Sputtering Target Comprising Al-Te-Cu-Zr Alloy, and Method for Producing Same

Patent metadata

Field	Value
Publication number	US-2017175252-A1
Application number	US-201515129464-A
Country	US
Kind code	A1
Filing date	Feb 6, 2015
Priority date	Mar 28, 2014
Publication date	Jun 22, 2017
Grant date	—

Abstract

An Al—Te—Cu—Zr alloy sputtering target, comprising 20 at % to 40 at % of Te, 5 at % to 20 at % of Cu, 5 at % to 15 at % of Zr and the remainder of Al, wherein a Te phase, a Cu phase and a CuTe phase are not present in a structure of the target. An object of the present invention is to provide an Al—Te—Cu—Zr alloy sputtering target capable of effectively reducing particle generation, nodule formation and the like upon sputtering and further capable of reducing oxygen contained in the target.

First claim

1 . An Al—Te—Cu—Zr alloy sputtering target, comprising 20 at % to 40 at % of Te, 5 at % to 20 at % of Cu, 5 at % to 15 at % of Zr and the remainder of Al, wherein a Te phase, a Cu phase and a CuTe phase are not present in a structure of the target.

2 . The Al—Te—Cu—Zr alloy sputtering target according to claim 1 , wherein an Al phase, a CuAl phase, a TeZr phase and a Zr phase are present in the structure of the target.

3 . The Al—Te—Cu—Zr alloy sputtering target according to claim 1 , having a mean grain size of 10 μm or less.

4 . The Al—Te—Cu—Zr alloy sputtering target according to claim 1 , having a purity of 3N or more and an oxygen content of 3000 wt. ppm or less.

5 . The Al—Te—Cu—Zr alloy sputtering target according to claim 1 , comprising one or more elements selected from Si, C, Ti, Hf, V, Nb, Ta, lanthanoid elements, Ge, Zn, Co, Ni, Fe, Mg, Ga, S and Se.

6 . The Al—Te—Cu—Zr alloy sputtering target according to claim 1 , having a relative density of 90% or more.

7 . A method of manufacturing an Al—Te—Cu—Zr alloy sputtering target, the method comprising the steps of: dissolving a Cu raw material and a Te raw material to produce a CuTe alloy ingot; pulverizing the CuTe alloy ingot; then hot-pressing the pulverized CuTe powder and a Zr raw material powder to produce a CuTeZr alloy; then pulverizing the CuTeZr alloy; hot-pressing the pulverized CuTeZr powder and an Al raw material powder to produce a CuTeZrAl alloy.

8 . The method of manufacturing an Al—Te—Cu—Zr alloy sputtering target according to claim 7 , wherein the pulverized CuTe powder and the Zr raw material powder are hot-pressed at a temperature of 300° C. to 400° C. to produce the CuTeZr alloy.

9 . The method of manufacturing an Al—Te—Cu—Zr alloy sputtering target according to claim 7 , wherein the pulverized CuTe powder and the Zr raw material powder are hot-pressed at a temperature of 400° C. to 600° C. to produce the CuTeZr alloy.

10 . The method of manufacturing an Al—Te—Cu—Zr alloy sputtering target according to claim 7 , wherein during the step of pulverizing the CuTeZr alloy, the alloy is pulverized under an inert atmosphere or under vacuum.

11 . A method of manufacturing an Al—Te—Cu—Zr alloy sputtering target, the method comprising the steps of: dissolving a Cu raw material and a Te raw material to produce a CuTe alloy ingot; pulverizing the CuTe alloy ingot; then hot-pressing the pulverized CuTe powder, a Zr raw material powder and an Al raw material powder to produce the CuTeZrAl alloy.

12 . The method of manufacturing an Al—Te—Cu—Zr alloy sputtering target according to claim 11 , wherein the pulverized CuTe powder, the Zr raw material powder and the Al raw material powder are hot-pressed at a temperature of 300° C. to 600° C. to produce the CuTeZrAl alloy.

13 . The method of manufacturing an Al—Te—Cu—Zr alloy sputtering target according to claim 11 , wherein the pulverized CuTe powder has a mean grain size of 0.1 to 10 μm, the Zr raw material powder has a mean grain size of 0.1 to 10 μm, and the Al raw material powder has a mean grain size of 0.1 to 10 μm.

14 . The method of manufacturing an Al—Te—Cu—Zr alloy sputtering target according to claim 11 , wherein the pulverized CuTe powder is subjected to hydrogen reduction.

15 . The method of manufacturing an Al—Te—Cu—Zr alloy sputtering target according to claim 11 , wherein during the step of pulverizing the CuTe alloy, the alloy is pulverized under an inert atmosphere or under vacuum.

16 . The method of manufacturing an Al—Te—Cu—Zr alloy sputtering target according to claim 7 , wherein the pulverized CuTe powder has a mean grain size of 0.1 to 10 μm, the Zr raw material powder has a mean grain size of 0.1 to 10 μm, and the Al raw material powder has a mean grain size of 0.1 to 10 μm.

17 . The method of manufacturing an Al—Te—Cu—Zr alloy sputtering target according to claim 7 , wherein the pulverized CuTe powder is subjected to hydrogen reduction.

18 . The method of manufacturing an Al—Te—Cu—Zr alloy sputtering target according to claim 7 , wherein during the step of pulverizing the CuTe alloy, the alloy is pulverized under an inert atmosphere or under vacuum.

Assignees

• Jx Nippon Mining & Metals Corp

Inventors

• Koido Yoshimasa

Classifications

• C22C28/00

  Alloys based on a metal not provided for in groups C22C5/00 - C22C27/00 · CPC title

• B22F2201/20

  Use of vacuum · CPC title

• B22F9/22

  using gaseous reductors · CPC title

• B22D7/005

  from non-ferrous metals · CPC title

• C22C21/00

  Alloys based on aluminium · CPC title