Gelling citrus fibers and methods of manufacture

Patent metadata

Field	Value
Publication number	US-2024270943-A1
Application number	US-202218568399-A
Country	US
Kind code	A1
Filing date	Jun 7, 2022
Priority date	Jun 8, 2021
Publication date	Aug 15, 2024
Grant date	—

Abstract

The technology disclosed in this specification pertains to pectin containing cellulosic materials. The cellulosic material is modified so that it can form strong gels when dispersed in aqueous solution. Also disclosed are methods for modifying the cellulosic materials, including, at least in some embodiments, methods to monitor changes in the infrared spectrum of the cellulosic material that happen during a modification reaction to control the reaction and obtain end products capable of making gels having the desired gel strength.

First claim

1 . A gelling citrus fiber material comprising:
a) a cellulosic component and b) an associated pectin component in an amount of from 40% to 50% (% galacturonic acid (% GA)); wherein the pectin component has a degree of esterification (% DE) of from about 10% to about 80%; and wherein the gelling citrus fiber material has a molecular weight from about 50 kDa to about 275 kDa.

2 . (canceled)

3 . (canceled)

4 . (canceled)

5 . (canceled)

6 . (canceled)

7 . (canceled)

8 . The gelling citrus fiber material of claim 1 capable of forming a gel in an aqueous solution when used in an amount of from about 0.5% to about 5% (wt % of the gel).

9 . The gelling citrus fiber material of claim 1 being capable of forming a test gel having a gel strength from about 10 to about 400 q at 20° C. in an aqueous solution when used in an amount from about 0.5% to about 5% (wt % of the gel)

10 . (canceled)

11 . (canceled)

12 . (canceled)

13 . (canceled)

14 . (canceled)

15 . The gelling citrus fiber material of claim 1 wherein the cellulosic component forms a matrix and at least a portion of the pectin component is within the matrix.

16 . A method for making a gelling citrus fiber material claim comprising:
a. mixing a comminuted citrus peel comprising a pectin component and a cellulosic component with an acidic solution to obtain an acid washed citrus peel; b. mixing the acid washed citrus peel with an alkaline solution to reduce the degree of esterification (% DE) of the pectin component thereby obtaining de-esterified citrus peel; and c. recovering the de-esterified citrus peel to obtain the gelling citrus fiber material.

17 . The method of claim 16 further comprising mixing the de-esterified citrus peel with a solution comprising an organic solvent to wash the de-esterified citrus peel.

18 . The method of claim 16 further comprising prior to step a) obtaining a citrus peel material and the milling citrus peel material to obtain the comminuted citrus peel.

19 . The method of claim 16 wherein the acidic solution has a pH of less than 3 and the comminuted citrus peal is mixed with the acidic solution for a time from about 10 to about 70 minutes.

20 . (canceled)

21 . (canceled)

22 . The method of claim 16 wherein the alkaline solution has a pH of greater than about 8.

23 . The method of claim 16 wherein the acid washed citrus peel is mixed with the alkaline solution at a temperature from about 1° C. to about 30° C.

24 . (canceled)

25 . A method of making a gelling citrus fiber, the fiber comprising a pectin component and a cellulosic component, the method comprising:
a. recording a measured spectrum of the material; b. and evaluating the spectrum against a model that correlates the spectrum against a second parameter of one or more of the pectin component or cellulosic component containing cellulosic material wherein the spectrum is evaluated at least within a wavenumber range selected from the group consisting of:
i. a wavenumber range from about 1400 to about 845 cm −1 .

26 . The method of claim 25 wherein the spectrum is measured using infrared spectroscopy.

27 . (canceled)

28 . The method of claim 25 wherein the spectrum is measured in a reaction vessel during a chemical reaction that alters the pectin component containing cellulosic material and wherein, the chemical reaction is altering one or more of: degree of esterification, total pectin component content, or molecular weight of the pectin component containing cellulosic material.

29 . The method of claim 25 wherein the spectrum is measured at least during a de-esterification step.

30 . (canceled)

31 . The method of claim 25 wherein the spectrum is measured from a sample obtained during taken during a de-esterification step.

32 . The method claim 25 further comprising adjusting one parameter of the chemical reaction based on the evaluation of the spectrum.

33 . (canceled)

34 . (canceled)

35 . (canceled)

36 . (canceled)

37 . A composition comprising: a gelling citrus fiber material and a second ingredient; wherein the gelling citrus fiber material comprises a) a cellulosic component and b) an associated pectin component in an amount of from 40% to 50% (% galacturonic acid (% GA)), the pectin component has a degree of esterification (% DE) of from about 10% to about 80% and the gelling citrus fiber material having a molecular weight from about 50 kDa to about 275 kDa.

38 . The composition of claim 37 wherein the second ingredient is an aqueous ingredient, and wherein the gelling citrus fiber material is used in an amount of from about 0.1% to about 10%.

39 . (canceled)

Assignees

• Corn Products Dev Inc

Inventors

• Welchoff Marjorie
• Carver Kelly
• Ghasemzadeh-Barvarz Massoud
• Coutros-Hoffmann Stella
• Crowe Matthew
• Hirsch Julie
• Dieng Senghane
• Lucero Carlos
• Tzeng John
• Medic Jelena

Classifications

• C08L2201/54

  Aqueous solutions or dispersions · CPC title

• C08L1/02

  Cellulose; Modified cellulose · CPC title

• C08J2305/06

  Pectin; Derivatives thereof · CPC title

• C08J2301/02

  Cellulose; Modified cellulose · CPC title

• C08J3/075

  Macromolecular gels · CPC title