Direct conversion of air to ammonia via advanced manufactured electrochemical reactors

Patent metadata

Field	Value
Publication number	US-2024301569-A1
Application number	US-202418667931-A
Country	US
Kind code	A1
Filing date	May 17, 2024
Priority date	Nov 4, 2021
Publication date	Sep 12, 2024
Grant date	—

Abstract

An advanced manufactured electrochemical reactor to convert air (N2+O2) to nitric acid (HNO3) and ammonia (NH3). The electrochemical reactor platform can be tailored via advanced manufacturing to improve activity, selectivity, energy efficiency and stability of the reactions.

First claim

What is claimed is:

1 . An apparatus for converting air to ammonia, the apparatus comprising:
an anode gas compartment for receiving air; an anode electrocatalyst coupled to the anode gas compartment; a cathode gas compartment; a cathode electrocatalyst coupled to the cathode gas compartment; and an electrolyte compartment comprising a liquid electrolyte, wherein the electrolyte compartment is positioned between the anode electrocatalyst and the cathode electrocatalyst, wherein the anode electrocatalyst is operably configured to convert nitrogen from the air to nitrate at the anode electrocatalyst, wherein the cathode electrocatalyst is operably configured to convert the nitrate to the ammonia at the cathode electrocatalyst.

2 . The apparatus for converting air to ammonia of claim 1 , wherein the anode electrocatalyst is selected from the group of electrocatalysts consisting of: platinum (Pt), titanium (Ti), iridium (Ir), nickel (Ni), iron (Fe), ruthenium (Ru), palladium (Pd), tin (Sn), and gallium (Ga).

3 . The apparatus for converting air to ammonia of claim 1 , wherein the anode electrocatalyst includes an oxide and/or an alloy of one or more elements selected from the group consisting of: platinum (Pt), titanium (Ti), Iridium (Ir), Nickle (Ni), Iron (Fe), Ruthenium (Ru), Palladium (Pd), tin (Sn), gold (Au), silver (Ag), copper (Cu), cobalt (Co), and Gallium (Ga).

4 . The apparatus for converting air to ammonia of claim 1 , wherein the cathode electrocatalyst is selected from the group of electrocatalysts consisting of: silver (Ag), gold (Au), copper (Cu), platinum (Pt), titanium (Ti), iridium (Ir), nickel (Ni), Iron (Fe), and tin (Sn).

5 . The apparatus for converting air to ammonia of claim 1 wherein the cathode electrocatalyst includes an oxide and/or alloy of one or more elements selected from the group consisting of: silver (Ag), gold ((Au), copper (Cu), platinum (Pt), titanium (Ti), iridium (Ir), nickel (Ni), Iron (Fe), and tin (Sn).

6 . The apparatus for converting air to ammonia of claim 1 , further comprising a silicon gasket positioned between at least two adjacent components of the apparatus.

7 . The apparatus for converting air to ammonia of claim 1 , wherein the anode gas compartment is open to the air.

8 . The apparatus for converting air to ammonia of claim 1 , comprising a conduit connected to the cathode gas compartment for flowing a sweep gas.

9 . The apparatus for converting air to ammonia of claim 1 , wherein the anode gas compartment is configured to flow air into the apparatus wherein a N 2 component of the air is configured to react at the anode electrocatalyst.

10 . The apparatus for converting air to ammonia of claim 1 , wherein the liquid electrolyte comprises a carbonate.

11 . The apparatus for converting air to ammonia of claim 1 , wherein the apparatus converts nitrogen and oxygen to nitrate and the ammonia.

12 . The apparatus for converting air to ammonia of claim 11 , further comprising a system for converting the ammonia and nitrate to fertilizers.

13 . A method of converting a feed gas to a reduced product, comprising:
providing an electrochemical reactor, wherein the electrochemical reactor comprises:
an anode gas compartment,
an anode electrocatalyst coupled to the anode gas compartment,
a cathode gas compartment;
a cathode electrocatalyst coupled to the cathode gas compartment; and
an electrolyte compartment comprising a liquid electrolyte, wherein the electrolyte compartment is positioned between the anode electrocatalyst and the cathode electrocatalyst;
directing the feed gas through the anode gas compartment to the anode electrocatalyst to convert one or more components of the feed gas to an intermediate in the liquid electrolyte; and directing a sweep gas through the cathode gas compartment to convert the intermediate in the liquid electrolyte to the reduced product.

14 . The method of claim 13 , wherein the anode electrocatalyst includes an electrocatalyst selected from a group consisting of: platinum (Pt), titanium (Ti), iridium (Ir), nickel (Ni), iron (Fe), ruthenium (Ru), palladium (Pd), tin (Sn), gold (Au), silver (Ag), copper (Cu), cobalt (Co), and gallium (Ga).

15 . The method of claim 13 , wherein the reactor operates on the gases at a temperature of about room temperature.

16 . The method of claim 13 , wherein the reactor operates on the gases at about ambient pressure.

17 . The method of claim 13 , wherein the feed gas is air, and the reduced product is ammonia.

18 . The method of claim 13 , wherein the one or more components of the feed gas are selected from the group consisting of: N 2 , Air, CO 2 , Ar, He, H 2 , H 2 O, O 2 , and combinations thereof.

19 . The method of claim 13 , wherein the liquid electrolyte comprises a carbonate.

20 . The method of claim 13 , wherein the sweep gas is an inert gas.

Assignees

• L Livermore Nat Security Llc

Inventors

• Feaster Jeremy Taylor
• Aines Roger
• Akhade Sneha Anil
• Baker Sarah
• Campbell Patrick
• Hernandez Maira Ceron
• Davis Jonathan Tesner
• Duoss Eric

Classifications

• C25B11/032

  Gas diffusion electrodes · CPC title

• C25B11/047

  Ceramics · CPC title

• C25B11/046

  Alloys · CPC title

• C25B9/17

  Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof · CPC title

• C25B15/08

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title