Method of producing catalyst, catalyst, and fuel cell

Patent metadata

Field	Value
Publication number	US-2023387420-A1
Application number	US-202318133114-A
Country	US
Kind code	A1
Filing date	Apr 11, 2023
Priority date	May 25, 2022
Publication date	Nov 30, 2023
Grant date	—

Abstract

Disclosed is a method of producing a catalyst. The method includes: dispersing, in an acid solution, a composite in which a plurality of raw material microparticles containing a noble metal is supported on a carbon support doped with a nitrogen atom and a first transition metal atom; immersing a noble metal member in the acid solution; and alternately blowing a first gas containing an oxidizing gas and a second gas containing a reducing gas into the acid solution.

First claim

1 . A method of producing a catalyst, comprising:
dispersing, in an acid solution, a composite in which a plurality of raw material microparticles containing a noble metal is supported on a carbon support doped with a nitrogen atom and a first transition metal atom; immersing a noble metal member in the acid solution; and alternately blowing a first gas containing an oxidizing gas and a second gas containing a reducing gas into the acid solution.

2 . The method of producing a catalyst according to claim 1 , wherein the acid solution is stirred.

3 . The method of producing a catalyst according to claim 1 , wherein the oxidizing gas is at least one selected from the group consisting of O 2 , NO x (x is an integer of 1 or more and 2 or less), N 2 O, CO 2 , and air.

4 . The method of producing a catalyst according to claim 2 , wherein the oxidizing gas is at least one selected from the group consisting of O 2 , NO x (x is an integer of 1 or more and 2 or less), N 2 O, CO 2 , and air.

5 . The method of producing a catalyst according to claim 1 , wherein the reducing gas is at least one selected from the group consisting of hydrogen, ammonia, hydrocarbon, and CO.

6 . The method of producing a catalyst according to claim 2 , wherein the reducing gas is at least one selected from the group consisting of hydrogen, ammonia, hydrocarbon, and CO.

7 . The method of producing a catalyst according to claim 1 , wherein at least one of the raw material microparticles is dissolved and micronized, and nascent microparticles are generated on the carbon support from metal ions generated by the dissolution.

8 . The method of producing a catalyst according to claim 2 , wherein at least one of the raw material microparticles is dissolved and micronized, and nascent microparticles are generated on the carbon support from metal ions generated by the dissolution.

9 . The method of producing a catalyst according to claim 3 , wherein a potential cycle due to a fluctuation in an open circuit potential of the noble metal member is enabled, and
the open circuit potential is controlled by adjusting at least one or more selected from the group consisting of a concentration of the oxidizing gas in the first gas, a supply rate of the first gas, and a supply amount of the first gas per one cycle of the potential cycle.

10 . The method of producing a catalyst according to claim 4 , wherein a potential cycle due to a fluctuation in an open circuit potential of the noble metal member is enabled, and
the open circuit potential is controlled by adjusting at least one or more selected from the group consisting of a concentration of the oxidizing gas in the first gas, a supply rate of the first gas, and a supply amount of the first gas per one cycle of the potential cycle.

11 . The method of producing a catalyst according to claim wherein a potential cycle due to a fluctuation in an open circuit potential of the noble metal member is enabled, and
the open circuit potential is controlled by adjusting at least one or more selected from the group consisting of a concentration of the reducing gas in the second gas, a supply rate of the second gas, and a supply amount of the second gas per one cycle of the potential cycle.

12 . The method of producing a catalyst according to claim 6 , wherein a potential cycle due to a fluctuation in an open circuit potential of the noble metal member is enabled, and
the open circuit potential is controlled by adjusting at least one or more selected from the group consisting of a concentration of the reducing gas in the second gas, a supply rate of the second gas, and a supply amount of the second gas per one cycle of the potential cycle.

13 . The method of producing a catalyst according to claim 1 , including a potential cycle caused by repeating a fluctuation in an open circuit potential of the noble metal member between a potential of 0 V or more and 1.0 V or less based on a standard hydrogen electrode.

14 . The method of producing a catalyst according to claim 2 , including a potential cycle caused by repeating a fluctuation in an open circuit potential of the noble metal member between a potential of 0 V or more and 1.0 V or less based on a standard hydrogen electrode.

15 . A catalyst produced by
dispersing, in an acid solution, a composite in which a plurality of raw material microparticles containing a noble metal is supported on a carbon support doped with a nitrogen atom and a first transition metal atom, immersing a noble metal member in the acid solution, and alternately blowing a first gas containing an oxidizing gas and a second gas containing a reducing gas into the acid solution.

16 . A fuel cell comprising the catalyst according to claim 15 .

Assignees

• Toyota Boshoku Kk

Inventors

• Yano Hiroshi
• Iwasaki Kouta

Classifications

• H01M4/8825 Primary

  Methods for deposition of the catalytic active composition · CPC title

• H01M4/926

  on carbon or graphite · CPC title

• C23C18/44

  using reducing agents · CPC title

• C23C18/1639

  Substrates other than metallic, e.g. inorganic or organic or non-conductive · CPC title

• C23C18/1683

  Control of electrolyte composition, e.g. measurement, adjustment (regeneration of bath C23C18/1617) · CPC title