Ultrafast flash joule heating synthesis methods and systems for performing same

Patent metadata

Field	Value
Publication number	US-2023374623-A1
Application number	US-202118246460-A
Country	US
Kind code	A1
Filing date	Sep 24, 2021
Priority date	Sep 24, 2020
Publication date	Nov 23, 2023
Grant date	—

Abstract

Ultrafast flash Joule heating synthesis methods and systems, and more particularly, ultrafast synthesis methods to recover metal from ores, fly ash, and bauxite residue (red mud).

First claim

1 . A method of recovering metal, wherein the method comprises:
(a) mixing a material with a conductive additive to form a mixture, wherein the material is prepared from ores, fly ash, and/or bauxite residue; (b) applying a voltage across the mixture to recover metal from the material, wherein
(i) the voltage is applied in one or more voltage pulses, and
(ii) duration of each of the one or more voltage pulses is for a duration period; and
(c) collecting the recovered metal, wherein the recovering and collecting of the metal comprises performing a leaching process after applying the voltage across the mixture.

2 . (canceled)

3 . The method of claim 1 , wherein the material is prepared from ore.

4 . The method of claim 1 , wherein the material is prepared from fly ash.

5 . The method of claim 1 , wherein the material is prepared from bauxite residue.

6 . The method of claim 1 , wherein the material is prepared by performing a mechanical process to transform the material into a fine powder.

7 - 11 . (canceled)

12 . The method of claim 1 , wherein the material and the conductive additive are mixed at a weight ratio in a range of 1:2 and 25:1.

13 . The method of claim 1 , wherein the voltage applied is in a range of 15 V and 300 V.

14 . The method of claim 1 , wherein
(a) mass of the mixture to which the voltage is applied is more than 1 kg; and (b) the voltage applied is between 100 V and 100,000 V.

15 . (canceled)

16 . The method of claim 1 , wherein
(a) mass of the mixture to which the voltage is applied is more than 1 kg; and (b) the current applied is between 1,000 amps and 30,000 amps.

17 . (canceled)

18 . The method of claim 1 , wherein the mixture has a resistance in the range of 0.1 ohms and 25 ohms when the voltage is applied.

19 - 23 . (canceled)

24 . The method of claim 1 , wherein the voltage pulse is performed using direct current (DC).

25 . The method of claim 1 , wherein the method is performed utilizing a pulsed direct current (PDC) Joule heating process

26 . The method of claim 1 , wherein the voltage pulse is performed using alternating current (AC).

27 . The method of claim 1 , wherein the voltage pulse is performed by using both direct current (DC) and alternating current.

28 . The method of claim 27 , wherein the method switches back and forth between the use of direct current (DC) and alternating current (AC).

29 - 30 . (canceled)

31 . The method of claim 1 , wherein the metal comprises a rare earth element.

32 . The method of claim 1 , wherein the metal comprises precious metal.

33 . The method of claim 1 , wherein
(a) the materials comprises a metal oxide; and (b) the step of applying a voltage across the mixture results in a carbothermic reaction of the metal oxide to recover the metal.

34 . The method of claim 1 , wherein the applying of the voltage across the mixture to recover the metal from the material is performed at a pressure between 0.001 and 25 atmospheres.

35 - 38 . (canceled)

39 . The method of claim 34 , wherein the method is performed using a pressurized cell.

40 . The method of claim 39 , wherein the applying of the voltage across the mixture to recover the metal from the material results in a majority of the metal remaining with graphene created by the method.

41 . The method of claim 40 , wherein the collecting of the recovered metal comprises separating the metal from the graphene.

42 . The method of claim 1 , wherein the step of collecting comprises collecting a gas stream comprising volatized products produced by the application of the voltage across the mixture.

43 . (canceled)

44 . The method of claim 1 , wherein the leachability of metals in the mixture after applying a voltage across the mixture is more than two times the leachability content of the metals in the mixture before applying the voltage across the mixture, when conducted using the same pH and same volume of aqueous treatment.

45 - 49 . (canceled)

50 . A system for performing the method of recovering metal utilizing the method of claim 1 , wherein the system comprises:
(a) a source of the mixture comprising the material and conductive additive, wherein the material is from ores, fly ash, and/or bauxite residue; (b) a cell operably connected to the source such that the mixture can be flowed into the cell and held under compression; (c) electrodes operatively connected to pressure cell; and (d) a flash power supply for applying a voltage across the mixture to recover the metal from the material.

51 . The system of claim 50 , wherein the system performs the method of recovering metal utilizing the method of claim 39 , and wherein the system further comprises:
(a) the cell that is a pressure cell; and (b) a gas supply for pressurizing the pressure cell.

52 . (canceled)

53 . The system of claim 51 , wherein the system further comprises a particle collector.

54 . The system of claim 51 , wherein the system further comprises a gas collector.

55 . (canceled)

56 . A method of recovering metal, wherein the method comprises:
(a) mixing a material with a conductive additive to form a mixture, wherein the material is prepared from ores, fly ash, and/or industrial waste; (b) applying a voltage across the mixture to recover metal from the material, wherein
(i) the voltage is applied in one or more voltage pulses, and
(ii) duration of each of the one or more voltage pulses is for a duration period; and
(c) collecting the recovered metal.

57 . The method of claim 56 , wherein the material is prepared from industrial waste.

58 . The method of claim 57 , wherein the recovering and collecting of the metal comprises performing a leaching process after applying the voltage across the mixture.

Assignees

• Univ Rice William M

Inventors

• Tour James M
• Deng Bing

Classifications

• C22B3/04

  by leaching (C22B3/18 takes precedence) · CPC title

• C22B59/00

  Obtaining rare earth metals · CPC title

• C22B11/025

  from manufactured products, e.g. from printed circuit boards, from photographic films, paper, or baths · CPC title

• C22B4/04 Primary

  Heavy metals {(C22B4/005 takes precedence)} · CPC title

• C22B4/00 Primary

  Electrothermal treatment of ores or metallurgical products for obtaining metals or alloys (obtaining iron or steel C21B, C21C) · CPC title