/or repeating units in accordance with

and/or repeating units in accordance with

6 . The composition of claim 1 , wherein the moderate solvent is selected from group formed by an aromatic, non-halogenated homocyclic solvent.

7 . The composition of claim 1 , wherein a solubility parameter of the medium or solvent is at least at least 5 MPa 1/2 smaller and/or at most 5 MPa 1/2 higher than a solubility parameter of the at least one polymer.

8 . The composition of claim 1 , wherein the at least one medium or solvent is selected from dimethylphthalate and/or acetophenone.

9 . A process for the production of a composition of claim 1 , wherein the process comprises at least the following steps:
(i) providing at least one polymer material, wherein the polymer material is selected from at least one thermoplastic polymer, (ii) mixing the polymer material with a solvent at a first temperature, wherein at the first temperature, the medium does not dissolve the at least one polymer and wherein at a second temperature, which is higher than the first temperature, the medium at least partially dissolves the one polymer, (iii) heating the polymer-solvent mixture at least up to the second temperature, in order to dissolve the polymer in the solvent, (iv) cooling the polymer-solvent mixture in order to precipitate the polymer out of the solvent, and (v) obtaining the powdered material.

10 . The process for the production of a composition of claim 1 , wherein the process additionally comprises at least one of the following steps:
(a) adding at least one first auxiliary substance to the polymer or the polymer-solvent mixture in accordance with step ii) or iii) cited above, and/or (b) adding at least one first auxiliary substance or anti-agglomeration agent to the composition or to the powdered material, wherein the addition is carried out after step v) cited above.

11 . The process for the production of a composition of claim 9 , wherein the polymer-solvent mixture contains at least 10% by weight and/or at most 25% by weight.

12 . The process for the production of a composition of claim 9 , wherein a moderate solvent is used which is selected from at least one non-halogenated, aromatic moderate solvent,
wherein a solubility parameter of the moderate solvent is at least at least 5 MPa 1/2 smaller and/or at most 5 MPa 1/2 higher than a solubility parameter of the at least one polymer, and/or wherein the moderate solvent is selected from at least dimethylphthalate and/or acetophenone, wherein the at least one polymer is selected from at least one polyimide and/or a polyarylethersulphone, from at least one polyetherimide.

13 . The process for the production of a composition of claim 9 , wherein the cooling of the polymer-solvent mixture from a second temperature to a third temperature is carried out in a manner such that a cooling rate for the polymer-solvent mixture is obtained at a cooling rate of at least 1.5° C./min and/or at most 2° C./min.

14 . A process for the production of a three-dimensional object, comprising the steps of:
(i) applying a layer of a composition of claim 1 , to a construction area, wherein the composition comprises at least one polymer, (ii) selectively consolidating the applied layer of the powdered material at positions which correspond to a cross section of the object to be produced by means of an irradiation unit, and (iii) dropping the carrier down and repeating the steps of application and of consolidation until the three-dimensional object has been completed.

15 . (canceled)

16 . A three-dimensional object comprising a composition of claim 1 .

17 . A three-dimensional object comprising a composition of claim 1 , wherein the three-dimensional object is in the amorphous or at least substantially amorphous form.

18 . Use of a composition of claim 1 , which has been produced from the group formed by the powder bed-based processes comprising laser sintering, high speed sintering, binder jetting, multi jet fusion, selective mask sintering, selective laser melting or laser pro fusion.

Assignees

• Eos Gmbh Electro Optical Systems

Inventors

• Fischer Sybille
• Pfister Andreas
• Freihart Karl
• Sesseg Jens
• Unger Laura
• Schmidt Jochen
• Bück Amdreas
• Dechet Maximilian

Classifications

• C09D5/03

  Powdery paints · CPC title

• C08J2379/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C08J3/14 Primary

  by precipitation from solutions {(C08J3/122 takes precedence)} · CPC title

• C08J3/11

  from solid polymers · CPC title

• C08J3/095

  Oxygen containing compounds · CPC title