Master batch composition for a weight-reduced plastic product and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-2024254292-A1
Application number	US-202418635031-A
Country	US
Kind code	A1
Filing date	Apr 15, 2024
Priority date	Jun 2, 2022
Publication date	Aug 1, 2024
Grant date	—

Abstract

A master batch composition for a weight-reduced plastic product includes a bi-component carrier resin, a core-shell foaming agent, and at least one lubricant. The core-shell foaming agent includes at least one outer polymeric shell and at least one inner foaming agent core. The outer polymeric shell encapsulates the inner foaming agent core. The inner foaming agent core includes alkane. The master batch composition is configured to be integrated into the weight-reduced plastic product by extrusion blow molding with a base plastic resin to create a foamed plastic having a foaming pore size from 10 to 80 μm.

First claim

What is claimed is:

1 . A method of preparing a master batch composition for a weight-reduced plastic product, comprising:
mixing a master batch composition to form a melt mixture in an internal mixer at a first temperature, wherein the master batch composition comprises a bi-component carrier resin, a core-shell foaming agent, and at least one lubricant, and the first temperature is a melting temperature of the bi-component carrier resin, wherein the core-shell foaming agent includes at least one outer polymeric shell and at least one inner foaming agent core, the polymeric outer polymeric shell encapsulates the inner foaming agent core, and the inner foaming agent core includes alkane; single-screw extruding and pelletizing the melt mixture at a second temperature ranging between 50 and 160° C. to form pellets; mixing the master batch composition in a form of pellets with a base plastic resin to form a molding mixture in an internal mixer, wherein the master batch composition has a particle size similar to that of the base plastic resin, thereby eliminating the need for additional foaming agents; single-screw extruding the molding mixture at a temperature ranging between 180 and 220° C. to form a product preform; and extrusion blow molding the product preform to form the weight-reduced plastic product, wherein the weight-reduced plastic product has a foaming pore size from 10 to 80 μm, and wherein the weight-reduced plastic product contains the master batch composition ranging from 1 to 10 wt %.

2 . The method of claim 1 , wherein step of mixing a master batch composition to form a melt mixture in an internal mixer at a first temperature does not require pre-foaming.

3 . The method of claim 1 , wherein step of extrusion blow molding the product preform to form the weight-reduced plastic product comprising:
heating a mold with a cavity according to the desired final shape of the weight-reduced plastic product to a temperature between 170° C. and 230° C.; placing the product preform into the cavity formed by two halves of the mold; introducing air into the cavity through a supply system, wherein the supply system has a blowing pressure ranges between 0.25 and 0.6 MPa,
wherein the product preform is subjected to air compression, causing the product preform to expand and conformingly overlay walls of the two halves of the mold, resulting in the formation of the weight-reduced plastic product.

4 . The method of claim 1 , wherein the master batch composition comprises 40 to 90 wt % of the bi-component carrier resin, 10 to 50 wt % of the core-shell foaming agent, and 1 to 30 wt % of at least one lubricant.

5 . The method of claim 1 , wherein the single-screw extruding comprises a die temperature ranging between 170 and 230° C., a screw rotation speed ranging between 15 and 17 Hz, and a blow pressure ranging between 0.25 and 0.6 MPa.

6 . The method of claim 1 , wherein the melting temperature of the bi-component carrier resin is in a range of 50° C. to 160° C.

7 . The method of claim 1 , wherein the bi-component carrier resin comprises thermoplastic polymers and their blends selected from polyethylene (PE) and ethylene vinyl acetate (EVA).

8 . The method of claim 7 , wherein the polyethylene comprises one or more linear low-density polyethylene, low-density polyethylene, and high-density polyethylene.

9 . The method of claim 8 , wherein the bi-component carrier resin is a copolymer of linear low-density polyethylene and ethylene vinyl acetate.

10 . The method of claim 1 , wherein the outer polymeric shell is selected from the group consisting of poly lactic acid (PLA), poly(lactic-co-glycolic acid)(PLGA), polystyrene (PS), poly methacrylate (PMA), poly methyl Methacrylate (PMMA), or polymers comprising one or more monomers of acrylonitrile, methacrylonitrile, 3-butene nitrile, methacrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, methyl ethyl acrylate, glycidyl methacrylate, or any combination thereof, and the inner foaming agent core is selected from the group consisting of pentane, butane, n-hexane, n-heptane, isooctane or any combination thereof.

11 . The method of claim 1 , wherein the at least one lubricant comprises one or more lubricant selected from paraffin oil, paraffin wax, stearic acid and their blends.

12 . The method of claim 1 , wherein the base plastic resin comprises one or more polyethylene and polypropylene.

13 . The method of claim 1 , wherein the weight-reduced plastic product achieves a weight reduction ranging from 12.4% to 16.7% while maintaining the same thickness compared to a plastic product without the master batch composition, and the weight-reduced plastic product exhibits a tensile strength retention of greater than 85%.

Assignees

• Nano & Advanced Materials Inst Ltd

Inventors

• Chen Yueying
• Jiang Qi
• Sun Dongli
• Liu Xianqiao

Classifications

• B29C44/50

  using pressure difference, e.g. by extrusion or by spraying {(B29C44/468 takes precedence)} · CPC title

• B29C44/3446

  Feeding the blowing agent · CPC title

• B29C44/3461 Primary

  Making or treating expandable particles · CPC title

• C08J2323/06

  Polyethene · CPC title

• C08J2205/044

  Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter · CPC title