Method for preparing nickel sulfate from ferronickel

Patent metadata

Field	Value
Publication number	US-2024018013-A1
Application number	US-202318374630-A
Country	US
Kind code	A1
Filing date	Sep 28, 2023
Priority date	Aug 25, 2021
Publication date	Jan 18, 2024
Grant date	—

Abstract

The present disclosure discloses a method for preparing nickel sulfate from ferronickel, including: S1: in a high-pressure oxygen environment, mixing crushed ferronickel with sulfuric acid, introducing a carbon monoxide gas to allow a reaction, and conducting solid-liquid separation (SLS) to obtain a filtrate and a filter residue; S2: adding an oxidizing agent and a precipitating agent successively to the filtrate, controlling a pH of the filtrate, and conducting SLS to obtain a nickel-containing filtrate and an iron hydroxide precipitate; and S3: subjecting the nickel-containing filtrate to extraction and back-extraction to obtain a nickel sulfate solution. In the present disclosure, the carbon monoxide gas is introduced under high-pressure acidic conditions to first react with nickel and iron to form nickel tetracarbonyl and iron pentacarbonyl, and the nickel tetracarbonyl and iron pentacarbonyl are oxidized by oxygen and then smoothly react with sulfuric acid to form nickel sulfate and iron sulfate.

First claim

Claims:

1 . A method for preparing nickel sulfate from ferronickel, comprising the following steps:
S1: in a high-pressure oxygen environment, mixing crushed ferronickel with sulfuric acid, introducing a carbon monoxide gas to allow a reaction, and conducting solid-liquid separation to obtain a filtrate and a filter residue, the reaction is conducted in a closed space, the carbon monoxide gas is introduced through a bottom of the crushed ferronickel, and a volume concentration of the carbon monoxide gas in the closed space is controlled at ≤2.5%; the reaction is conducted at 40° C. to 200° C.; the sulfuric acid has a concentration of 3 mol/L to 8 mol/L; S2:adding an oxidizing agent to the filtrate, and then adding a precipitating agent, controlling a pH of the filtrate, and conducting solid-liquid separation to obtain a nickel-containing filtrate and an iron hydroxide precipitate; and S3: subjecting the nickel-containing filtrate to extraction and back-extraction to obtain a nickel sulfate solution; a process of the extraction and back-extraction comprises: adding an extracting agent to the nickel-containing filtrate for nickel extraction to obtain a nickel-containing organic phase, and adding a sulfuric acid solution to the nickel-containing organic phase for nickel back-extraction to obtain the nickel sulfate solution; the extracting agent is one or more selected from the group consisting of P204, P507, DEHPA, and Cyanex272.

2 . The method according to claim 1 , wherein in S1, the reaction is conducted at a pressure of 3.0 MPa to 6.5 MPa.

3 . The method according to claim 1 , wherein in S2, the oxidizing agent is one or more selected from the group consisting of hydrogen peroxide, compressed air, chlorine, and sodium chlorate.

4 . The method according to claim 1 , wherein in S2, the precipitating agent is one or more selected from the group consisting of ammonia water, sodium hydroxide, sodium carbonate, and sodium bicarbonate.

5 . The method according to claim 1 , wherein in S 2 , the pH is 3 to 3.5.

Assignees

• Guangdong Brunp Recycling Technology Co Ltd
• Hunan Brunp Recycling Tech Co Ltd
• Hunan Brunp Ev Recycling Co Ltd

Inventors

• Yu Haijun
• Xie Yinghao
• Li Aixia
• Zhang Xuemei
• Li Changdong

Classifications

• C01G49/06

  Ferric oxide [Fe2O3] · CPC title

• C01G53/10 Primary

  Sulfates · CPC title

• C01G53/01

  Preparation or separation involving a liquid-liquid extraction, an adsorption or an ion-exchange · CPC title

• C01G99/003

  Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange · CPC title

• Y02P10/20

  Recycling · CPC title