Chiral magnetic nanocoil and synthesis methods thereof

Patent metadata

Field	Value
Publication number	US-2024254636-A1
Application number	US-202318390703-A
Country	US
Kind code	A1
Filing date	Dec 20, 2023
Priority date	Jan 30, 2023
Publication date	Aug 1, 2024
Grant date	—

Abstract

Disclosed herein is a technique for synthesizing chiral magnetic nanocoils using an electrodeposition technique, which can be used to fabricate magnetic nanosensors capable of generating an electric field by strongly reacting to an external magnetic field, such as Faraday's law of electromagnetic induction at the nanoscale, depending on the coil shape of the nanostructure. In accordance with one embodiment, a method of synthesizing a chiral magnetic nanocoil may include generating a primary particle composed of metal ions by applying an external electric field, binding a chiral molecule to a surface of the generated primary particle, and controlling an assembly direction of a next primary particle by the bound chiral molecule.

First claim

What is claimed is:

1 . A chiral magnetic nanocoil comprising:
a primary particle generated with metal ions by applying an external electric field; and a chiral molecule bound to a surface of the generated primary particle, wherein the bound chiral molecule controls an assembly direction of a next primary particle and an orientation of another shaping molecule.

2 . The chiral magnetic nanocoil of claim 1 , wherein an influence of the chiral molecule is controlled by adjusting at least one of an intensity of the external electric field, a concentration of metal ion precursors and additives, or a concentration of the chiral molecule.

3 . The chiral magnetic nanocoil of claim 1 , wherein the chiral molecule is bound to the surface of the generated primary particle by binding cinchonine as a chiral modifier of a first orientation.

4 . The chiral magnetic nanocoil of claim 3 , wherein the cinchonine is bound as the chiral modifier of the first orientation by binding C 19 H 22 N 2 O·½H 2 SO 4 of a concentration within a selected range as the chiral modifier of the first orientation.

5 . The chiral magnetic nanocoil of claim 3 , wherein the chiral molecule is bound to the surface of the generated primary particle by binding cinchonidine as a chiral modifier of a second orientation opposite to the first orientation.

6 . The chiral magnetic nanocoil of claim 4 , wherein the cinchonidine is bound as a chiral modifier of a second orientation by binding C 19 H 22 N 2 O of a concentration within a selected range as the chiral modifier of the second orientation.

7 . The chiral magnetic nanocoil of claim 6 , wherein a concentration of the chiral modifier is designed taking into account a volume ratio of an anodic aluminum oxide (AAO) template and a concentration of metal ions.

8 . The chiral magnetic nanocoil of claim 7 , wherein, when the AAO template is within a range of 70 to 300 nm in diameter and 10 to 100 μm in height, the chiral magnetic nanocoil is synthesized by adjusting a concentration of the metal ions and the chiral modifier in a precursor solution to a selected ratio.

9 . The chiral magnetic nanocoil of claim 7 , wherein, when the concentration of the metal ions is 50-200 mM based on the AAO template having a size of one nanopore of 200 nm in diameter and 60 μm in height, the concentration of the chiral modifier of the first orientation or the second orientation is designed in a range of [helical modifier]:[chiral modifier]=60-80 mM:5-50 μM (1200-16000:1).

10 . The chiral magnetic nanocoil of claim 1 , wherein, after adding a chiral modifier of a first orientation or a chiral modifier of a second orientation to a solution containing a metal precursor and at least one additive, a small amount of acid is added to adjust pH of the solution to 1.0 to 3.0, and then a nanopore template is filled and electrodeposited with the solution.

11 . A method of synthesizing a chiral magnetic nanocoil, the method comprising:
generating a primary particle composed of metal ions by applying an external electric field; binding a chiral molecule to a surface of the generated primary particle; and controlling an assembly direction of a next primary particle or an orientation of another shaping molecule by the bound chiral molecule.

12 . A nanopart comprising the chiral magnetic nanocoil of claim 1 .

Assignees

• Univ Korea Res & Bus Found
• Korea Inst Sci & Tech
• Seoul Nat Univ R&Db Foundation

Inventors

• Kim Young Keun
• Jeon Yoo Sang
• Jeong Eunjin
• Yoo Sung Jong
• Nam Ki Tae
• Im Sang Won

Classifications

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• B82B1/00

  Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units · CPC title

• C25D11/02

  Anodisation · CPC title

• C25D9/02

  with organic materials · CPC title

• C25D3/02

  from solutions (C25D5/34 - C25D5/46 take precedence) · CPC title