Process for leaching metal sulfides with reagents having thiocarbonyl functional groups

Patent metadata

Field	Value
Publication number	US-10876187-B2
Application number	US-202016744012-A
Country	US
Kind code	B2
Filing date	Jan 15, 2020
Priority date	Apr 17, 2015
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

This application pertains to methods of recovering metals from metal sulfides that involve contacting the metal sulfide with an acidic sulfate solution containing ferric sulfate and a reagent that has a thiocarbonyl functional group, wherein the concentration of reagent in the acidic sulfate solution is sufficient to increase the rate of metal ion extraction relative to an acidic sulfate solution that does not contain the reagent, to produce a pregnant solution containing the metal ions.

First claim

What is claimed is:

1. A method of recovering at least one base metal from at least one base metal sulfide in a material, the method comprising:
contacting a material comprising at least one base metal sulfide with an acidic sulfate solution comprising a reagent having a thiocarbonyl functional group, wherein the reagent is thiosemicarbazide (TSCA), to produce a pregnant solution containing base metal ions; and
recovering the at least one base metal from the at least one base metal sulfide from the pregnant solution.

2. The method of claim 1 , wherein the acidic sulfate solution further comprises ferric sulfate.

3. The method of claim 1 , wherein the concentration of the reagent in the acidic sulfate solution is in the range of about 0.2 mM to about 30 mM.

4. The method of claim 1 , wherein the concentration of the reagent in the acidic sulfate solution is in the range of about 0.2 mM to about 20 mM.

5. The method of claim 1 , wherein the concentration of the reagent in the acidic sulfate solution is in the range of about 0.2 mM to about 10 mM.

6. The method of claim 1 , wherein the concentration of the reagent in the acidic sulfate solution is in the range of about 0.2 mM to about 5 mM.

7. The method of claim 1 , wherein the concentration of the reagent in the acidic sulfate solution is in the range of about 0.2 mM to about 4 mM.

8. The method of claim 1 , wherein the concentration of the reagent in the acidic sulfate solution is in the range of about 0.2 mM to about 3 mM.

9. The method of claim 1 , wherein the concentration of the reagent in the acidic sulfate solution is in the range of about 0.2 mM to about 2 mM.

10. The method of claim 1 , wherein the concentration of the reagent in the acidic sulfate solution is in the range of about 0.2 mM to about 1.5 mM.

11. The method of claim 1 , wherein the concentration of the reagent in the acidic sulfate solution is in the range of about 0.2 mM to about 1.0 mM.

12. The method of claim 1 , wherein the concentration of the reagent in the acidic sulfate solution is in the range of about 0.2 mM to about 0.5 mM.

13. The method of claim 1 , wherein the at least one base metal sulfide includes at least one copper sulfide.

14. The method of claim 13 , wherein the at least one copper sulfide includes chalcopyrite.

15. The method of claim 13 , wherein the at least one copper sulfide includes covellite.

16. The method of claim 13 , wherein the at least one copper sulfide includes bornite.

17. The method of claim 13 , wherein the at least one copper sulfide includes enargite.

18. The method of claim 13 , wherein the at least one copper sulfide includes a copper sulfide of the formula CuxSy wherein the x:y ratio is between 1 and 2.

19. The method of claim 13 , wherein the at least one copper sulfide of the formula CuxSy includes chalcocite.

20. The method of claim 13 , wherein the at least one copper sulfide of the formula CuxSy includes djurleite.

21. The method of claim 13 , wherein the at least one copper sulfide of the formula CuxSy includes digenite.

22. The method of claim 1 , wherein the at least one base metal sulfide includes a cadmium sulfide.

23. The method of claim 22 , wherein the cadmium sulfide is greenockite.

24. The method of claim 1 , wherein the at least one base metal sulfide includes at least one nickel sulfide.

25. The method of claim 24 , wherein the at least one nickel sulfide includes pentlandite.

26. The method of claim 24 , wherein the at least one nickel sulfide includes violarite.

27. The method of claim 1 , wherein the material is an ore.

28. The method of claim 1 , wherein the material is a concentrate of the at least one base metal sulfide.

29. The method of claim 1 , wherein the material comprises agglomerated particles.

30. The method of claim 1 , wherein ferric ions are used to oxidize the metal sulfide.

31. The method of claim 30 , wherein the ferric ions are generated at least in part by bacteria.

32. The method of claim 1 , wherein the method is a percolation leach.

33. The method of claim 32 , wherein the percolation leach is a heap leach.

34. The method of claim 1 , wherein the leach is a vat leach.

35. The method of claim 1 , wherein the method is a tank leach.

36. The method of claim 1 , wherein the method is a column leach.

37. The method of claim 1 , wherein recovering the at least one base metal from the pregnant solution comprises solvent extraction and electrowinning.

38. The method of claim 1 , further comprising maintaining the operating potential of the acidic sulfate solution above 500 mV vs Ag/AgCl.

Assignees

• Univ British Columbia

Inventors

• Dixon David
• Asselin Edouard
• Ren Zihe

Classifications

• C25C1/08

  of nickel or cobalt · CPC title

• C25C1/16

  of zinc, cadmium or mercury · CPC title

• C22B23/0461

  by chemical methods · CPC title

• C22B15/0089

  by chemical methods · CPC title

• C22B3/18

  with the aid of microorganisms or enzymes, e.g. bacteria or algae · CPC title