Process for the recovery of lithium

Patent metadata

Field	Value
Publication number	US-2024384370-A1
Application number	US-202418666885-A
Country	US
Kind code	A1
Filing date	May 17, 2024
Priority date	May 19, 2023
Publication date	Nov 21, 2024
Grant date	—

Abstract

The present invention relates to a process for the concentration of lithium in metallurgical fumes wherein a metallurgical charge is smelted, thus obtaining a molten bath comprising a slag phase and optionally an alloy phase and fuming the lithium from the molten slag, by addition of a halogen intermediate, wherein said halogen intermediate is a gaseous halogen or gaseous halogen compound.

First claim

1 .- 15 . (canceled)

16 . Process for the concentration of lithium in metallurgical fumes, comprising the steps of:
providing a metallurgical molten bath furnace; preparing a metallurgical charge comprising lithium-bearing material, and fluxing agents; smelting the metallurgical charge and fluxing agents in in said furnace, thereby obtaining a molten bath comprising a slag phase and optionally an alloy phase; and, optionally separating the alloy and the slag phase; fuming a major part of the lithium as Li halide from the molten slag, by addition of a halogen intermediate; wherein said halogen intermediate is a gaseous halogen, gaseous hydrogen halide or a combination thereof.

17 . Process according to claim 16 , wherein the halogen or hydrogen halide is added in an amount corresponding to a stoichiometric excess with respect to the Li in the fumes.

18 . Process according to claim 17 , wherein the stoichiometric excess of halogen or hydrogen halide amounts to at least 10%.

19 . Process according to claim 16 , wherein the halogen or hydrogen halide is selected from chlorine, bromine, iodine, hydrogen chloride, hydrogen bromide, hydrogen iodide and mixtures thereof.

20 . Process according to claim 16 , wherein the process comprises at least one step in which the halogen intermediate used for the fuming of Li halide from the molten slag is produced from the Li halide fumed from the molten slag, which is reacted under conditions sufficient to produce said halogen intermediate and a lithium product, and wherein halogen is selected from Cl, Br and I.

21 . Process according to claim 16 , wherein the halogen intermediate may further comprise alkali chloride, alkaline earth chloride or combinations thereof, more specifically the halogen intermediate may further comprise AlCl 3 , MgCl 2 and/or CaCl 2 .

22 . Process according to claim 16 , wherein the lithium-bearing material also contains nickel and/or cobalt, and wherein a pO 2 is maintained that is sufficiently low to reduce a major part of at least one of nickel and cobalt to the alloy phase.

23 . Process according to claim 22 , wherein hydrogen, carbon or a combination thereof is added.

24 . Process according to claim 20 , wherein the step in which the halogen intermediate is produced comprises an aqueous electrolysis step or a molten salt electrolysis.

25 . Process of claim 24 , wherein the step in which the halogen intermediate is produced comprises
an aqueous electrolysis and a conversion reaction, in which the Li halide obtained from the fuming is converted into different lithium compound.

26 . Process of claim 25 , wherein the conversion reaction is (a) a reaction of the Li halide with alkali hydroxide to alkali halide and lithium hydroxide, or (b) a reaction of the Li halide with an alkali carbonate to obtain lithium carbonate and alkali halide.

27 . Process according to claim 24 , wherein the aqueous electrolysis is an electrolysis of alkali halide to obtain alkali hydroxide and the halogen intermediate.

28 . Process according to claim 24 , wherein the molten salt electrolysis comprises an electrolysis of a salt melt comprising the Li halide under conditions sufficient to obtain lithium metal and the halogen intermediate.

29 . Process according to claim 24 , wherein the aqueous electrolysis step comprises an electrolysis of an aqueous solution comprising the Li halide under conditions sufficient to obtain lithium hydroxide and the halogen intermediate that comprises hydrogen chloride, chlorine or mixtures thereof.

30 . Process for the concentration of lithium in metallurgical fumes according to claim 16 , comprising the steps of:
providing a metallurgical molten bath furnace; preparing a metallurgical charge comprising lithium-bearing material, and fluxing agents; smelting the metallurgical charge and fluxing agents in in said furnace, thereby obtaining a molten bath comprising a slag phase and optionally an alloy phase; and, optionally separating the alloy and the slag phase; fuming a major part of the lithium as Li halide from the molten slag, by addition of a first halogen intermediate; converting the Li halide fumed from the molten slag into a different lithium compound and a—second halogen intermediate; re-using the second halogen intermediate in the step of fuming as first halogen intermediate; wherein halogen is selected from Cl, Br and I, and wherein the first and second halogen intermediate comprise a gaseous halogen, gaseous hydrogen halide or a combination thereof.

Assignees

• Umicore Nv

Inventors

• Scheunis Lennart
• Schutyser Wouter
• Verhees Pieter

Classifications

• Y02W30/84

  Recycling of batteries or fuel cells · CPC title

• Y02P10/20

  Recycling · CPC title

• H01M10/54

  Reclaiming serviceable parts of waste accumulators · CPC title

• C25C3/02

  of alkali or alkaline earth metals · CPC title

• C25B15/081

  Supplying products to non-electrochemical reactors that are combined with the electrochemical cell, e.g. Sabatier reactor · CPC title