Systems and methods for high reactant conversion through multiple reactant flow ratio staging

Patent metadata

Field	Value
Publication number	US-2023241679-A1
Application number	US-202118003457-A
Country	US
Kind code	A1
Filing date	Jun 29, 2021
Priority date	Jun 29, 2020
Publication date	Aug 3, 2023
Grant date	—

Abstract

Reactor configurations may include one or more staged inlets and/or one or more staged outlets for gaseous and solid feedstocks. In one embodiment of the present disclosure, a reactor design for gas-solid reaction with one or more additional outlet for gas and/or solid phase is provided. In yet another embodiment, the design for a gas-solid reactor with one side inlet and two outlets for gas phase is described. In one embodiment, a reactor design with pairs of inlet and outlet for both gas and solid phase is provided. In another embodiment, a reactor design with one or more side inlets but only one outlet for gas phase is provided. In yet another embodiment, a reactor design with two inlets at the top/bottom of reactor and two side outlets for gaseous phase is described. In yet another embodiment, a reactor design with one or more side inlets and outlets for both gas and solid phases is provided.

First claim

1 . A method for operating a reactor having a top and a bottom, the method comprising:
providing, in a first flow direction, metal particles to a solids inlet of the reactor,
wherein the metal particles have at least two oxidation states; and
wherein the metal particles enter the solids inlet at a first oxidation state;
providing, in a second flow direction, an inlet gas stream to a gas inlet of the reactor, such that the first flow direction and the second flow direction are counter-current; providing a first gas outlet stream via a first gas outlet arranged proximate a top of the reactor,
wherein at least 85% of carbon species in the first gas outlet stream is in the form of carbon dioxide (CO 2 );
providing a second gas outlet stream via a second gas outlet positioned below the first gas outlet; and discharging metal particles via a solids outlet positioned proximate a bottom portion of the reactor, the metal particles being at a second oxidation state that is different from the first oxidation state,
wherein the metal particles comprise less oxygen at the solids outlet than directly below the second gas outlet.

2 . The method according to claim 1 , further comprising recycling the second gas outlet stream at a position in the reactor that is relatively higher than the second gas outlet.

3 . The method according to claim 1 , further comprising:
discharging metal particles via a second solids outlet arranged at a side of the reactor and above the bottom of the reactor, wherein the metal particles discharged at the solids outlet comprise less oxygen than the metal particles discharged at the second solids outlet.

4 . The method according to claim 3 , the metal particles being discharged through the second solids outlet at a position that is relatively higher in the reactor than the second gas outlet.

5 . The method according to claim 4 , further comprising recycling the metal particles discharged through the second solids outlet back through a second solids inlet positioned lower in the reactor than the second solids outlet.

6 . The method according to claim 1 , further comprising providing the inlet gas stream in the first flow direction such that a portion of the inlet gas stream flows co-currently with the metal particles.

7 . The method according to claim 6 , wherein the gas inlet of the reactor is positioned at a side of the reactor positioned below the top of the reactor.

8 . The method according to claim 1 , wherein the gas inlet of the reactor is positioned at the bottom of the reactor.

9 . The method according to claim 8 , further comprising providing a second gas inlet stream via a second gas inlet, the second gas inlet being positioned relatively higher in the reactor than the second gas outlet.

10 . The method according to claim 9 , further comprising recycling a portion of the second gas outlet stream back through the second gas inlet.

11 . The method according to claim 1 , wherein 60-75% of the inlet gas stream is provided in the first gas outlet stream.

12 . The method according to claim 1 , wherein at least 95% of carbon species in the first gas outlet stream is carbon dioxide (CO 2 ).

13 . The method according to claim 1 , wherein the metal particles comprise iron ore.

14 . The method according to claim 1 , wherein the inlet gas stream comprises carbon monoxide (CO) and hydrogen (H 2 ).

15 . A method for operating a reactor having a top and a bottom, the method comprising:
providing, in a first flow direction, metal oxide particles to a solids inlet of the reactor,
where the metal oxide particles have at least two oxidation states; and
wherein the metal oxide particles enter the solids inlet at a first oxidation state;
providing, in a second flow direction, a first inlet gas stream to a first gas inlet proximate the bottom of the reactor, such that the first flow direction and the second flow direction are counter-current, providing a second inlet gas stream in the second flow direction to a second gas inlet of the reactor, the second gas inlet positioned closer to a top of the reactor than the first gas inlet; providing a gas outlet stream via a gas outlet arranged near the top of the reactor,
wherein the metal oxide particles below the second gas inlet comprise more oxygen than the metal oxide particles below the first gas inlet.
wherein at least 85% of carbon in the first gas outlet stream being in the form of carbon dioxide (CO 2 ); and
discharging metal particles via a solids outlet positioned proximate a bottom portion of the reactor, the metal particles being at a second oxidation state that is different from the first oxidation state.

16 . The method according to claim 15 , further comprising discharging metal oxide particles via a second solids outlet arranged at a side of the reactor and above the bottom of the reactor.

17 . The method according to claim 15 , wherein the metal oxide particles are iron oxide particles; and
wherein the second gas inlet stream comprises carbon dioxide (CO 2 ), carbon monoxide (CO), and hydrogen (H 2 ).

18 . A reactor in a chemical looping system, the reactor comprising:
a solids inlet arranged to provide metal oxide particles in a first flow direction,
where the metal oxide particles have at least two oxidation states; and
wherein the metal oxide particles enter the solids inlet at a first oxidation state;
a first gas inlet arranged to provide an inlet gas stream in a second flow direction such that the first flow direction and the second flow direction are counter-current,
the first gas inlet positioned near a bottom of the reactor;
a second gas inlet arranged to provide a gas stream in the second flow direction,
the second gas inlet positioned closer to a top of the reactor than the first gas inlet;
a gas outlet arranged near the top of the reactor and configured to provide a gas outlet stream,
wherein the metal oxide particles below the second gas inlet comprise more oxygen than the metal oxide particles below the first gas inlet.
wherein at least 85% of carbon in the first gas outlet stream being in the form of carbon dioxide (CO 2 ); and
a solids outlet positioned near the bottom of the reactor and configured to provide metal oxide particles at a second oxidation state that is different from the first oxidation state.

19 . The reactor according to claim 18 , wherein the metal oxide particles are iron oxide particles.

20 . The reactor according to claim 19 , wherein the second gas inlet stream comprises carbon dioxide (CO 2 ), carbon monoxide (CO), and hydrogen (H 2 ).

Assignees

• Ohio State Innovation Foundation

Inventors

• Fan Liang-Shih
• Tong Andrew
• Zeng Liang
• Zhang Yitao
• Kong Frank
• Chen Yu-Yen

Classifications

• B22F9/22 Primary

  using gaseous reductors · CPC title

• B01J8/08

  with moving particles (with fluidised particles B01J8/18) · CPC title

• B22F1/145

  Chemical treatment, e.g. passivation or decarburisation · CPC title

• B01J6/008 Primary

  Pyrolysis reactions (of hydrocarbons C10G9/00) · CPC title

• B01J8/003

  in a downward flow · CPC title