Method for processing alloy

Patent metadata

Field	Value
Publication number	US-2024318282-A1
Application number	US-202218579520-A
Country	US
Kind code	A1
Filing date	Jul 14, 2022
Priority date	Jul 20, 2021
Publication date	Sep 26, 2024
Grant date	—

Abstract

The present invention provides a method that is capable of selectively obtaining nickel and/or cobalt from an alloy, which contains copper. A method comprises: a leaching step S 1 in which an alloy that contains copper as well as nickel and/or cobalt is subjected to a leaching treatment by means of an acid solution in the coexistence of a sulfurizing agent, thereby obtaining a leachate and a leaching residue; and a reduction step S 2 in which a reducing agent is added to the thus-obtained leachate so as to reduce the leachate, thereby obtaining a post-reduction solution and a reduction residue. This method is characterized in that the reduction is carried out in the reduction step S 2 , while controlling the addition amount of the reducing agent so that the redox potential of the leachate is 0 mV or less as determined where a silver/silver chloride electrode is the reference electrode.

First claim

1 . An alloy processing method comprising:
a leaching step that comprises subjecting an alloy comprising nickel and/or cobalt and copper to a leaching treatment with an acid solution in the presence of a sulfurizing agent to obtain a leachate and a leached residue; and a reduction step that comprises subjecting the leachate to a reduction treatment by adding a reducing agent to the leachate to obtain a post-reduction solution and a reduced residue, wherein, in the reduction step, the reduction treatment is performed by controlling an addition amount of the reducing agent so that oxidation-reduction potential of the leachate is 0 mV or less, as a value determined using a silver/silver chloride electrode as a reference electrode.

2 . The alloy processing method according to claim 1 , wherein at least some of the alloy to be subjected to the leaching treatment in the leaching step is used as the reducing agent to be added in the reduction step.

3 . The alloy processing method according to claim 1 , wherein the reduced residue obtained by the treatment in the reduction step is subjected to the leaching treatment in the leaching step.

4 . The alloy processing method according to claim 1 , wherein the alloy includes an alloy obtained by melting a waste battery of a lithium ion battery.

5 . The alloy processing method according to claim 1 , wherein, in the leaching step, the leaching treatment is performed in the presence of the sulfurizing agent in an amount of 1 equivalent or more and 1.25 equivalents or less with respect to copper contained in the alloy.

6 . The alloy processing method according to claim 1 , wherein, in the leaching step, the leaching treatment is performed so that the pH of the obtained leachate is in a range of 0.8 or more and 1.6 or less.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Takenouchi Hiroshi
• HEGURI Shin-ichi
• Asano Satoshi
• Shouji Hirofumi
• Matsuoka Itsumi
• Sanjo Shota
• MATSUGI Takumi

Classifications

• C22B23/0461

  by chemical methods · CPC title

• C22B23/043 Primary

  Sulfurated acids or salts thereof · CPC title

• C22B7/005

  Separation by a physical processing technique only, e.g. by mechanical breaking · CPC title

• C22B1/005

  Preliminary treatment of scrap (C22B1/02 - C22B1/26 take precedence) · CPC title

• C22B3/08

  Sulfuric acid {, other sulfurated acids or salts thereof} · CPC title